Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods
In this research, polyalkyd resins were prepared from palm oil by polycondensation reaction. A two-step method viz., alcoholysis and esterification were conducted to synthesize polyalkyd resins. Response surface methodology was used to optimize the reaction parameters for esterification like reactio...
| Main Authors: | , , , , |
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| Format: | Conference or Workshop Item |
| Language: | English |
| Published: |
IOP Publishing
2019
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/26956/ http://umpir.ump.edu.my/id/eprint/26956/1/Optimization%20of%20reaction%20parameters%20of%20esterification%20on%20the%20synthesis.pdf |
| _version_ | 1848822667209080832 |
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| author | Beg, M. D. H. Islam, M. R. Ahmed, Badlishah R. M., Yunus Abdullah, Abu Hannifa |
| author_facet | Beg, M. D. H. Islam, M. R. Ahmed, Badlishah R. M., Yunus Abdullah, Abu Hannifa |
| author_sort | Beg, M. D. H. |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | In this research, polyalkyd resins were prepared from palm oil by polycondensation reaction. A two-step method viz., alcoholysis and esterification were conducted to synthesize polyalkyd resins. Response surface methodology was used to optimize the reaction parameters for esterification like reaction temperature, reaction time, catalyst concentration, acid anhydride to mono-glyceride ratio and agitation speed. The optimum condition was used to prepare various types of polyalkyds using different types of acid anhydrides such as, maleic anhydride, succinic anhydride, phthalic anhydride, 3,4,5,6-tetrahydrophthalic anhydride and cis-1,2-cyclohexanedicarboxylic anhydride. Result analyses through RSM revealed a desirability of 0.985 for the reaction time of 88.64 min. Moreover, 91.5% fractional conversion was achieved actually, which is close to the predicted value. The analysis revealed that 3,4,5,6-tetrahydophthalic anhydride-based resin showed improved resinous property than others due to the high degree of crosslinking. |
| first_indexed | 2025-11-15T02:44:53Z |
| format | Conference or Workshop Item |
| id | ump-26956 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:44:53Z |
| publishDate | 2019 |
| publisher | IOP Publishing |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-269562020-03-20T02:55:22Z http://umpir.ump.edu.my/id/eprint/26956/ Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods Beg, M. D. H. Islam, M. R. Ahmed, Badlishah R. M., Yunus Abdullah, Abu Hannifa TP Chemical technology In this research, polyalkyd resins were prepared from palm oil by polycondensation reaction. A two-step method viz., alcoholysis and esterification were conducted to synthesize polyalkyd resins. Response surface methodology was used to optimize the reaction parameters for esterification like reaction temperature, reaction time, catalyst concentration, acid anhydride to mono-glyceride ratio and agitation speed. The optimum condition was used to prepare various types of polyalkyds using different types of acid anhydrides such as, maleic anhydride, succinic anhydride, phthalic anhydride, 3,4,5,6-tetrahydrophthalic anhydride and cis-1,2-cyclohexanedicarboxylic anhydride. Result analyses through RSM revealed a desirability of 0.985 for the reaction time of 88.64 min. Moreover, 91.5% fractional conversion was achieved actually, which is close to the predicted value. The analysis revealed that 3,4,5,6-tetrahydophthalic anhydride-based resin showed improved resinous property than others due to the high degree of crosslinking. IOP Publishing 2019-10-14 Conference or Workshop Item PeerReviewed pdf en cc_by http://umpir.ump.edu.my/id/eprint/26956/1/Optimization%20of%20reaction%20parameters%20of%20esterification%20on%20the%20synthesis.pdf Beg, M. D. H. and Islam, M. R. and Ahmed, Badlishah and R. M., Yunus and Abdullah, Abu Hannifa (2019) Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods. In: IOP Conference Series: Materials Science and Engineering, 6th Global Conference on Polymer and Composite Materials (PCM 2019) , 8-11 July 2019 , Bangkok, Thailand. pp. 1-8., 634 (012038). ISSN 1757-8981 (Print), 1757-899X (Online) (Published) https://doi.org/10.1088/1757-899X/634/1/012038 |
| spellingShingle | TP Chemical technology Beg, M. D. H. Islam, M. R. Ahmed, Badlishah R. M., Yunus Abdullah, Abu Hannifa Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods |
| title | Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods |
| title_full | Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods |
| title_fullStr | Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods |
| title_full_unstemmed | Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods |
| title_short | Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods |
| title_sort | optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/26956/ http://umpir.ump.edu.my/id/eprint/26956/ http://umpir.ump.edu.my/id/eprint/26956/1/Optimization%20of%20reaction%20parameters%20of%20esterification%20on%20the%20synthesis.pdf |