Correlation study on temperature dependent conductivity and line profile along the LLTO/LFP-C cross section for all solid-state Lithium-ion batteries
Nanocrystalline lithium lanthanum titanate (LLTO) – lithium iron phosphate (LFP/C) layered pellets have been prepared to analyze its interface for all solid-state batteries. The conductivity of the samples as a function of temperatures was analyzed and reported. The total conductivity of the sample...
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| Format: | Article |
| Language: | English |
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Elsevier Ltd
2019
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| Online Access: | http://umpir.ump.edu.my/id/eprint/26171/ http://umpir.ump.edu.my/id/eprint/26171/1/Correlation%20study%20on%20temperature%20dependent%20conductivity%20and%20line%20.pdf |
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| author | Abhilash, K. P. Selvin, P. Christopher Nalini, B. Rajan, Jose Hui, Xia Elim, Hendry Izaac Reddy, M. V. |
| author_facet | Abhilash, K. P. Selvin, P. Christopher Nalini, B. Rajan, Jose Hui, Xia Elim, Hendry Izaac Reddy, M. V. |
| author_sort | Abhilash, K. P. |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Nanocrystalline lithium lanthanum titanate (LLTO) – lithium iron phosphate (LFP/C) layered pellets have been prepared to analyze its interface for all solid-state batteries. The conductivity of the samples as a function of temperatures was analyzed and reported. The total conductivity of the sample at room temperature is in the order of 10−5 S cm−1. The SEM and line scan analysis of the samples have been carried out across the cross sections at different temperatures. The study gives a correlation between the line profiles across the LLTO-LFP/C interface and the temperature dependent conductivity of the sample at various temperatures for the first time. At lower temperatures up to 398 K, a narrow interface region occurs at the LLTO – LFP/C interface. At higher temperatures, the ions of elements with higher atomic mass than the lithium, such as lanthanum, iron, titanium, are also accumulate near the interface, which have been verified from the broad interface region occurring in the elemental line scan mapping across the interface. This accumulation of ions causes an additional impediment to the movement of Li+ ions which results in the breakdown in conductivity at 448 K. |
| first_indexed | 2025-11-15T02:41:41Z |
| format | Article |
| id | ump-26171 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:41:41Z |
| publishDate | 2019 |
| publisher | Elsevier Ltd |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-261712019-12-06T08:19:27Z http://umpir.ump.edu.my/id/eprint/26171/ Correlation study on temperature dependent conductivity and line profile along the LLTO/LFP-C cross section for all solid-state Lithium-ion batteries Abhilash, K. P. Selvin, P. Christopher Nalini, B. Rajan, Jose Hui, Xia Elim, Hendry Izaac Reddy, M. V. QC Physics QD Chemistry TP Chemical technology Nanocrystalline lithium lanthanum titanate (LLTO) – lithium iron phosphate (LFP/C) layered pellets have been prepared to analyze its interface for all solid-state batteries. The conductivity of the samples as a function of temperatures was analyzed and reported. The total conductivity of the sample at room temperature is in the order of 10−5 S cm−1. The SEM and line scan analysis of the samples have been carried out across the cross sections at different temperatures. The study gives a correlation between the line profiles across the LLTO-LFP/C interface and the temperature dependent conductivity of the sample at various temperatures for the first time. At lower temperatures up to 398 K, a narrow interface region occurs at the LLTO – LFP/C interface. At higher temperatures, the ions of elements with higher atomic mass than the lithium, such as lanthanum, iron, titanium, are also accumulate near the interface, which have been verified from the broad interface region occurring in the elemental line scan mapping across the interface. This accumulation of ions causes an additional impediment to the movement of Li+ ions which results in the breakdown in conductivity at 448 K. Elsevier Ltd 2019-11 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/26171/1/Correlation%20study%20on%20temperature%20dependent%20conductivity%20and%20line%20.pdf Abhilash, K. P. and Selvin, P. Christopher and Nalini, B. and Rajan, Jose and Hui, Xia and Elim, Hendry Izaac and Reddy, M. V. (2019) Correlation study on temperature dependent conductivity and line profile along the LLTO/LFP-C cross section for all solid-state Lithium-ion batteries. Solid State Ionics, 341. pp. 1-2. ISSN 0167-2738. (Published) https://doi.org/10.1016/j.ssi.2019.115032 https://doi.org/10.1016/j.ssi.2019.115032 |
| spellingShingle | QC Physics QD Chemistry TP Chemical technology Abhilash, K. P. Selvin, P. Christopher Nalini, B. Rajan, Jose Hui, Xia Elim, Hendry Izaac Reddy, M. V. Correlation study on temperature dependent conductivity and line profile along the LLTO/LFP-C cross section for all solid-state Lithium-ion batteries |
| title | Correlation study on temperature dependent conductivity and line profile along the LLTO/LFP-C cross section for all solid-state Lithium-ion batteries |
| title_full | Correlation study on temperature dependent conductivity and line profile along the LLTO/LFP-C cross section for all solid-state Lithium-ion batteries |
| title_fullStr | Correlation study on temperature dependent conductivity and line profile along the LLTO/LFP-C cross section for all solid-state Lithium-ion batteries |
| title_full_unstemmed | Correlation study on temperature dependent conductivity and line profile along the LLTO/LFP-C cross section for all solid-state Lithium-ion batteries |
| title_short | Correlation study on temperature dependent conductivity and line profile along the LLTO/LFP-C cross section for all solid-state Lithium-ion batteries |
| title_sort | correlation study on temperature dependent conductivity and line profile along the llto/lfp-c cross section for all solid-state lithium-ion batteries |
| topic | QC Physics QD Chemistry TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/26171/ http://umpir.ump.edu.my/id/eprint/26171/ http://umpir.ump.edu.my/id/eprint/26171/ http://umpir.ump.edu.my/id/eprint/26171/1/Correlation%20study%20on%20temperature%20dependent%20conductivity%20and%20line%20.pdf |