PI/NCC carbon membrane : effect of additives loading towards hydrogen separation

Incorporating thermally labile polymer-based additives is a facile and practical approach in developing superior carbon membranes. In this study, three different thermally labile polymers, microcrystalline cellulose (MCC), nanocrystalline cellulose (NCC), and polyvinylpyrrolidone (PVP), were introdu...

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Main Authors: Norazlianie, Sazali, R., Mamat, J. P., Siregar, T., Gunawan, W. N. W., Salleh, N. A. H. M., Nordin
Format: Conference or Workshop Item
Language:English
English
Published: IOP Publishing 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/28078/
http://umpir.ump.edu.my/id/eprint/28078/1/Sazali_2020_IOP_Conf._Ser.__Mater._Sci._Eng._736_022008.pdf
http://umpir.ump.edu.my/id/eprint/28078/7/PI%20NCC%20carbon%20membrane-effect%20of%20additives%20loading%20towards%20hydrogen%20separation.pdf
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author Norazlianie, Sazali
R., Mamat
J. P., Siregar
T., Gunawan
W. N. W., Salleh
N. A. H. M., Nordin
author_facet Norazlianie, Sazali
R., Mamat
J. P., Siregar
T., Gunawan
W. N. W., Salleh
N. A. H. M., Nordin
author_sort Norazlianie, Sazali
building UMP Institutional Repository
collection Online Access
description Incorporating thermally labile polymer-based additives is a facile and practical approach in developing superior carbon membranes. In this study, three different thermally labile polymers, microcrystalline cellulose (MCC), nanocrystalline cellulose (NCC), and polyvinylpyrrolidone (PVP), were introduced separately to P84-copolyimide (PI) solution as additive and their impact on membrane performance were investigated. Firstly, NCC was added as the membrane pore former for hydrogen gas (H2) separation. The addition of NCC significantly increased pore channels in the membrane, hence contributed to high gas permeance and selectivity. The tests involving pure H2 and N2 permeation were carried out at room temperature. Carbon membranes carbonized at a final temperature of 800°C with the heating rate of 3°C/min under Ar flow achieved the greatest H2/N2 selectivity of 434.68±1.39, hence proving the potential of NCC as a good additive.
first_indexed 2025-11-15T02:49:33Z
format Conference or Workshop Item
id ump-28078
institution Universiti Malaysia Pahang
institution_category Local University
language English
English
last_indexed 2025-11-15T02:49:33Z
publishDate 2020
publisher IOP Publishing
recordtype eprints
repository_type Digital Repository
spelling ump-280782020-03-10T07:03:21Z http://umpir.ump.edu.my/id/eprint/28078/ PI/NCC carbon membrane : effect of additives loading towards hydrogen separation Norazlianie, Sazali R., Mamat J. P., Siregar T., Gunawan W. N. W., Salleh N. A. H. M., Nordin Q Science (General) TJ Mechanical engineering and machinery TP Chemical technology Incorporating thermally labile polymer-based additives is a facile and practical approach in developing superior carbon membranes. In this study, three different thermally labile polymers, microcrystalline cellulose (MCC), nanocrystalline cellulose (NCC), and polyvinylpyrrolidone (PVP), were introduced separately to P84-copolyimide (PI) solution as additive and their impact on membrane performance were investigated. Firstly, NCC was added as the membrane pore former for hydrogen gas (H2) separation. The addition of NCC significantly increased pore channels in the membrane, hence contributed to high gas permeance and selectivity. The tests involving pure H2 and N2 permeation were carried out at room temperature. Carbon membranes carbonized at a final temperature of 800°C with the heating rate of 3°C/min under Ar flow achieved the greatest H2/N2 selectivity of 434.68±1.39, hence proving the potential of NCC as a good additive. IOP Publishing 2020 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/28078/1/Sazali_2020_IOP_Conf._Ser.__Mater._Sci._Eng._736_022008.pdf pdf en cc_by http://umpir.ump.edu.my/id/eprint/28078/7/PI%20NCC%20carbon%20membrane-effect%20of%20additives%20loading%20towards%20hydrogen%20separation.pdf Norazlianie, Sazali and R., Mamat and J. P., Siregar and T., Gunawan and W. N. W., Salleh and N. A. H. M., Nordin (2020) PI/NCC carbon membrane : effect of additives loading towards hydrogen separation. In: IOP Conference Series: Materials Science and Engineering; Energy Security and Chemical Engineering Congress (ESChE) 2019 , 17-19 July 2019 , Kuala Lumpur, Malaysia. pp. 1-8., 736 (022002). ISSN 1757-8981 (Print), 1757-899X (Online) (Published) https://doi.org/10.1088/1757-899X/736/2/022002
spellingShingle Q Science (General)
TJ Mechanical engineering and machinery
TP Chemical technology
Norazlianie, Sazali
R., Mamat
J. P., Siregar
T., Gunawan
W. N. W., Salleh
N. A. H. M., Nordin
PI/NCC carbon membrane : effect of additives loading towards hydrogen separation
title PI/NCC carbon membrane : effect of additives loading towards hydrogen separation
title_full PI/NCC carbon membrane : effect of additives loading towards hydrogen separation
title_fullStr PI/NCC carbon membrane : effect of additives loading towards hydrogen separation
title_full_unstemmed PI/NCC carbon membrane : effect of additives loading towards hydrogen separation
title_short PI/NCC carbon membrane : effect of additives loading towards hydrogen separation
title_sort pi/ncc carbon membrane : effect of additives loading towards hydrogen separation
topic Q Science (General)
TJ Mechanical engineering and machinery
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/28078/
http://umpir.ump.edu.my/id/eprint/28078/
http://umpir.ump.edu.my/id/eprint/28078/1/Sazali_2020_IOP_Conf._Ser.__Mater._Sci._Eng._736_022008.pdf
http://umpir.ump.edu.my/id/eprint/28078/7/PI%20NCC%20carbon%20membrane-effect%20of%20additives%20loading%20towards%20hydrogen%20separation.pdf