Acrylonitrile-grafted recycled papers for Ni(II) ions removal

Recently, naturally occurring biopolymers have gained interests in its application as adsorbent for the removal of metal ions. The graft copolymerization modification of acrylonitrile monomer in the presence of ceric ammonium nitrate was successfully done on extracted recycled papers. The fabricated...

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Main Authors: N. A., Awang, W. N. W., Salleh, S. Z. N., Ahmad, N. H., Ismail, N., Rosman, Norazlianie, Sazali, H., Ibrahim, A. F., Ismail
Format: Article
Published: Elsevier Ltd 2021
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Online Access:http://umpir.ump.edu.my/id/eprint/30630/
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author N. A., Awang
W. N. W., Salleh
S. Z. N., Ahmad
N. H., Ismail
N., Rosman
Norazlianie, Sazali
H., Ibrahim
A. F., Ismail
author_facet N. A., Awang
W. N. W., Salleh
S. Z. N., Ahmad
N. H., Ismail
N., Rosman
Norazlianie, Sazali
H., Ibrahim
A. F., Ismail
author_sort N. A., Awang
building UMP Institutional Repository
collection Online Access
description Recently, naturally occurring biopolymers have gained interests in its application as adsorbent for the removal of metal ions. The graft copolymerization modification of acrylonitrile monomer in the presence of ceric ammonium nitrate was successfully done on extracted recycled papers. The fabricated grafted adsorbent was analyzed by using scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) mapping, X-ray powder diffraction (XRD), as well as Fourier-transform infrared spectroscopy (FTIR). The parameters of the adsorption process were varied for the pH of the solution, concentration of Ni(II) ions, and time duration. As a result, the most optimum condition was achieved at pH 5 with 160 mg/L in a duration of 1 h, which reached 317.5 mg/g equivalent to 79.3% removal. The adsorption behavior tallied with Freundlich and Pseudo-second-order for adsorption and kinetic models, respectively. Convincingly, acrylonitrile-grafted recycled papers are able to be competitive and act as an efficient adsorbent in metal ions removal.
first_indexed 2025-11-15T02:59:06Z
format Article
id ump-30630
institution Universiti Malaysia Pahang
institution_category Local University
last_indexed 2025-11-15T02:59:06Z
publishDate 2021
publisher Elsevier Ltd
recordtype eprints
repository_type Digital Repository
spelling ump-306302021-02-04T08:42:18Z http://umpir.ump.edu.my/id/eprint/30630/ Acrylonitrile-grafted recycled papers for Ni(II) ions removal N. A., Awang W. N. W., Salleh S. Z. N., Ahmad N. H., Ismail N., Rosman Norazlianie, Sazali H., Ibrahim A. F., Ismail TP Chemical technology Recently, naturally occurring biopolymers have gained interests in its application as adsorbent for the removal of metal ions. The graft copolymerization modification of acrylonitrile monomer in the presence of ceric ammonium nitrate was successfully done on extracted recycled papers. The fabricated grafted adsorbent was analyzed by using scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) mapping, X-ray powder diffraction (XRD), as well as Fourier-transform infrared spectroscopy (FTIR). The parameters of the adsorption process were varied for the pH of the solution, concentration of Ni(II) ions, and time duration. As a result, the most optimum condition was achieved at pH 5 with 160 mg/L in a duration of 1 h, which reached 317.5 mg/g equivalent to 79.3% removal. The adsorption behavior tallied with Freundlich and Pseudo-second-order for adsorption and kinetic models, respectively. Convincingly, acrylonitrile-grafted recycled papers are able to be competitive and act as an efficient adsorbent in metal ions removal. Elsevier Ltd 2021 Article PeerReviewed N. A., Awang and W. N. W., Salleh and S. Z. N., Ahmad and N. H., Ismail and N., Rosman and Norazlianie, Sazali and H., Ibrahim and A. F., Ismail (2021) Acrylonitrile-grafted recycled papers for Ni(II) ions removal. Materials Today: Proceedings. pp. 1-6. ISSN 2214-7853. (In Press / Online First) (In Press / Online First) https://doi.org/10.1016/j.matpr.2020.11.851 https://doi.org/10.1016/j.matpr.2020.11.851
spellingShingle TP Chemical technology
N. A., Awang
W. N. W., Salleh
S. Z. N., Ahmad
N. H., Ismail
N., Rosman
Norazlianie, Sazali
H., Ibrahim
A. F., Ismail
Acrylonitrile-grafted recycled papers for Ni(II) ions removal
title Acrylonitrile-grafted recycled papers for Ni(II) ions removal
title_full Acrylonitrile-grafted recycled papers for Ni(II) ions removal
title_fullStr Acrylonitrile-grafted recycled papers for Ni(II) ions removal
title_full_unstemmed Acrylonitrile-grafted recycled papers for Ni(II) ions removal
title_short Acrylonitrile-grafted recycled papers for Ni(II) ions removal
title_sort acrylonitrile-grafted recycled papers for ni(ii) ions removal
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/30630/
http://umpir.ump.edu.my/id/eprint/30630/
http://umpir.ump.edu.my/id/eprint/30630/