Electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries
Nickel–cobalt–manganese oxides (NCMs) are widely investigated as cathode materials for lithium-ion batteries (LIBs) given their beneficial synergistic effects of high storability, electrical conductivity, and stability. However, their use as an anode for LIBs has not been adequately addressed. NCM n...
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| Language: | English |
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Frontiers Media S.A.
2022
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| Online Access: | http://umpir.ump.edu.my/id/eprint/33577/ http://umpir.ump.edu.my/id/eprint/33577/1/Electrospun%20ternary%20composite%20metal%20oxide%20fibers%20as%20an%20anode%20for%20lithium-ion%20batteries.pdf |
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| author | Ling, Jin Kiong Karuppiah, Chelladurai Das, Santanu Izan Izwan, Misnon Mohd Hasbi, Ab. Rahim Yang, Chun-Chen Jose, Rajan |
| author_facet | Ling, Jin Kiong Karuppiah, Chelladurai Das, Santanu Izan Izwan, Misnon Mohd Hasbi, Ab. Rahim Yang, Chun-Chen Jose, Rajan |
| author_sort | Ling, Jin Kiong |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Nickel–cobalt–manganese oxides (NCMs) are widely investigated as cathode materials for lithium-ion batteries (LIBs) given their beneficial synergistic effects of high storability, electrical conductivity, and stability. However, their use as an anode for LIBs has not been adequately addressed. NCM nanofibers prepared using the multi-needle electrospinning technique are examined as the anode in LIBs. The NCM nanofibers demonstrated an initial discharge capacity of ∼1,075 mAh g−1 with an initial capacity loss of ∼42%. Through controlling the conductive additive content, the initial discharge capacity can be further improved to ∼1810 mAh g−1, mostly attributing to the improved interfiber connectivity supported by the significant lowering of impedance when the amount of conductive additive is increased. This study also reveals that the conventional ratio of 80:10:10 wt% (active materials:additives:binder) is not optimal for all samples, especially for the high active surface area electrospun nanofibers. |
| first_indexed | 2025-11-15T03:10:40Z |
| format | Article |
| id | ump-33577 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T03:10:40Z |
| publishDate | 2022 |
| publisher | Frontiers Media S.A. |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-335772022-04-15T03:37:20Z http://umpir.ump.edu.my/id/eprint/33577/ Electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries Ling, Jin Kiong Karuppiah, Chelladurai Das, Santanu Izan Izwan, Misnon Mohd Hasbi, Ab. Rahim Yang, Chun-Chen Jose, Rajan Q Science (General) T Technology (General) Nickel–cobalt–manganese oxides (NCMs) are widely investigated as cathode materials for lithium-ion batteries (LIBs) given their beneficial synergistic effects of high storability, electrical conductivity, and stability. However, their use as an anode for LIBs has not been adequately addressed. NCM nanofibers prepared using the multi-needle electrospinning technique are examined as the anode in LIBs. The NCM nanofibers demonstrated an initial discharge capacity of ∼1,075 mAh g−1 with an initial capacity loss of ∼42%. Through controlling the conductive additive content, the initial discharge capacity can be further improved to ∼1810 mAh g−1, mostly attributing to the improved interfiber connectivity supported by the significant lowering of impedance when the amount of conductive additive is increased. This study also reveals that the conventional ratio of 80:10:10 wt% (active materials:additives:binder) is not optimal for all samples, especially for the high active surface area electrospun nanofibers. Frontiers Media S.A. 2022-02-22 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/33577/1/Electrospun%20ternary%20composite%20metal%20oxide%20fibers%20as%20an%20anode%20for%20lithium-ion%20batteries.pdf Ling, Jin Kiong and Karuppiah, Chelladurai and Das, Santanu and Izan Izwan, Misnon and Mohd Hasbi, Ab. Rahim and Yang, Chun-Chen and Jose, Rajan (2022) Electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries. Frontiers in Materials, 9 (815204). pp. 1-10. ISSN 2296-8016. (Published) https://doi.org/10.3389/fmats.2022.815204 https://doi.org/10.3389/fmats.2022.815204 |
| spellingShingle | Q Science (General) T Technology (General) Ling, Jin Kiong Karuppiah, Chelladurai Das, Santanu Izan Izwan, Misnon Mohd Hasbi, Ab. Rahim Yang, Chun-Chen Jose, Rajan Electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries |
| title | Electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries |
| title_full | Electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries |
| title_fullStr | Electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries |
| title_full_unstemmed | Electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries |
| title_short | Electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries |
| title_sort | electrospun ternary composite metal oxide fibers as an anode for lithium-ion batteries |
| topic | Q Science (General) T Technology (General) |
| url | http://umpir.ump.edu.my/id/eprint/33577/ http://umpir.ump.edu.my/id/eprint/33577/ http://umpir.ump.edu.my/id/eprint/33577/ http://umpir.ump.edu.my/id/eprint/33577/1/Electrospun%20ternary%20composite%20metal%20oxide%20fibers%20as%20an%20anode%20for%20lithium-ion%20batteries.pdf |