Electrical properties of a novel solid biopolymer electrolyte based on alginate incorporated with citric acid

In the present study, a novel solid biopolymer electrolytes (SBE) system has been introduced by doping citric acid into alginate polymer. The sample of alginate-citric acid SBE system was prepared via solution casting technique. By using Electrical Impedance Spectroscopy (EIS), the electrolytes of a...

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Bibliographic Details
Main Authors: Ahmad Faizrin, Ahmad Fuzlin, Noor Syahida, Ismail, Nagao, Yuki, Ahmad Salihin, Samsudin
Format: Article
Language:English
English
Published: DRPM Universitas Indonesia 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/24900/
http://umpir.ump.edu.my/id/eprint/24900/1/Electrical%20Properties%20of%20A%20Novel%20Solid%20Biopolymer%20Electrolyte1.pdf
http://umpir.ump.edu.my/id/eprint/24900/7/Electrical%20properties%20of%20a%20novel%20solid%20biopolymer%20electrolyte%20based%20on%20alginate%20incorporated%20with%20citric%20acid.pdf
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Summary:In the present study, a novel solid biopolymer electrolytes (SBE) system has been introduced by doping citric acid into alginate polymer. The sample of alginate-citric acid SBE system was prepared via solution casting technique. By using Electrical Impedance Spectroscopy (EIS), the electrolytes of alginate-citric acid has been analyzed from 5 Hz to 1 MHz achieved highest conductivity value at 20 wt.% of 5.49 x 10-7 S cm-1. The temperature dependence of various composition citric acid was found to obey the Arrhenius rules with R2~1 where all SBE system is thermally activated when increasing temperature. The dielectric studies of the alginate-citric acid SBE system showed a non-debye behavior based on data measured using complex permittivity (ε*) and complex electrical modulus (M*) at selected temperature where there are no single relation was found in new biopolymer electrolytes system.