Biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell

This paper reports on preparation and characterization of eggshell for fluid catalytic cracking (FCC) reaction of waste cooking oil (WCO) to produce biogasoline. Hydrocarbon from condensate of gas emitted from a spherical flask reactor was agitated at 350, 400 and 450 resolution per minute (rpm) und...

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Main Authors: Syaiful Nizam, Hassan, Nurdin, Said, Zahira, Yaakob, Mohd Sabri, Mahmud
Format: Conference or Workshop Item
Language:English
Published: IOP Publishing 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/28196/
http://umpir.ump.edu.my/id/eprint/28196/7/Biogasoline%20synthesis%20via%20fluid%20catalytic%20cracking%20of%20waste.pdf
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author Syaiful Nizam, Hassan
Nurdin, Said
Zahira, Yaakob
Mohd Sabri, Mahmud
author_facet Syaiful Nizam, Hassan
Nurdin, Said
Zahira, Yaakob
Mohd Sabri, Mahmud
author_sort Syaiful Nizam, Hassan
building UMP Institutional Repository
collection Online Access
description This paper reports on preparation and characterization of eggshell for fluid catalytic cracking (FCC) reaction of waste cooking oil (WCO) to produce biogasoline. Hydrocarbon from condensate of gas emitted from a spherical flask reactor was agitated at 350, 400 and 450 resolution per minute (rpm) under 350, 400 and 450 oC reaction temperature by the one-factorat-a-time (OFAT) approach was analyzed by using a gas chromatography mass spectrometer (GC-MS). Acid compounds were also recorded. Earlier, the eggshell was ground, calcined at 900 oC for three hours and sieved into 250 – 425 m range of particle size before being analyzed using Fourier-transform-infrared-spectroscopy (FTIR) for calcium oxide content. About 30 wt% of biogasoline ranged from C4 to C12 of alkanes and alkenes was obtained from the 350-oC hydrocarbon condensate after 30, 45 and 60 min of which aromatic compounds increased with the reaction temperature. However, the biogasoline compounds decreased with the reaction temperature. More than 20 wt% was esters and free fatty acids of carbon number greater than 20 were also formed, respectively. Stirring speeds generally increased condensate yield but the increment does not have pattern due to various volatility of the content. The highest biogasoline yield through the FCC reaction was 4.5 wt% at 350 0C at 400 rpm stirring speed, and the product was found comparable with previous research and commercial gasoline.
first_indexed 2025-11-15T02:50:00Z
format Conference or Workshop Item
id ump-28196
institution Universiti Malaysia Pahang
institution_category Local University
language English
last_indexed 2025-11-15T02:50:00Z
publishDate 2020
publisher IOP Publishing
recordtype eprints
repository_type Digital Repository
spelling ump-281962020-04-15T14:58:43Z http://umpir.ump.edu.my/id/eprint/28196/ Biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell Syaiful Nizam, Hassan Nurdin, Said Zahira, Yaakob Mohd Sabri, Mahmud TP Chemical technology This paper reports on preparation and characterization of eggshell for fluid catalytic cracking (FCC) reaction of waste cooking oil (WCO) to produce biogasoline. Hydrocarbon from condensate of gas emitted from a spherical flask reactor was agitated at 350, 400 and 450 resolution per minute (rpm) under 350, 400 and 450 oC reaction temperature by the one-factorat-a-time (OFAT) approach was analyzed by using a gas chromatography mass spectrometer (GC-MS). Acid compounds were also recorded. Earlier, the eggshell was ground, calcined at 900 oC for three hours and sieved into 250 – 425 m range of particle size before being analyzed using Fourier-transform-infrared-spectroscopy (FTIR) for calcium oxide content. About 30 wt% of biogasoline ranged from C4 to C12 of alkanes and alkenes was obtained from the 350-oC hydrocarbon condensate after 30, 45 and 60 min of which aromatic compounds increased with the reaction temperature. However, the biogasoline compounds decreased with the reaction temperature. More than 20 wt% was esters and free fatty acids of carbon number greater than 20 were also formed, respectively. Stirring speeds generally increased condensate yield but the increment does not have pattern due to various volatility of the content. The highest biogasoline yield through the FCC reaction was 4.5 wt% at 350 0C at 400 rpm stirring speed, and the product was found comparable with previous research and commercial gasoline. IOP Publishing 2020 Conference or Workshop Item PeerReviewed pdf en cc_by http://umpir.ump.edu.my/id/eprint/28196/7/Biogasoline%20synthesis%20via%20fluid%20catalytic%20cracking%20of%20waste.pdf Syaiful Nizam, Hassan and Nurdin, Said and Zahira, Yaakob and Mohd Sabri, Mahmud (2020) Biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell. In: IOP Conference Series: Materials Science and Engineering, Energy Security and Chemical Engineering Congress , 17-19 July 2019 , Kuala Lumpur, Malaysia. pp. 1-6., 736 (022069). ISSN 1757-8981 (Print), 1757-899X (Online) (Published) https://doi.org/10.1088/1757-899X/736/2/022069 022069
spellingShingle TP Chemical technology
Syaiful Nizam, Hassan
Nurdin, Said
Zahira, Yaakob
Mohd Sabri, Mahmud
Biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell
title Biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell
title_full Biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell
title_fullStr Biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell
title_full_unstemmed Biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell
title_short Biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell
title_sort biogasoline synthesis via fluid catalytic cracking of waste cooking oil using treated eggshell
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/28196/
http://umpir.ump.edu.my/id/eprint/28196/
http://umpir.ump.edu.my/id/eprint/28196/
http://umpir.ump.edu.my/id/eprint/28196/7/Biogasoline%20synthesis%20via%20fluid%20catalytic%20cracking%20of%20waste.pdf