Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applicat...
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| Format: | Article |
| Language: | English |
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MDPI AG
2019
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| Online Access: | http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/1/Synthesis%20and%20reactivities%20of%20triphenyl%20acetamide%20analogs%20for%20potential%20.pdf |
| _version_ | 1848822314489085952 |
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| author | Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Mohd Zobir, Hussein Akhtar, Muhammad Nadeem |
| author_facet | Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Mohd Zobir, Hussein Akhtar, Muhammad Nadeem |
| author_sort | Israr, Hira |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applications as optoelectronic devices, the nonlinear optical (NLO) properties of all synthesized derivatives (3a–h) were investigated with the help of density functional theory (DFT) methods. The frontier molecular orbitals analysis and reactivity descriptors were investigated for exploring the reactivities. |
| first_indexed | 2025-11-15T02:39:16Z |
| format | Article |
| id | ump-25577 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:39:16Z |
| publishDate | 2019 |
| publisher | MDPI AG |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-255772019-11-20T07:49:17Z http://umpir.ump.edu.my/id/eprint/25577/ Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Mohd Zobir, Hussein Akhtar, Muhammad Nadeem QD Chemistry TP Chemical technology We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applications as optoelectronic devices, the nonlinear optical (NLO) properties of all synthesized derivatives (3a–h) were investigated with the help of density functional theory (DFT) methods. The frontier molecular orbitals analysis and reactivity descriptors were investigated for exploring the reactivities. MDPI AG 2019-05-01 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/25577/1/Synthesis%20and%20reactivities%20of%20triphenyl%20acetamide%20analogs%20for%20potential%20.pdf Israr, Hira and Rasool, Nasir and Rizwan, Komal and Hashmi, Muhammad Ali and Mahmood, Tariq and Rashid, Umer and Mohd Zobir, Hussein and Akhtar, Muhammad Nadeem (2019) Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses. Symmetry, 11 (5). pp. 1-11. ISSN 2073-8994. (Published) https://doi.org/10.3390/sym11050622 https://doi.org/10.3390/sym11050622 |
| spellingShingle | QD Chemistry TP Chemical technology Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Mohd Zobir, Hussein Akhtar, Muhammad Nadeem Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_full | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_fullStr | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_full_unstemmed | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_short | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_sort | synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| topic | QD Chemistry TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/1/Synthesis%20and%20reactivities%20of%20triphenyl%20acetamide%20analogs%20for%20potential%20.pdf |