Influence of molecular weight on the morphology and structure of Electrospun Polyvinylidene Fluoride (PVDF)

Polyvinylidene fluoride (PVDF) reveals outstanding properties such as lightweight, high flexibility and temperature independence material compared to other polymers. In this study, PVDF as a function of molecular weight was prepared by using an electrospinning method in order to study the influences...

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Main Authors: Aminatul Sobirah, Zahari, Muhammad Hafiz, Mazwir, Izan Izwan, Misnon
Format: Article
Language:English
Published: Trans Tech Publications Ltd, Switzerland 2021
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/31627/
http://umpir.ump.edu.my/id/eprint/31627/1/Influence%20of%20Molecular%20Weight%20on%20the%20Morphology%20and%20Structure%20of%20Electrospun%20Polyvinylidene%20Fluoride%20%28PVDF%29%20%281%29.pdf
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author Aminatul Sobirah, Zahari
Muhammad Hafiz, Mazwir
Izan Izwan, Misnon
author_facet Aminatul Sobirah, Zahari
Muhammad Hafiz, Mazwir
Izan Izwan, Misnon
author_sort Aminatul Sobirah, Zahari
building UMP Institutional Repository
collection Online Access
description Polyvinylidene fluoride (PVDF) reveals outstanding properties such as lightweight, high flexibility and temperature independence material compared to other polymers. In this study, PVDF as a function of molecular weight was prepared by using an electrospinning method in order to study the influences of the molecular weight of the PVDF membrane on the morphology. Analytical techniques such as field emission scanning electron microscope (FESEM), Fourier transform infrared (FTIR) and X-ray diffraction (XRD) were used to characterize the electrospun PVDF membranes. FESEM was used for morphology characterization and also to measure the diameter of fibers while XRD and FTIR were employed to examine crystalline phase membranes. The lowest molecular weight has the smallest average diameter of fibers. Besides, a combination of both α-phase and β- phase crystalline was showed by XRD and FTIR results. This is because the crystalline phases and membrane morphology depend on the polymer molecular weight. In this research, it was found that the largest β-phase fraction for the electrospun PVDF membrane is 80.25 % with a molecular weight at 180,000 g/mol.
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spelling ump-316272021-09-30T08:34:22Z http://umpir.ump.edu.my/id/eprint/31627/ Influence of molecular weight on the morphology and structure of Electrospun Polyvinylidene Fluoride (PVDF) Aminatul Sobirah, Zahari Muhammad Hafiz, Mazwir Izan Izwan, Misnon HD28 Management. Industrial Management TP Chemical technology Polyvinylidene fluoride (PVDF) reveals outstanding properties such as lightweight, high flexibility and temperature independence material compared to other polymers. In this study, PVDF as a function of molecular weight was prepared by using an electrospinning method in order to study the influences of the molecular weight of the PVDF membrane on the morphology. Analytical techniques such as field emission scanning electron microscope (FESEM), Fourier transform infrared (FTIR) and X-ray diffraction (XRD) were used to characterize the electrospun PVDF membranes. FESEM was used for morphology characterization and also to measure the diameter of fibers while XRD and FTIR were employed to examine crystalline phase membranes. The lowest molecular weight has the smallest average diameter of fibers. Besides, a combination of both α-phase and β- phase crystalline was showed by XRD and FTIR results. This is because the crystalline phases and membrane morphology depend on the polymer molecular weight. In this research, it was found that the largest β-phase fraction for the electrospun PVDF membrane is 80.25 % with a molecular weight at 180,000 g/mol. Trans Tech Publications Ltd, Switzerland 2021-03-30 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/31627/1/Influence%20of%20Molecular%20Weight%20on%20the%20Morphology%20and%20Structure%20of%20Electrospun%20Polyvinylidene%20Fluoride%20%28PVDF%29%20%281%29.pdf Aminatul Sobirah, Zahari and Muhammad Hafiz, Mazwir and Izan Izwan, Misnon (2021) Influence of molecular weight on the morphology and structure of Electrospun Polyvinylidene Fluoride (PVDF). Materials Science Forum, 1025. pp. 293-298. ISSN 1662-9752. (Published) https://doi.org/10.4028/www.scientific.net/MSF.1025.293
spellingShingle HD28 Management. Industrial Management
TP Chemical technology
Aminatul Sobirah, Zahari
Muhammad Hafiz, Mazwir
Izan Izwan, Misnon
Influence of molecular weight on the morphology and structure of Electrospun Polyvinylidene Fluoride (PVDF)
title Influence of molecular weight on the morphology and structure of Electrospun Polyvinylidene Fluoride (PVDF)
title_full Influence of molecular weight on the morphology and structure of Electrospun Polyvinylidene Fluoride (PVDF)
title_fullStr Influence of molecular weight on the morphology and structure of Electrospun Polyvinylidene Fluoride (PVDF)
title_full_unstemmed Influence of molecular weight on the morphology and structure of Electrospun Polyvinylidene Fluoride (PVDF)
title_short Influence of molecular weight on the morphology and structure of Electrospun Polyvinylidene Fluoride (PVDF)
title_sort influence of molecular weight on the morphology and structure of electrospun polyvinylidene fluoride (pvdf)
topic HD28 Management. Industrial Management
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/31627/
http://umpir.ump.edu.my/id/eprint/31627/
http://umpir.ump.edu.my/id/eprint/31627/1/Influence%20of%20Molecular%20Weight%20on%20the%20Morphology%20and%20Structure%20of%20Electrospun%20Polyvinylidene%20Fluoride%20%28PVDF%29%20%281%29.pdf