A simple synthesis route for preparation and optical properties of PMMA-g-ZnO nanocomposites through surface-initiated radical polymerization

An effortless chemisorption access for the planning of nanocomposites containing a semiconductor ZnO nanoparticles and poly(methyl methacrylate) (PMMA) is demonstrated. First, thiol-functionalized ZnO (ZnO-SH) were prepared by a silanization reaction between ZnO nanoparticles and (3-mercaptopropyl)...

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Main Authors: Bach, Long Giang, Nguyen, Duy Chinh, Nguyen, Phu Thuong Nhan, Tran, T. H., Islam, Md. Rafiqul, Lim, Kwon Taek, Vo, Dai-Viet N., Nguyen, Trinh Duy
Format: Conference or Workshop Item
Language:English
Published: IOP Publishing 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/27575/
http://umpir.ump.edu.my/id/eprint/27575/1/A%20simple%20synthesis%20route%20for%20preparation%20and%20optical%20properties.pdf
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author Bach, Long Giang
Nguyen, Duy Chinh
Nguyen, Phu Thuong Nhan
Tran, T. H.
Islam, Md. Rafiqul
Lim, Kwon Taek
Vo, Dai-Viet N.
Nguyen, Trinh Duy
author_facet Bach, Long Giang
Nguyen, Duy Chinh
Nguyen, Phu Thuong Nhan
Tran, T. H.
Islam, Md. Rafiqul
Lim, Kwon Taek
Vo, Dai-Viet N.
Nguyen, Trinh Duy
author_sort Bach, Long Giang
building UMP Institutional Repository
collection Online Access
description An effortless chemisorption access for the planning of nanocomposites containing a semiconductor ZnO nanoparticles and poly(methyl methacrylate) (PMMA) is demonstrated. First, thiol-functionalized ZnO (ZnO-SH) were prepared by a silanization reaction between ZnO nanoparticles and (3-mercaptopropyl) trimethoxysilane. Then, a reserved radical polymerization of methyl methacrylate in the attendance of Zinc oxide-thiol (ZnO-SH) and butyrolactam produced PMMA-g-ZnO nanocomposites. DSC were used to examine the weight decline of glass transition temperature of nanocomposites. The ocular characteristics of the nanocomposites were studied by Ultraviolet-visible (UV–vis) absorption spectroscopy and photoluminescence spectroscopy (PL). The results accentuate the role of the grafted PMMA polymer segments in augmenting the strength of dispersal and near-band edge (NBE) emission of ZnO nanoparticles.
first_indexed 2025-11-15T02:47:30Z
format Conference or Workshop Item
id ump-27575
institution Universiti Malaysia Pahang
institution_category Local University
language English
last_indexed 2025-11-15T02:47:30Z
publishDate 2019
publisher IOP Publishing
recordtype eprints
repository_type Digital Repository
spelling ump-275752020-04-03T07:09:28Z http://umpir.ump.edu.my/id/eprint/27575/ A simple synthesis route for preparation and optical properties of PMMA-g-ZnO nanocomposites through surface-initiated radical polymerization Bach, Long Giang Nguyen, Duy Chinh Nguyen, Phu Thuong Nhan Tran, T. H. Islam, Md. Rafiqul Lim, Kwon Taek Vo, Dai-Viet N. Nguyen, Trinh Duy TP Chemical technology An effortless chemisorption access for the planning of nanocomposites containing a semiconductor ZnO nanoparticles and poly(methyl methacrylate) (PMMA) is demonstrated. First, thiol-functionalized ZnO (ZnO-SH) were prepared by a silanization reaction between ZnO nanoparticles and (3-mercaptopropyl) trimethoxysilane. Then, a reserved radical polymerization of methyl methacrylate in the attendance of Zinc oxide-thiol (ZnO-SH) and butyrolactam produced PMMA-g-ZnO nanocomposites. DSC were used to examine the weight decline of glass transition temperature of nanocomposites. The ocular characteristics of the nanocomposites were studied by Ultraviolet-visible (UV–vis) absorption spectroscopy and photoluminescence spectroscopy (PL). The results accentuate the role of the grafted PMMA polymer segments in augmenting the strength of dispersal and near-band edge (NBE) emission of ZnO nanoparticles. IOP Publishing 2019-03-11 Conference or Workshop Item PeerReviewed pdf en cc_by http://umpir.ump.edu.my/id/eprint/27575/1/A%20simple%20synthesis%20route%20for%20preparation%20and%20optical%20properties.pdf Bach, Long Giang and Nguyen, Duy Chinh and Nguyen, Phu Thuong Nhan and Tran, T. H. and Islam, Md. Rafiqul and Lim, Kwon Taek and Vo, Dai-Viet N. and Nguyen, Trinh Duy (2019) A simple synthesis route for preparation and optical properties of PMMA-g-ZnO nanocomposites through surface-initiated radical polymerization. In: IOP Conference Series: Materials Science and Engineering, 3rd International Conference on New Material and Chemical Industry , 17-19 November 2018 , Sanya, China. pp. 1-8., 479 (012108). ISSN 1757-8981 (Print), 1757-899X (Online) (Published) https://doi.org/10.1088/1757-899X/479/1/012108
spellingShingle TP Chemical technology
Bach, Long Giang
Nguyen, Duy Chinh
Nguyen, Phu Thuong Nhan
Tran, T. H.
Islam, Md. Rafiqul
Lim, Kwon Taek
Vo, Dai-Viet N.
Nguyen, Trinh Duy
A simple synthesis route for preparation and optical properties of PMMA-g-ZnO nanocomposites through surface-initiated radical polymerization
title A simple synthesis route for preparation and optical properties of PMMA-g-ZnO nanocomposites through surface-initiated radical polymerization
title_full A simple synthesis route for preparation and optical properties of PMMA-g-ZnO nanocomposites through surface-initiated radical polymerization
title_fullStr A simple synthesis route for preparation and optical properties of PMMA-g-ZnO nanocomposites through surface-initiated radical polymerization
title_full_unstemmed A simple synthesis route for preparation and optical properties of PMMA-g-ZnO nanocomposites through surface-initiated radical polymerization
title_short A simple synthesis route for preparation and optical properties of PMMA-g-ZnO nanocomposites through surface-initiated radical polymerization
title_sort simple synthesis route for preparation and optical properties of pmma-g-zno nanocomposites through surface-initiated radical polymerization
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/27575/
http://umpir.ump.edu.my/id/eprint/27575/
http://umpir.ump.edu.my/id/eprint/27575/1/A%20simple%20synthesis%20route%20for%20preparation%20and%20optical%20properties.pdf