Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture
Ion imprinted polymers (IIPs) draw great attention in various fields because of powerful selectivity to the target metal ions. Thus, the synthesis of copper-ion imprinted polymer (Cu-IIP) was performed by using copper ion and complexing agent rufigallol with ethylene glycol dimethacrylate (EGDMA) an...
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| Format: | Article |
| Language: | English |
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Asian Publication Corporation
2019
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| Online Access: | http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/1/Synthesis%20of%20Ion-Imprinted%20Polymer%20for%20Selective%20Separation.pdf |
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| author | Nor Asiken, Abdul Wahab Mohd Sani, Sarjadi Sazmal Effendi, Arshad M. M., Yusoff Rahman, Md. Lutfor |
| author_facet | Nor Asiken, Abdul Wahab Mohd Sani, Sarjadi Sazmal Effendi, Arshad M. M., Yusoff Rahman, Md. Lutfor |
| author_sort | Nor Asiken, Abdul Wahab |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Ion imprinted polymers (IIPs) draw great attention in various fields because of powerful selectivity to the target metal ions. Thus, the synthesis of copper-ion imprinted polymer (Cu-IIP) was performed by using copper ion and complexing agent rufigallol with ethylene glycol dimethacrylate (EGDMA) and 2,2-azobisisobutyronitrile (AIBN). Aqueous HCl was used to leach Cu2+ ions from the imprinted polymer for creation of cavities of template, which is utilized for cooper ions adsorption with high selectivity. The IIP were characterized using ICP-MS, FE-SEM and also solid state analysis by UV-visible NIR spectroscopy. FT-IR study confirmed the successful complexation of Cu-IIP. The optimum pH was found to be 6 and highest adsorption capacity was estimated about 112.5 mg g-1. Thus, IIP gave good selectivity to copper ions in presence of other transition metals and also IIP can be regenerated for eight times without a subst-antial loss in adsorption capacity. |
| first_indexed | 2025-11-15T02:36:15Z |
| format | Article |
| id | ump-24795 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:36:15Z |
| publishDate | 2019 |
| publisher | Asian Publication Corporation |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-247952019-07-05T07:31:05Z http://umpir.ump.edu.my/id/eprint/24795/ Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture Nor Asiken, Abdul Wahab Mohd Sani, Sarjadi Sazmal Effendi, Arshad M. M., Yusoff Rahman, Md. Lutfor QD Chemistry TP Chemical technology Ion imprinted polymers (IIPs) draw great attention in various fields because of powerful selectivity to the target metal ions. Thus, the synthesis of copper-ion imprinted polymer (Cu-IIP) was performed by using copper ion and complexing agent rufigallol with ethylene glycol dimethacrylate (EGDMA) and 2,2-azobisisobutyronitrile (AIBN). Aqueous HCl was used to leach Cu2+ ions from the imprinted polymer for creation of cavities of template, which is utilized for cooper ions adsorption with high selectivity. The IIP were characterized using ICP-MS, FE-SEM and also solid state analysis by UV-visible NIR spectroscopy. FT-IR study confirmed the successful complexation of Cu-IIP. The optimum pH was found to be 6 and highest adsorption capacity was estimated about 112.5 mg g-1. Thus, IIP gave good selectivity to copper ions in presence of other transition metals and also IIP can be regenerated for eight times without a subst-antial loss in adsorption capacity. Asian Publication Corporation 2019-01-01 Article PeerReviewed pdf en cc_by_nc_4 http://umpir.ump.edu.my/id/eprint/24795/1/Synthesis%20of%20Ion-Imprinted%20Polymer%20for%20Selective%20Separation.pdf Nor Asiken, Abdul Wahab and Mohd Sani, Sarjadi and Sazmal Effendi, Arshad and M. M., Yusoff and Rahman, Md. Lutfor (2019) Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture. Asian Journal of Chemistry, 31 (2). pp. 427-432. ISSN 0970-7077. (Published) https://doi.org/10.14233/ajchem.2019.21544 https://doi.org/10.14233/ajchem.2019.21544 |
| spellingShingle | QD Chemistry TP Chemical technology Nor Asiken, Abdul Wahab Mohd Sani, Sarjadi Sazmal Effendi, Arshad M. M., Yusoff Rahman, Md. Lutfor Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture |
| title | Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture |
| title_full | Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture |
| title_fullStr | Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture |
| title_full_unstemmed | Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture |
| title_short | Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture |
| title_sort | synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture |
| topic | QD Chemistry TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/1/Synthesis%20of%20Ion-Imprinted%20Polymer%20for%20Selective%20Separation.pdf |