Cross metathesis of plant oil: A mini review on reaction condition and catalysis
The extensive use of the renewable plant oil-derived polyols could be hindered by its low hydroxyl value owing to the oil saturation level and structural limitations. In recent years, olefin cross-metathesis has turn out to be one of the attractive methods to overcome this constraint by redistributi...
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| Format: | Conference or Workshop Item |
| Language: | English |
| Published: |
IOP Publishing
2020
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| Online Access: | http://umpir.ump.edu.my/id/eprint/30475/ http://umpir.ump.edu.my/id/eprint/30475/1/Cross%20metathesis%20of%20plant%20oil.pdf |
| _version_ | 1848823522992848896 |
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| author | Thangavel, Mythili S. Y., Chin |
| author_facet | Thangavel, Mythili S. Y., Chin |
| author_sort | Thangavel, Mythili |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | The extensive use of the renewable plant oil-derived polyols could be hindered by its low hydroxyl value owing to the oil saturation level and structural limitations. In recent years, olefin cross-metathesis has turn out to be one of the attractive methods to overcome this constraint by redistributing alkenes fragments and regenerating carbon-carbon double bonds in the plant oil. The product distribution of the cross-metathesis of plant oil is significantly influenced by the types of catalysts and olefin as well as reaction conditions. Accordingly, dissimilar from the extensive reviews on the types of bio-based feedstocks and catalysts for cross metathesis, this article evaluates in specific the operating condition of cross-metathesising the plant oils using different olefins and catalysts, aiming to identify the future research avenues in developing a more technical feasible process to value add the plant oil. It is anticipated that the product yield resulted from the cross-metathesis of another potential feedstocks, the palm oil could be increased within a practical timeframe using 1-propene or 1-octene with a temperature not more than 60 °C and catalyst loading in ppm level. |
| first_indexed | 2025-11-15T02:58:29Z |
| format | Conference or Workshop Item |
| id | ump-30475 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:58:29Z |
| publishDate | 2020 |
| publisher | IOP Publishing |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-304752021-01-12T04:43:37Z http://umpir.ump.edu.my/id/eprint/30475/ Cross metathesis of plant oil: A mini review on reaction condition and catalysis Thangavel, Mythili S. Y., Chin QD Chemistry TP Chemical technology The extensive use of the renewable plant oil-derived polyols could be hindered by its low hydroxyl value owing to the oil saturation level and structural limitations. In recent years, olefin cross-metathesis has turn out to be one of the attractive methods to overcome this constraint by redistributing alkenes fragments and regenerating carbon-carbon double bonds in the plant oil. The product distribution of the cross-metathesis of plant oil is significantly influenced by the types of catalysts and olefin as well as reaction conditions. Accordingly, dissimilar from the extensive reviews on the types of bio-based feedstocks and catalysts for cross metathesis, this article evaluates in specific the operating condition of cross-metathesising the plant oils using different olefins and catalysts, aiming to identify the future research avenues in developing a more technical feasible process to value add the plant oil. It is anticipated that the product yield resulted from the cross-metathesis of another potential feedstocks, the palm oil could be increased within a practical timeframe using 1-propene or 1-octene with a temperature not more than 60 °C and catalyst loading in ppm level. IOP Publishing 2020 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/30475/1/Cross%20metathesis%20of%20plant%20oil.pdf Thangavel, Mythili and S. Y., Chin (2020) Cross metathesis of plant oil: A mini review on reaction condition and catalysis. In: IOP Conference Series: Materials Science and Engineering, 5th International Conference of Chemical Engineering and Industrial Biotechnology (ICCEIB 2020) , 9-11 August 2020 , Kuala Lumpur, Malaysia. pp. 1-12., 991 (012073). ISSN 1757-899X (Published) |
| spellingShingle | QD Chemistry TP Chemical technology Thangavel, Mythili S. Y., Chin Cross metathesis of plant oil: A mini review on reaction condition and catalysis |
| title | Cross metathesis of plant oil: A mini review on reaction condition and catalysis |
| title_full | Cross metathesis of plant oil: A mini review on reaction condition and catalysis |
| title_fullStr | Cross metathesis of plant oil: A mini review on reaction condition and catalysis |
| title_full_unstemmed | Cross metathesis of plant oil: A mini review on reaction condition and catalysis |
| title_short | Cross metathesis of plant oil: A mini review on reaction condition and catalysis |
| title_sort | cross metathesis of plant oil: a mini review on reaction condition and catalysis |
| topic | QD Chemistry TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/30475/ http://umpir.ump.edu.my/id/eprint/30475/1/Cross%20metathesis%20of%20plant%20oil.pdf |