Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes

In this present work, solid biopolymer electrolytes (SBEs) system consists of the blended polymer namely carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) doped ammonium chloride (NH4Cl) at different composition from 0 to 10 wt. % were successfully prepared by using casting technique. The el...

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Main Authors: Norfatihah, Mazuki, Nur Muhitul Jalilah, Rasali, Saadiah, M. A., Ahmad Salihin, Samsudin
Format: Conference or Workshop Item
Language:English
English
Published: American Institute of Physics Inc. 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/23991/
http://umpir.ump.edu.my/id/eprint/23991/7/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMCPVA1.pdf
http://umpir.ump.edu.my/id/eprint/23991/13/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMC-PVA-NH4Cl%20based%20solid%20biopolymer%20electrolytes.pdf
_version_ 1848821931236655104
author Norfatihah, Mazuki
Nur Muhitul Jalilah, Rasali
Saadiah, M. A.
Ahmad Salihin, Samsudin
author_facet Norfatihah, Mazuki
Nur Muhitul Jalilah, Rasali
Saadiah, M. A.
Ahmad Salihin, Samsudin
author_sort Norfatihah, Mazuki
building UMP Institutional Repository
collection Online Access
description In this present work, solid biopolymer electrolytes (SBEs) system consists of the blended polymer namely carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) doped ammonium chloride (NH4Cl) at different composition from 0 to 10 wt. % were successfully prepared by using casting technique. The electrical conductivity of solid biopolymer electrolytes (SBEs) system was investigated by using Electrical Impedance Spectroscopy (EIS). Electrical study shows the highest ionic conductivity in room temperature (303 K) was achieved at 8.86 × 10−5 Scm−1 for sample containing 6 wt. % of NH4Cl. The present system shown unexpected drop after different amount of NH4Cl (1-5 wt. %) were added into the CMC/PVA and its might attributed to the factor of composition of dopant. All SBEs systems were found to be obeys Arrhenius behaviour where the plots show close to unity (R2∼1) and thermally activated.
first_indexed 2025-11-15T02:33:11Z
format Conference or Workshop Item
id ump-23991
institution Universiti Malaysia Pahang
institution_category Local University
language English
English
last_indexed 2025-11-15T02:33:11Z
publishDate 2018
publisher American Institute of Physics Inc.
recordtype eprints
repository_type Digital Repository
spelling ump-239912023-12-04T02:47:26Z http://umpir.ump.edu.my/id/eprint/23991/ Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes Norfatihah, Mazuki Nur Muhitul Jalilah, Rasali Saadiah, M. A. Ahmad Salihin, Samsudin Q Science (General) QC Physics QD Chemistry In this present work, solid biopolymer electrolytes (SBEs) system consists of the blended polymer namely carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) doped ammonium chloride (NH4Cl) at different composition from 0 to 10 wt. % were successfully prepared by using casting technique. The electrical conductivity of solid biopolymer electrolytes (SBEs) system was investigated by using Electrical Impedance Spectroscopy (EIS). Electrical study shows the highest ionic conductivity in room temperature (303 K) was achieved at 8.86 × 10−5 Scm−1 for sample containing 6 wt. % of NH4Cl. The present system shown unexpected drop after different amount of NH4Cl (1-5 wt. %) were added into the CMC/PVA and its might attributed to the factor of composition of dopant. All SBEs systems were found to be obeys Arrhenius behaviour where the plots show close to unity (R2∼1) and thermally activated. American Institute of Physics Inc. 2018 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23991/7/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMCPVA1.pdf pdf en http://umpir.ump.edu.my/id/eprint/23991/13/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMC-PVA-NH4Cl%20based%20solid%20biopolymer%20electrolytes.pdf Norfatihah, Mazuki and Nur Muhitul Jalilah, Rasali and Saadiah, M. A. and Ahmad Salihin, Samsudin (2018) Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes. In: AIP Conference Proceedings: 4th International Conference on Green Design and Manufacture 2018, IConGDM 2018 , 29-30 April 2018 , Ho Chi Minh, Vietnam. pp. 1-7., 2030 (020221). ISSN 0094-243X ISBN 978-0-7354-1752-6 (Published) https://doi.org/10.1063/1.5066862 10.1063/1.5066862
spellingShingle Q Science (General)
QC Physics
QD Chemistry
Norfatihah, Mazuki
Nur Muhitul Jalilah, Rasali
Saadiah, M. A.
Ahmad Salihin, Samsudin
Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_full Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_fullStr Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_full_unstemmed Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_short Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_sort irregularities trend in electrical conductivity of cmc/pva-nh4cl based solid biopolymer electrolytes
topic Q Science (General)
QC Physics
QD Chemistry
url http://umpir.ump.edu.my/id/eprint/23991/
http://umpir.ump.edu.my/id/eprint/23991/
http://umpir.ump.edu.my/id/eprint/23991/
http://umpir.ump.edu.my/id/eprint/23991/7/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMCPVA1.pdf
http://umpir.ump.edu.my/id/eprint/23991/13/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMC-PVA-NH4Cl%20based%20solid%20biopolymer%20electrolytes.pdf