Simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance

Herein, glass fiber (GF) reinforced binary, ternary, and quaternary poly(lactic acid) (PLA) composites were prepared. Toughening, and chain extension of PLA was achieved through the incorporation of impact modifier and chain extender and their concurrent effects on the spectroscopic, crystallization...

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Main Authors: Akindoyo, John Olabode, Beg, M. D. H., Suriati, Ghazali, Heim, Hans P., Feldmann, Maik, Mariatti, M.
Format: Article
Language:English
Published: John Wiley and Sons Inc. 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/29910/
http://umpir.ump.edu.my/id/eprint/29910/1/Simultaneous%20impact%20modified%20and%20chain%20extended%20glass%20fiber%20.pdf
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author Akindoyo, John Olabode
Beg, M. D. H.
Suriati, Ghazali
Heim, Hans P.
Feldmann, Maik
Mariatti, M.
author_facet Akindoyo, John Olabode
Beg, M. D. H.
Suriati, Ghazali
Heim, Hans P.
Feldmann, Maik
Mariatti, M.
author_sort Akindoyo, John Olabode
building UMP Institutional Repository
collection Online Access
description Herein, glass fiber (GF) reinforced binary, ternary, and quaternary poly(lactic acid) (PLA) composites were prepared. Toughening, and chain extension of PLA was achieved through the incorporation of impact modifier and chain extender and their concurrent effects on the spectroscopic, crystallization, mechanical, thermal, and thermomechanical properties of the composites were investigated. High mechanical properties of GF influenced the mechanical performance of the composites. However, GF alone could not restrict the chain mobility of PLA due to poor interface and low crystallization activities in the PLA‐GF composite. Incorporation of impact modifier and chain extender produced significantly enhanced interaction between GF and PLA. Significantly, the crystallinity, impact strength, and flexural modulus of PLA in the quaternary composite were increased by 58%, 63%, and 66%, respectively. In addition, damping and effectiveness coefficient of the PLA‐GF composite were notably reduced by the simultaneous impact modification and chain extension of the reinforced composites.
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publishDate 2020
publisher John Wiley and Sons Inc.
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spelling ump-299102021-10-27T07:34:58Z http://umpir.ump.edu.my/id/eprint/29910/ Simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance Akindoyo, John Olabode Beg, M. D. H. Suriati, Ghazali Heim, Hans P. Feldmann, Maik Mariatti, M. TP Chemical technology Herein, glass fiber (GF) reinforced binary, ternary, and quaternary poly(lactic acid) (PLA) composites were prepared. Toughening, and chain extension of PLA was achieved through the incorporation of impact modifier and chain extender and their concurrent effects on the spectroscopic, crystallization, mechanical, thermal, and thermomechanical properties of the composites were investigated. High mechanical properties of GF influenced the mechanical performance of the composites. However, GF alone could not restrict the chain mobility of PLA due to poor interface and low crystallization activities in the PLA‐GF composite. Incorporation of impact modifier and chain extender produced significantly enhanced interaction between GF and PLA. Significantly, the crystallinity, impact strength, and flexural modulus of PLA in the quaternary composite were increased by 58%, 63%, and 66%, respectively. In addition, damping and effectiveness coefficient of the PLA‐GF composite were notably reduced by the simultaneous impact modification and chain extension of the reinforced composites. John Wiley and Sons Inc. 2020-08-04 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/29910/1/Simultaneous%20impact%20modified%20and%20chain%20extended%20glass%20fiber%20.pdf Akindoyo, John Olabode and Beg, M. D. H. and Suriati, Ghazali and Heim, Hans P. and Feldmann, Maik and Mariatti, M. (2020) Simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance. Journal of Applied Polymer Science, 138 (5). pp. 1-2. ISSN 0021-8995 (print); 1097-4628 (online). (Published) https://onlinelibrary.wiley.com/doi/epdf/10.1002/app.49752 https://doi.org/10.1002/app.49752
spellingShingle TP Chemical technology
Akindoyo, John Olabode
Beg, M. D. H.
Suriati, Ghazali
Heim, Hans P.
Feldmann, Maik
Mariatti, M.
Simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance
title Simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance
title_full Simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance
title_fullStr Simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance
title_full_unstemmed Simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance
title_short Simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance
title_sort simultaneous impact modified and chain extended glass fiber reinforced poly(lactic acid) composites: mechanical, thermal, crystallization, and dynamic mechanical performance
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/29910/
http://umpir.ump.edu.my/id/eprint/29910/
http://umpir.ump.edu.my/id/eprint/29910/
http://umpir.ump.edu.my/id/eprint/29910/1/Simultaneous%20impact%20modified%20and%20chain%20extended%20glass%20fiber%20.pdf