Physicochemical and electrochemical characterization of CdO/g-C3N4 nanocomposite for the photoreforming of petrochemical wastewater

Current research involved fabrication of cadmium oxide-graphitic carbon nitride (CdO/g-C3N4) nanocomposite and evaluation of their photocatalytic properties by physical and electrochemical analysis techniques. The X-ray diffraction (XRD) test demonstrated that the nanocomposite consists of graphite...

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Main Authors: Thurga Devi, Munusamy, Chin, Sim Yee, Khan, Maksudur R.
Format: Article
Language:English
Published: Elsevier Ltd 2021
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/32003/
http://umpir.ump.edu.my/id/eprint/32003/1/Physicochemical%20and%20electrochemical.pdf
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author Thurga Devi, Munusamy
Chin, Sim Yee
Khan, Maksudur R.
author_facet Thurga Devi, Munusamy
Chin, Sim Yee
Khan, Maksudur R.
author_sort Thurga Devi, Munusamy
building UMP Institutional Repository
collection Online Access
description Current research involved fabrication of cadmium oxide-graphitic carbon nitride (CdO/g-C3N4) nanocomposite and evaluation of their photocatalytic properties by physical and electrochemical analysis techniques. The X-ray diffraction (XRD) test demonstrated that the nanocomposite consists of graphite and monteponite phases. UV–Vis absorption and photoluminescence (PL) analysis clearly pointed out both the band gap reduction and inhibition in recombination rate of charge carriers. Based on the photoelectrochemical (PEC) analysis, linear sweep voltammetry (LSV) data demonstrated that CdO/g-C3N4 nanocomposite shows higher anodic current (0.57 mA/cm2) under light emission as compared to dark environment (0.02 mA/cm2). This study was also deliberated with proposed mechanism on photoreforming of wastewater reaction scheme.
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spelling ump-320032021-09-09T08:30:34Z http://umpir.ump.edu.my/id/eprint/32003/ Physicochemical and electrochemical characterization of CdO/g-C3N4 nanocomposite for the photoreforming of petrochemical wastewater Thurga Devi, Munusamy Chin, Sim Yee Khan, Maksudur R. TP Chemical technology Current research involved fabrication of cadmium oxide-graphitic carbon nitride (CdO/g-C3N4) nanocomposite and evaluation of their photocatalytic properties by physical and electrochemical analysis techniques. The X-ray diffraction (XRD) test demonstrated that the nanocomposite consists of graphite and monteponite phases. UV–Vis absorption and photoluminescence (PL) analysis clearly pointed out both the band gap reduction and inhibition in recombination rate of charge carriers. Based on the photoelectrochemical (PEC) analysis, linear sweep voltammetry (LSV) data demonstrated that CdO/g-C3N4 nanocomposite shows higher anodic current (0.57 mA/cm2) under light emission as compared to dark environment (0.02 mA/cm2). This study was also deliberated with proposed mechanism on photoreforming of wastewater reaction scheme. Elsevier Ltd 2021 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/32003/1/Physicochemical%20and%20electrochemical.pdf Thurga Devi, Munusamy and Chin, Sim Yee and Khan, Maksudur R. (2021) Physicochemical and electrochemical characterization of CdO/g-C3N4 nanocomposite for the photoreforming of petrochemical wastewater. Materials Today: Proceedings, 42 (Part1). pp. 15-21. ISSN 2214-7853. (Published) https://doi.org/10.1016/j.matpr.2020.08.340 https://doi.org/10.1016/j.matpr.2020.08.340
spellingShingle TP Chemical technology
Thurga Devi, Munusamy
Chin, Sim Yee
Khan, Maksudur R.
Physicochemical and electrochemical characterization of CdO/g-C3N4 nanocomposite for the photoreforming of petrochemical wastewater
title Physicochemical and electrochemical characterization of CdO/g-C3N4 nanocomposite for the photoreforming of petrochemical wastewater
title_full Physicochemical and electrochemical characterization of CdO/g-C3N4 nanocomposite for the photoreforming of petrochemical wastewater
title_fullStr Physicochemical and electrochemical characterization of CdO/g-C3N4 nanocomposite for the photoreforming of petrochemical wastewater
title_full_unstemmed Physicochemical and electrochemical characterization of CdO/g-C3N4 nanocomposite for the photoreforming of petrochemical wastewater
title_short Physicochemical and electrochemical characterization of CdO/g-C3N4 nanocomposite for the photoreforming of petrochemical wastewater
title_sort physicochemical and electrochemical characterization of cdo/g-c3n4 nanocomposite for the photoreforming of petrochemical wastewater
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/32003/
http://umpir.ump.edu.my/id/eprint/32003/
http://umpir.ump.edu.my/id/eprint/32003/
http://umpir.ump.edu.my/id/eprint/32003/1/Physicochemical%20and%20electrochemical.pdf