Ionic conductivity and electrochemical properties of alginate–NN4NO3-based biopolymer electrolytes for EDLC application

The alginate doped with various content of ammonium nitrate (NH4NO3) as solid biopolymer electrolytes (SBEs) has been carried out in this work by casting method using distilled water as solvent. The impedance studies of alginate-NH4NO3 SBEs film were determined via impedance spectroscopy. The lowest...

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Main Authors: Norfatihah, Mazuki, Nur Muhitul Jalilah, Rasali, Sahraoui, B., Ahmad Salihin, Samsudin
Format: Article
Language:English
Published: DRPM Universitas Indonesia 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/31059/
http://umpir.ump.edu.my/id/eprint/31059/1/Ionic%20conductivity%20and%20electrochemical%20properties%20of%20alginate_NN4.pdf
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author Norfatihah, Mazuki
Nur Muhitul Jalilah, Rasali
Sahraoui, B.
Ahmad Salihin, Samsudin
author_facet Norfatihah, Mazuki
Nur Muhitul Jalilah, Rasali
Sahraoui, B.
Ahmad Salihin, Samsudin
author_sort Norfatihah, Mazuki
building UMP Institutional Repository
collection Online Access
description The alginate doped with various content of ammonium nitrate (NH4NO3) as solid biopolymer electrolytes (SBEs) has been carried out in this work by casting method using distilled water as solvent. The impedance studies of alginate-NH4NO3 SBEs film were determined via impedance spectroscopy. The lowest value of bulk resistance, Rb shows the maximum ionic conductivity is observed at 5.56 x 10-5 S cm-1 for sample containing with 25 wt. % NH4NO3 at ambient temperature (303K). The temperature dependence of ionic conductivity has been evaluated and confirm the present electrolytes follows Arrhenius behavior. The highest conducting sample was fabricated into electrical double layer and characterized for their electrochemical properties by using cyclic voltammetry (CV) and galvanostatic charge-discharged (GCD). The specific capacitance obtained from CV analysis shows decreasing pattern as increased the scan rate. While the value of specific capacitance calculated from GCD analysis exhibits almost persistent value up to 5000th cycles.
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institution Universiti Malaysia Pahang
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language English
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publishDate 2020
publisher DRPM Universitas Indonesia
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spelling ump-310592021-04-28T06:01:12Z http://umpir.ump.edu.my/id/eprint/31059/ Ionic conductivity and electrochemical properties of alginate–NN4NO3-based biopolymer electrolytes for EDLC application Norfatihah, Mazuki Nur Muhitul Jalilah, Rasali Sahraoui, B. Ahmad Salihin, Samsudin QC Physics TP Chemical technology The alginate doped with various content of ammonium nitrate (NH4NO3) as solid biopolymer electrolytes (SBEs) has been carried out in this work by casting method using distilled water as solvent. The impedance studies of alginate-NH4NO3 SBEs film were determined via impedance spectroscopy. The lowest value of bulk resistance, Rb shows the maximum ionic conductivity is observed at 5.56 x 10-5 S cm-1 for sample containing with 25 wt. % NH4NO3 at ambient temperature (303K). The temperature dependence of ionic conductivity has been evaluated and confirm the present electrolytes follows Arrhenius behavior. The highest conducting sample was fabricated into electrical double layer and characterized for their electrochemical properties by using cyclic voltammetry (CV) and galvanostatic charge-discharged (GCD). The specific capacitance obtained from CV analysis shows decreasing pattern as increased the scan rate. While the value of specific capacitance calculated from GCD analysis exhibits almost persistent value up to 5000th cycles. DRPM Universitas Indonesia 2020-01-04 Article PeerReviewed pdf en cc_by_nc_nd_4 http://umpir.ump.edu.my/id/eprint/31059/1/Ionic%20conductivity%20and%20electrochemical%20properties%20of%20alginate_NN4.pdf Norfatihah, Mazuki and Nur Muhitul Jalilah, Rasali and Sahraoui, B. and Ahmad Salihin, Samsudin (2020) Ionic conductivity and electrochemical properties of alginate–NN4NO3-based biopolymer electrolytes for EDLC application. Makara Journal of Technology, 24 (1). pp. 1-7. ISSN 2355-2786. (Published) https://doi.org/10.7454/mst.v24i1.3832 https://doi.org/10.7454/mst.v24i1.3832
spellingShingle QC Physics
TP Chemical technology
Norfatihah, Mazuki
Nur Muhitul Jalilah, Rasali
Sahraoui, B.
Ahmad Salihin, Samsudin
Ionic conductivity and electrochemical properties of alginate–NN4NO3-based biopolymer electrolytes for EDLC application
title Ionic conductivity and electrochemical properties of alginate–NN4NO3-based biopolymer electrolytes for EDLC application
title_full Ionic conductivity and electrochemical properties of alginate–NN4NO3-based biopolymer electrolytes for EDLC application
title_fullStr Ionic conductivity and electrochemical properties of alginate–NN4NO3-based biopolymer electrolytes for EDLC application
title_full_unstemmed Ionic conductivity and electrochemical properties of alginate–NN4NO3-based biopolymer electrolytes for EDLC application
title_short Ionic conductivity and electrochemical properties of alginate–NN4NO3-based biopolymer electrolytes for EDLC application
title_sort ionic conductivity and electrochemical properties of alginate–nn4no3-based biopolymer electrolytes for edlc application
topic QC Physics
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/31059/
http://umpir.ump.edu.my/id/eprint/31059/
http://umpir.ump.edu.my/id/eprint/31059/
http://umpir.ump.edu.my/id/eprint/31059/1/Ionic%20conductivity%20and%20electrochemical%20properties%20of%20alginate_NN4.pdf