Enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: An experimental approach

BACKGROUND: The wide bandgap and low activity under visible light of titanium dioxide (TiO2) have limited its use in many industrial processes. This limitation is associated with the inadequate solar spectrum that activates its surface, where most of the photoexcited electron–hole pairs recombine th...

Full description

Bibliographic Details
Main Authors: Basheer, Esmail Abdullah Mohammed, Abdulbari, Hayder A., Mahmood, Wafaa K.
Format: Article
Language:English
Published: Society of Chemical Industry 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/28895/
http://umpir.ump.edu.my/id/eprint/28895/1/Enhanced%20Titanium%20Dioxide%20Photocatalyst%20Embolized1.pdf
_version_ 1848823161601130496
author Basheer, Esmail Abdullah Mohammed
Abdulbari, Hayder A.
Mahmood, Wafaa K.
author_facet Basheer, Esmail Abdullah Mohammed
Abdulbari, Hayder A.
Mahmood, Wafaa K.
author_sort Basheer, Esmail Abdullah Mohammed
building UMP Institutional Repository
collection Online Access
description BACKGROUND: The wide bandgap and low activity under visible light of titanium dioxide (TiO2) have limited its use in many industrial processes. This limitation is associated with the inadequate solar spectrum that activates its surface, where most of the photoexcited electron–hole pairs recombine thus, leading to a drop in the photocatalytic performance. Immobilization of TiO2 on the surface of other materials such as silicon is a suitable approach to overcome these drawbacks. However, the known immobilization methods require either high‐temperature or high‐pressure conditions. The objective of the present work is to introduce and evaluate a low power‐consumption electrodeposition method for creating a new photocatalyst that can act in visible light using electrochemical anodization for immobilizing the TiO2 on a silicon wafer surface. Two methods were utilized for immobilization which is electrodeposition and sol–gel. The prepared photocatalyst surface and composition were characterized by scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), X‐ray diffraction (XRD), and X‐ray photoelectron spectroscopy (XPS).
first_indexed 2025-11-15T02:52:44Z
format Article
id ump-28895
institution Universiti Malaysia Pahang
institution_category Local University
language English
last_indexed 2025-11-15T02:52:44Z
publishDate 2020
publisher Society of Chemical Industry
recordtype eprints
repository_type Digital Repository
spelling ump-288952020-07-27T06:26:24Z http://umpir.ump.edu.my/id/eprint/28895/ Enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: An experimental approach Basheer, Esmail Abdullah Mohammed Abdulbari, Hayder A. Mahmood, Wafaa K. TP Chemical technology BACKGROUND: The wide bandgap and low activity under visible light of titanium dioxide (TiO2) have limited its use in many industrial processes. This limitation is associated with the inadequate solar spectrum that activates its surface, where most of the photoexcited electron–hole pairs recombine thus, leading to a drop in the photocatalytic performance. Immobilization of TiO2 on the surface of other materials such as silicon is a suitable approach to overcome these drawbacks. However, the known immobilization methods require either high‐temperature or high‐pressure conditions. The objective of the present work is to introduce and evaluate a low power‐consumption electrodeposition method for creating a new photocatalyst that can act in visible light using electrochemical anodization for immobilizing the TiO2 on a silicon wafer surface. Two methods were utilized for immobilization which is electrodeposition and sol–gel. The prepared photocatalyst surface and composition were characterized by scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), X‐ray diffraction (XRD), and X‐ray photoelectron spectroscopy (XPS). Society of Chemical Industry 2020 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/28895/1/Enhanced%20Titanium%20Dioxide%20Photocatalyst%20Embolized1.pdf Basheer, Esmail Abdullah Mohammed and Abdulbari, Hayder A. and Mahmood, Wafaa K. (2020) Enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: An experimental approach. Journal of Chemical Technology and Biotechnology. pp. 1-27. ISSN 1097-4660. (In Press / Online First) (In Press / Online First) https://doi.org/10.1002/jctb.6307 https://doi.org/10.1002/jctb.6307
spellingShingle TP Chemical technology
Basheer, Esmail Abdullah Mohammed
Abdulbari, Hayder A.
Mahmood, Wafaa K.
Enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: An experimental approach
title Enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: An experimental approach
title_full Enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: An experimental approach
title_fullStr Enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: An experimental approach
title_full_unstemmed Enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: An experimental approach
title_short Enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: An experimental approach
title_sort enhanced titanium dioxide photocatalyst embolized on micropores silicon wafer: an experimental approach
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/28895/
http://umpir.ump.edu.my/id/eprint/28895/
http://umpir.ump.edu.my/id/eprint/28895/
http://umpir.ump.edu.my/id/eprint/28895/1/Enhanced%20Titanium%20Dioxide%20Photocatalyst%20Embolized1.pdf