Development of heterogeneous base catayst for transesterification reaction

In this study of heterogeneous base catalyst of potassium nitrate with alumina support was investigated for transesterification of vegetable oil which is palm oil to methyl ester. The environmental problem could be overcome by using heterogeneous base catalyst because the separation of catalyst from...

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Main Author: Sharmilla, Arumugam
Format: Undergraduates Project Papers
Language:English
Published: 2010
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/2488/
http://umpir.ump.edu.my/id/eprint/2488/1/Development%20of%20heterogeneous%20base%20catayst%20for%20transesterification%20reaction.pdf
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author Sharmilla, Arumugam
author_facet Sharmilla, Arumugam
author_sort Sharmilla, Arumugam
building UMP Institutional Repository
collection Online Access
description In this study of heterogeneous base catalyst of potassium nitrate with alumina support was investigated for transesterification of vegetable oil which is palm oil to methyl ester. The environmental problem could be overcome by using heterogeneous base catalyst because the separation of catalyst from final product is easier without use of any solvent and the catalyst is recyclable. The objective of this study is to characterise the developed heterogeneous base catalyst and test it in transesterification reaction at different operating parameters such as molar ratio of methanol to oil, reaction temperature and catalyst loading. After loading potassium nitrate of 35 wt.% on alumina followed by calcination at 773K for 5 h, the catalyst gave the highest basicity and the best catalytic activity for this reaction. The catalysts were characterized by using Fourier Transform Infrared Spectrometers (FTIR) and Scanning Electron Microscopy (SEM). It was found that KNO3/ Al2O show high activity which converting 78.44% of palm oil to methyl ester with the optimum conditions which are at temperature 65°C, methanol to oil ratio of 15:1 and catalyst loading of 8.5% . Therefore, base heterogeneous catalyst of potassium on alumina of support has the potential to be used in biodiesel production processes due to its high activity on transesterification of palm oil.
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format Undergraduates Project Papers
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institution Universiti Malaysia Pahang
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language English
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publishDate 2010
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spelling ump-24882023-08-04T08:08:35Z http://umpir.ump.edu.my/id/eprint/2488/ Development of heterogeneous base catayst for transesterification reaction Sharmilla, Arumugam TP Chemical technology In this study of heterogeneous base catalyst of potassium nitrate with alumina support was investigated for transesterification of vegetable oil which is palm oil to methyl ester. The environmental problem could be overcome by using heterogeneous base catalyst because the separation of catalyst from final product is easier without use of any solvent and the catalyst is recyclable. The objective of this study is to characterise the developed heterogeneous base catalyst and test it in transesterification reaction at different operating parameters such as molar ratio of methanol to oil, reaction temperature and catalyst loading. After loading potassium nitrate of 35 wt.% on alumina followed by calcination at 773K for 5 h, the catalyst gave the highest basicity and the best catalytic activity for this reaction. The catalysts were characterized by using Fourier Transform Infrared Spectrometers (FTIR) and Scanning Electron Microscopy (SEM). It was found that KNO3/ Al2O show high activity which converting 78.44% of palm oil to methyl ester with the optimum conditions which are at temperature 65°C, methanol to oil ratio of 15:1 and catalyst loading of 8.5% . Therefore, base heterogeneous catalyst of potassium on alumina of support has the potential to be used in biodiesel production processes due to its high activity on transesterification of palm oil. 2010-11 Undergraduates Project Papers NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/2488/1/Development%20of%20heterogeneous%20base%20catayst%20for%20transesterification%20reaction.pdf Sharmilla, Arumugam (2010) Development of heterogeneous base catayst for transesterification reaction. Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang.
spellingShingle TP Chemical technology
Sharmilla, Arumugam
Development of heterogeneous base catayst for transesterification reaction
title Development of heterogeneous base catayst for transesterification reaction
title_full Development of heterogeneous base catayst for transesterification reaction
title_fullStr Development of heterogeneous base catayst for transesterification reaction
title_full_unstemmed Development of heterogeneous base catayst for transesterification reaction
title_short Development of heterogeneous base catayst for transesterification reaction
title_sort development of heterogeneous base catayst for transesterification reaction
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/2488/
http://umpir.ump.edu.my/id/eprint/2488/1/Development%20of%20heterogeneous%20base%20catayst%20for%20transesterification%20reaction.pdf