Cellulose Supported Pd(II) Complex Catalyzed Carbon-Carbon Bonds Formation
Corn-cobs are an agro-industrial waste and composed of cellulose mostly. In this study cellulose was isolated from the waste corn-cobs and modified to polymeric hydroxamic acid palladium complex 1 and characterized by using a variety of spectroscopic methods such as field emission scanning electron...
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| Format: | Article |
| Language: | English |
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American Scientific Publishers
2019
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| Online Access: | http://umpir.ump.edu.my/id/eprint/24085/ http://umpir.ump.edu.my/id/eprint/24085/1/Cellulose%20Supported%20Pd%28II%29%20Complex%20Catalyzed1.pdf |
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| author | Sarkar, Shaheen M. Rashid, S. S. Karim, Kaykobad Md Rezaul Siti Noor Hidayah, Mustapha Yuen, Mei Lian Normaiza, Z. Khan, Maksudur R. Rahman, Md. Lutfor |
| author_facet | Sarkar, Shaheen M. Rashid, S. S. Karim, Kaykobad Md Rezaul Siti Noor Hidayah, Mustapha Yuen, Mei Lian Normaiza, Z. Khan, Maksudur R. Rahman, Md. Lutfor |
| author_sort | Sarkar, Shaheen M. |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Corn-cobs are an agro-industrial waste and composed of cellulose mostly. In this study cellulose was isolated from the waste corn-cobs and modified to polymeric hydroxamic acid palladium complex 1 and characterized by using a variety of spectroscopic methods such as field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma atomic emission spectroscopy (ICP-AES). The complex 1 exhibited high catalytic activity towards Suzuki and Heck coupling reactions of activated and deactivated aryl halides to give the respective coupling products with high yield. Moreover, the complex 1 was recovered and recycled five times with no considerable loss of catalytic overall performance. |
| first_indexed | 2025-11-15T02:33:27Z |
| format | Article |
| id | ump-24085 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:33:27Z |
| publishDate | 2019 |
| publisher | American Scientific Publishers |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-240852020-06-18T03:56:51Z http://umpir.ump.edu.my/id/eprint/24085/ Cellulose Supported Pd(II) Complex Catalyzed Carbon-Carbon Bonds Formation Sarkar, Shaheen M. Rashid, S. S. Karim, Kaykobad Md Rezaul Siti Noor Hidayah, Mustapha Yuen, Mei Lian Normaiza, Z. Khan, Maksudur R. Rahman, Md. Lutfor QD Chemistry Corn-cobs are an agro-industrial waste and composed of cellulose mostly. In this study cellulose was isolated from the waste corn-cobs and modified to polymeric hydroxamic acid palladium complex 1 and characterized by using a variety of spectroscopic methods such as field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma atomic emission spectroscopy (ICP-AES). The complex 1 exhibited high catalytic activity towards Suzuki and Heck coupling reactions of activated and deactivated aryl halides to give the respective coupling products with high yield. Moreover, the complex 1 was recovered and recycled five times with no considerable loss of catalytic overall performance. American Scientific Publishers 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24085/1/Cellulose%20Supported%20Pd%28II%29%20Complex%20Catalyzed1.pdf Sarkar, Shaheen M. and Rashid, S. S. and Karim, Kaykobad Md Rezaul and Siti Noor Hidayah, Mustapha and Yuen, Mei Lian and Normaiza, Z. and Khan, Maksudur R. and Rahman, Md. Lutfor (2019) Cellulose Supported Pd(II) Complex Catalyzed Carbon-Carbon Bonds Formation. Journal of Nanoscience and Nanotechnology, 19 (5). pp. 2856-2861. ISSN 1533-4880 (Print); 1533-4899 (Online). (Published) https://doi.org/10.1166/jnn.2019.16289 https://doi.org/10.1166/jnn.2019.16289 |
| spellingShingle | QD Chemistry Sarkar, Shaheen M. Rashid, S. S. Karim, Kaykobad Md Rezaul Siti Noor Hidayah, Mustapha Yuen, Mei Lian Normaiza, Z. Khan, Maksudur R. Rahman, Md. Lutfor Cellulose Supported Pd(II) Complex Catalyzed Carbon-Carbon Bonds Formation |
| title | Cellulose Supported Pd(II) Complex Catalyzed Carbon-Carbon Bonds Formation |
| title_full | Cellulose Supported Pd(II) Complex Catalyzed Carbon-Carbon Bonds Formation |
| title_fullStr | Cellulose Supported Pd(II) Complex Catalyzed Carbon-Carbon Bonds Formation |
| title_full_unstemmed | Cellulose Supported Pd(II) Complex Catalyzed Carbon-Carbon Bonds Formation |
| title_short | Cellulose Supported Pd(II) Complex Catalyzed Carbon-Carbon Bonds Formation |
| title_sort | cellulose supported pd(ii) complex catalyzed carbon-carbon bonds formation |
| topic | QD Chemistry |
| url | http://umpir.ump.edu.my/id/eprint/24085/ http://umpir.ump.edu.my/id/eprint/24085/ http://umpir.ump.edu.my/id/eprint/24085/ http://umpir.ump.edu.my/id/eprint/24085/1/Cellulose%20Supported%20Pd%28II%29%20Complex%20Catalyzed1.pdf |