Modification of diutan gum to enhance rheological properties for oil and gas application

A favorable gelling fluid for oil and gas industry is the one that have good rheological, thermally stable properties and environmental friendly. In the present study, a gelling agent, diutan gum (DG) was modified with N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride (CHPTAC) to enhance the...

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Main Authors: Norhanis, Arbaa′In, Rasidi, Roslan, Jamil, Ismail, Mohd Hasbi, Ab. Rahim
Format: Conference or Workshop Item
Language:English
Published: AIP Publishing 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/29106/
http://umpir.ump.edu.my/id/eprint/29106/1/Modification%20of%20diutan%20gum%20to%20enhance%20rheological%20properties.pdf
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author Norhanis, Arbaa′In
Rasidi, Roslan
Jamil, Ismail
Mohd Hasbi, Ab. Rahim
author_facet Norhanis, Arbaa′In
Rasidi, Roslan
Jamil, Ismail
Mohd Hasbi, Ab. Rahim
author_sort Norhanis, Arbaa′In
building UMP Institutional Repository
collection Online Access
description A favorable gelling fluid for oil and gas industry is the one that have good rheological, thermally stable properties and environmental friendly. In the present study, a gelling agent, diutan gum (DG) was modified with N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride (CHPTAC) to enhance the rheological properties. The modified-diutan gum (MDG) were characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and rheometer. FTIR result shows a significant decreasing of hydroxyl group intensity and the appearance of new peak at 1250 cm-1 attributed to the substitution of CHPTAC on the DG backbone. In addition, the rheological properties of the MDG fluid showed remarkable increases in apparent viscosity. The elastic modulus (G′) and viscous modulus (G″) also increases showing that the MDG have good viscoelastic properties which due to the strong electrostatic interaction between the chains after the modification. This finding showed that, with simple modification using CHPTAC, the rheological properties of MDG gelling agent can be tailored and expected to increase the thermal properties.
first_indexed 2025-11-15T02:53:31Z
format Conference or Workshop Item
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institution Universiti Malaysia Pahang
institution_category Local University
language English
last_indexed 2025-11-15T02:53:31Z
publishDate 2018
publisher AIP Publishing
recordtype eprints
repository_type Digital Repository
spelling ump-291062023-08-15T01:30:58Z http://umpir.ump.edu.my/id/eprint/29106/ Modification of diutan gum to enhance rheological properties for oil and gas application Norhanis, Arbaa′In Rasidi, Roslan Jamil, Ismail Mohd Hasbi, Ab. Rahim QD Chemistry TP Chemical technology A favorable gelling fluid for oil and gas industry is the one that have good rheological, thermally stable properties and environmental friendly. In the present study, a gelling agent, diutan gum (DG) was modified with N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride (CHPTAC) to enhance the rheological properties. The modified-diutan gum (MDG) were characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and rheometer. FTIR result shows a significant decreasing of hydroxyl group intensity and the appearance of new peak at 1250 cm-1 attributed to the substitution of CHPTAC on the DG backbone. In addition, the rheological properties of the MDG fluid showed remarkable increases in apparent viscosity. The elastic modulus (G′) and viscous modulus (G″) also increases showing that the MDG have good viscoelastic properties which due to the strong electrostatic interaction between the chains after the modification. This finding showed that, with simple modification using CHPTAC, the rheological properties of MDG gelling agent can be tailored and expected to increase the thermal properties. AIP Publishing 2018-11-09 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/29106/1/Modification%20of%20diutan%20gum%20to%20enhance%20rheological%20properties.pdf Norhanis, Arbaa′In and Rasidi, Roslan and Jamil, Ismail and Mohd Hasbi, Ab. Rahim (2018) Modification of diutan gum to enhance rheological properties for oil and gas application. In: AIP Conference Proceedings; 4th International Conference on Green Design and Manufacture 2018, IConGDM 2018 , 29 - 30 April 2018 , Eden Star Saigon Hotel, Ho Chi Minh, Vietnam. pp. 1-2., 2030 (020218). ISSN 0094-243X ISBN 9780735417526 (Published) https://doi.org/10.1063/1.5066859
spellingShingle QD Chemistry
TP Chemical technology
Norhanis, Arbaa′In
Rasidi, Roslan
Jamil, Ismail
Mohd Hasbi, Ab. Rahim
Modification of diutan gum to enhance rheological properties for oil and gas application
title Modification of diutan gum to enhance rheological properties for oil and gas application
title_full Modification of diutan gum to enhance rheological properties for oil and gas application
title_fullStr Modification of diutan gum to enhance rheological properties for oil and gas application
title_full_unstemmed Modification of diutan gum to enhance rheological properties for oil and gas application
title_short Modification of diutan gum to enhance rheological properties for oil and gas application
title_sort modification of diutan gum to enhance rheological properties for oil and gas application
topic QD Chemistry
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/29106/
http://umpir.ump.edu.my/id/eprint/29106/
http://umpir.ump.edu.my/id/eprint/29106/1/Modification%20of%20diutan%20gum%20to%20enhance%20rheological%20properties.pdf