PVDF/HMO ultrafiltration membrane for efficient oil/water separation

In this research, hydrous manganese oxide (HMO) nanoparticles was adopted in polyvinylidene fluoride (PVDF) to improve the ability of the mixed matrix membrane (MMM) to separate oil/water emulsions. The MMMs – which were added with various amounts of HMO loading (3, 5, 7 and 10 wt%) – were character...

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Main Authors: Nurul Hafiza, Ismail, Wan Norharyati, Wan Salleh, Nor Asikin, Awang, Siti Zu Nurain, Ahmad, Nurafiqah, Rosman, Norazlianie, Sazali, Ismail, A. F.
Format: Article
Language:English
English
Published: Taylor & Francis 2019
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Online Access:http://umpir.ump.edu.my/id/eprint/27044/
http://umpir.ump.edu.my/id/eprint/27044/1/N%20SAZALI%20CEC%20NEW.docx
http://umpir.ump.edu.my/id/eprint/27044/2/PVDF-HMO%20ultrafiltration%20membrane%20for%20efficient%20oil__abstract.pdf
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author Nurul Hafiza, Ismail
Wan Norharyati, Wan Salleh
Nor Asikin, Awang
Siti Zu Nurain, Ahmad
Nurafiqah, Rosman
Norazlianie, Sazali
Ismail, A. F.
author_facet Nurul Hafiza, Ismail
Wan Norharyati, Wan Salleh
Nor Asikin, Awang
Siti Zu Nurain, Ahmad
Nurafiqah, Rosman
Norazlianie, Sazali
Ismail, A. F.
author_sort Nurul Hafiza, Ismail
building UMP Institutional Repository
collection Online Access
description In this research, hydrous manganese oxide (HMO) nanoparticles was adopted in polyvinylidene fluoride (PVDF) to improve the ability of the mixed matrix membrane (MMM) to separate oil/water emulsions. The MMMs – which were added with various amounts of HMO loading (3, 5, 7 and 10 wt%) – were characterized for its physicochemical properties, morphological structure, and nanoparticles dispersion of the PVDF/HMO membrane. Evidently, the presence of these nanoparticles increased the hydrophilicity and oleophobicity of the PVDF/HMO membrane as compared to those of the pristine PVDF. Concurrently, the water contact angle was reduced from 99 to 58 while oil contact angle increased from 0 to 35 . The presence of -OH groups and Mn element channeling the PVDF/HMO membrane wetting properties, which in turn improved the membrane’s affinity towards water molecules and aversion to oil droplets. The PVDF/HMO membrane that contained 10 wt% of HMO loading exhibited a water flux (402 L/m2 h) – 10 times greater than the pristine PVDF membrane with 93% oil rejection rate.
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publishDate 2019
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spelling ump-270442020-03-09T04:50:08Z http://umpir.ump.edu.my/id/eprint/27044/ PVDF/HMO ultrafiltration membrane for efficient oil/water separation Nurul Hafiza, Ismail Wan Norharyati, Wan Salleh Nor Asikin, Awang Siti Zu Nurain, Ahmad Nurafiqah, Rosman Norazlianie, Sazali Ismail, A. F. Q Science (General) TP Chemical technology In this research, hydrous manganese oxide (HMO) nanoparticles was adopted in polyvinylidene fluoride (PVDF) to improve the ability of the mixed matrix membrane (MMM) to separate oil/water emulsions. The MMMs – which were added with various amounts of HMO loading (3, 5, 7 and 10 wt%) – were characterized for its physicochemical properties, morphological structure, and nanoparticles dispersion of the PVDF/HMO membrane. Evidently, the presence of these nanoparticles increased the hydrophilicity and oleophobicity of the PVDF/HMO membrane as compared to those of the pristine PVDF. Concurrently, the water contact angle was reduced from 99 to 58 while oil contact angle increased from 0 to 35 . The presence of -OH groups and Mn element channeling the PVDF/HMO membrane wetting properties, which in turn improved the membrane’s affinity towards water molecules and aversion to oil droplets. The PVDF/HMO membrane that contained 10 wt% of HMO loading exhibited a water flux (402 L/m2 h) – 10 times greater than the pristine PVDF membrane with 93% oil rejection rate. Taylor & Francis 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/27044/1/N%20SAZALI%20CEC%20NEW.docx pdf en http://umpir.ump.edu.my/id/eprint/27044/2/PVDF-HMO%20ultrafiltration%20membrane%20for%20efficient%20oil__abstract.pdf Nurul Hafiza, Ismail and Wan Norharyati, Wan Salleh and Nor Asikin, Awang and Siti Zu Nurain, Ahmad and Nurafiqah, Rosman and Norazlianie, Sazali and Ismail, A. F. (2019) PVDF/HMO ultrafiltration membrane for efficient oil/water separation. Chemical Engineering Communications. pp. 1-12. ISSN 0098-6445 (print); 1563-5201 (online). (In Press / Online First) (In Press / Online First) https://doi.org/10.1080/00986445.2019.1650035 https://doi.org/10.1080/00986445.2019.1650035
spellingShingle Q Science (General)
TP Chemical technology
Nurul Hafiza, Ismail
Wan Norharyati, Wan Salleh
Nor Asikin, Awang
Siti Zu Nurain, Ahmad
Nurafiqah, Rosman
Norazlianie, Sazali
Ismail, A. F.
PVDF/HMO ultrafiltration membrane for efficient oil/water separation
title PVDF/HMO ultrafiltration membrane for efficient oil/water separation
title_full PVDF/HMO ultrafiltration membrane for efficient oil/water separation
title_fullStr PVDF/HMO ultrafiltration membrane for efficient oil/water separation
title_full_unstemmed PVDF/HMO ultrafiltration membrane for efficient oil/water separation
title_short PVDF/HMO ultrafiltration membrane for efficient oil/water separation
title_sort pvdf/hmo ultrafiltration membrane for efficient oil/water separation
topic Q Science (General)
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/27044/
http://umpir.ump.edu.my/id/eprint/27044/
http://umpir.ump.edu.my/id/eprint/27044/
http://umpir.ump.edu.my/id/eprint/27044/1/N%20SAZALI%20CEC%20NEW.docx
http://umpir.ump.edu.my/id/eprint/27044/2/PVDF-HMO%20ultrafiltration%20membrane%20for%20efficient%20oil__abstract.pdf