Size-dependent corrosion behavior of graphene oxide coating

Graphene oxide emerges as an effective corrosion resistant coating. However, the influence of graphene oxide sheets size on the corrosion protection remains unclear. In this report, we investigate the effect of different graphene oxide (GO) sheets size in the formation of corrosion resistant coating...

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Main Authors: Nurul Huda, Abu Bakar, Ali, Gomaa A. M., Jamil, Ismail, Algarni, H., K. F., Chong
Format: Article
Language:English
Published: Elsevier Ltd. 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/25060/
http://umpir.ump.edu.my/id/eprint/25060/1/Size-dependent%20corrosion%20behavior%20of%20graphene%20oxide%20coating.pdf
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author Nurul Huda, Abu Bakar
Ali, Gomaa A. M.
Jamil, Ismail
Algarni, H.
K. F., Chong
author_facet Nurul Huda, Abu Bakar
Ali, Gomaa A. M.
Jamil, Ismail
Algarni, H.
K. F., Chong
author_sort Nurul Huda, Abu Bakar
building UMP Institutional Repository
collection Online Access
description Graphene oxide emerges as an effective corrosion resistant coating. However, the influence of graphene oxide sheets size on the corrosion protection remains unclear. In this report, we investigate the effect of different graphene oxide (GO) sheets size in the formation of corrosion resistant coating. We provide valuable input for electrophoretic deposition in which GO sheets in smaller size diffuse faster during deposition to cause more oxygen reduction, thereby forms a coating with higher hydrophobicity, stronger adhesion, and lesser pinholes. Detailed electrochemical impedance analysis shows that the coating formed from GO sheets in smaller size exhibits higher activation energy for water diffusion, causing slower water diffusion rate and lower permeation into the coating. The findings suggest that GO sheets in smaller size produce a reliable coating with excellent corrosion resistance behavior.
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spelling ump-250602019-10-07T06:51:57Z http://umpir.ump.edu.my/id/eprint/25060/ Size-dependent corrosion behavior of graphene oxide coating Nurul Huda, Abu Bakar Ali, Gomaa A. M. Jamil, Ismail Algarni, H. K. F., Chong TA Engineering (General). Civil engineering (General) TP Chemical technology TS Manufactures Graphene oxide emerges as an effective corrosion resistant coating. However, the influence of graphene oxide sheets size on the corrosion protection remains unclear. In this report, we investigate the effect of different graphene oxide (GO) sheets size in the formation of corrosion resistant coating. We provide valuable input for electrophoretic deposition in which GO sheets in smaller size diffuse faster during deposition to cause more oxygen reduction, thereby forms a coating with higher hydrophobicity, stronger adhesion, and lesser pinholes. Detailed electrochemical impedance analysis shows that the coating formed from GO sheets in smaller size exhibits higher activation energy for water diffusion, causing slower water diffusion rate and lower permeation into the coating. The findings suggest that GO sheets in smaller size produce a reliable coating with excellent corrosion resistance behavior. Elsevier Ltd. 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/25060/1/Size-dependent%20corrosion%20behavior%20of%20graphene%20oxide%20coating.pdf Nurul Huda, Abu Bakar and Ali, Gomaa A. M. and Jamil, Ismail and Algarni, H. and K. F., Chong (2019) Size-dependent corrosion behavior of graphene oxide coating. Progress in Organic Coatings, 134. pp. 272-280. ISSN 0300-9440. (Published) https://doi.org/10.1016/j.porgcoat.2019.05.011 https://doi.org/10.1016/j.porgcoat.2019.05.011
spellingShingle TA Engineering (General). Civil engineering (General)
TP Chemical technology
TS Manufactures
Nurul Huda, Abu Bakar
Ali, Gomaa A. M.
Jamil, Ismail
Algarni, H.
K. F., Chong
Size-dependent corrosion behavior of graphene oxide coating
title Size-dependent corrosion behavior of graphene oxide coating
title_full Size-dependent corrosion behavior of graphene oxide coating
title_fullStr Size-dependent corrosion behavior of graphene oxide coating
title_full_unstemmed Size-dependent corrosion behavior of graphene oxide coating
title_short Size-dependent corrosion behavior of graphene oxide coating
title_sort size-dependent corrosion behavior of graphene oxide coating
topic TA Engineering (General). Civil engineering (General)
TP Chemical technology
TS Manufactures
url http://umpir.ump.edu.my/id/eprint/25060/
http://umpir.ump.edu.my/id/eprint/25060/
http://umpir.ump.edu.my/id/eprint/25060/
http://umpir.ump.edu.my/id/eprint/25060/1/Size-dependent%20corrosion%20behavior%20of%20graphene%20oxide%20coating.pdf