Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media

In this work, commercial cellulose was modified with allylthiourea (Cel-AT) to remove methylene blue (MB) from aqueous solution. Characterization study include FTIR analysis along with UV spectrophotometer. A variety of physico-chemical properties such as kinetic, total sorption capacity loaded and...

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Main Authors: Siti Maizatul Ameera, Azhar, Ahmad Salihin, Samsudin, Wan Norfazilah, Wan Ismail, Nurlin, Abu Samah
Format: Article
Language:English
Published: John Wiley & Sons, Inc. 2021
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/31591/
http://umpir.ump.edu.my/id/eprint/31591/1/MB.pdf
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author Siti Maizatul Ameera, Azhar
Ahmad Salihin, Samsudin
Wan Norfazilah, Wan Ismail
Nurlin, Abu Samah
author_facet Siti Maizatul Ameera, Azhar
Ahmad Salihin, Samsudin
Wan Norfazilah, Wan Ismail
Nurlin, Abu Samah
author_sort Siti Maizatul Ameera, Azhar
building UMP Institutional Repository
collection Online Access
description In this work, commercial cellulose was modified with allylthiourea (Cel-AT) to remove methylene blue (MB) from aqueous solution. Characterization study include FTIR analysis along with UV spectrophotometer. A variety of physico-chemical properties such as kinetic, total sorption capacity loaded and pH effect by using Cel-AT sorbent has been carried out. The main finding was the adsorption total capacity of Cel-AT for MB was 3 times more than commercial cellulose (Cel) when the concentration of MB increase in batch mode. In kinetic study, the MB removal efficiency was at 90% after 5 min of removal using Cel-AT as a sorbent and Cel-AT fulfil pseudo second order of reaction. The optimum MB removal is at pH 11 with 95% of removal. There was spectral peak was observed in the spectrum of FTIR and it has been addressed accordingly. As a conclusion, the suggested method improved the quality of MB sorption onto the Cel-AT in terms of contact time and less laborious.
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publisher John Wiley & Sons, Inc.
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spelling ump-315912024-01-03T03:43:11Z http://umpir.ump.edu.my/id/eprint/31591/ Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media Siti Maizatul Ameera, Azhar Ahmad Salihin, Samsudin Wan Norfazilah, Wan Ismail Nurlin, Abu Samah QD Chemistry In this work, commercial cellulose was modified with allylthiourea (Cel-AT) to remove methylene blue (MB) from aqueous solution. Characterization study include FTIR analysis along with UV spectrophotometer. A variety of physico-chemical properties such as kinetic, total sorption capacity loaded and pH effect by using Cel-AT sorbent has been carried out. The main finding was the adsorption total capacity of Cel-AT for MB was 3 times more than commercial cellulose (Cel) when the concentration of MB increase in batch mode. In kinetic study, the MB removal efficiency was at 90% after 5 min of removal using Cel-AT as a sorbent and Cel-AT fulfil pseudo second order of reaction. The optimum MB removal is at pH 11 with 95% of removal. There was spectral peak was observed in the spectrum of FTIR and it has been addressed accordingly. As a conclusion, the suggested method improved the quality of MB sorption onto the Cel-AT in terms of contact time and less laborious. John Wiley & Sons, Inc. 2021-06-17 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/31591/1/MB.pdf Siti Maizatul Ameera, Azhar and Ahmad Salihin, Samsudin and Wan Norfazilah, Wan Ismail and Nurlin, Abu Samah (2021) Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media. Macromolecular Symposia, 397 (1). p. 2000239. ISSN 1521-3900. (Published) https://onlinelibrary.wiley.com/journal/15213900 https://doi.org/10.1002/masy.202000239
spellingShingle QD Chemistry
Siti Maizatul Ameera, Azhar
Ahmad Salihin, Samsudin
Wan Norfazilah, Wan Ismail
Nurlin, Abu Samah
Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media
title Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media
title_full Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media
title_fullStr Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media
title_full_unstemmed Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media
title_short Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media
title_sort kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/31591/
http://umpir.ump.edu.my/id/eprint/31591/
http://umpir.ump.edu.my/id/eprint/31591/
http://umpir.ump.edu.my/id/eprint/31591/1/MB.pdf