Characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system

The present work deals with the development of carboxymethyl cellulose (CMC) blended with kappa carrageenan (KC) as a host-based polymer electrolyte (PE) system. The CMC/KC films were successfully prepared using solution casting method and were characterized through electrical impedance spectroscopy...

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Main Authors: Nur Khalidah, Zainuddin, Noor Saadiah, Mohd Ali, Anwar, P. P. Abdul Majeed, Ahmad Salihin, Samsudin
Format: Article
Language:English
Published: Taylor & Francis 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/23025/
http://umpir.ump.edu.my/id/eprint/23025/1/Characterization%20on%20conduction%20properties%20of%20carboxymethyl%20cellulose.pdf
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author Nur Khalidah, Zainuddin
Noor Saadiah, Mohd Ali
Anwar, P. P. Abdul Majeed
Ahmad Salihin, Samsudin
author_facet Nur Khalidah, Zainuddin
Noor Saadiah, Mohd Ali
Anwar, P. P. Abdul Majeed
Ahmad Salihin, Samsudin
author_sort Nur Khalidah, Zainuddin
building UMP Institutional Repository
collection Online Access
description The present work deals with the development of carboxymethyl cellulose (CMC) blended with kappa carrageenan (KC) as a host-based polymer electrolyte (PE) system. The CMC/KC films were successfully prepared using solution casting method and were characterized through electrical impedance spectroscopy, Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD) methods, respectively. The FTIR spectrum revealed that the significant region of interaction transpires at wave number 1,057, 1,326, 1,584, and 3,387 cm−1 which correspond to the bending of C–O–C, bending of –OH, asymmetric of –COO− as well as the stretching of –OH, respectively. It has also been demonstrated that the complexation process occurred between CMC and KC. The CMC/KC blend PE system with a ratio of 80:20 achieved an optimum conductivity of 3.91 × 10−7 S cm−1 and had the lowest crystallinity percentage as suggested by the XRD analysis.
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spelling ump-230252023-12-04T03:19:56Z http://umpir.ump.edu.my/id/eprint/23025/ Characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system Nur Khalidah, Zainuddin Noor Saadiah, Mohd Ali Anwar, P. P. Abdul Majeed Ahmad Salihin, Samsudin Q Science (General) TS Manufactures The present work deals with the development of carboxymethyl cellulose (CMC) blended with kappa carrageenan (KC) as a host-based polymer electrolyte (PE) system. The CMC/KC films were successfully prepared using solution casting method and were characterized through electrical impedance spectroscopy, Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD) methods, respectively. The FTIR spectrum revealed that the significant region of interaction transpires at wave number 1,057, 1,326, 1,584, and 3,387 cm−1 which correspond to the bending of C–O–C, bending of –OH, asymmetric of –COO− as well as the stretching of –OH, respectively. It has also been demonstrated that the complexation process occurred between CMC and KC. The CMC/KC blend PE system with a ratio of 80:20 achieved an optimum conductivity of 3.91 × 10−7 S cm−1 and had the lowest crystallinity percentage as suggested by the XRD analysis. Taylor & Francis 2018-05-19 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23025/1/Characterization%20on%20conduction%20properties%20of%20carboxymethyl%20cellulose.pdf Nur Khalidah, Zainuddin and Noor Saadiah, Mohd Ali and Anwar, P. P. Abdul Majeed and Ahmad Salihin, Samsudin (2018) Characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system. International Journal of Polymer Analysis and Characterization, 23 (4). pp. 321-330. ISSN 1023-666X. (Published) https://www.tandfonline.com/doi/abs/10.1080/1023666X.2018.1446887 https://doi.org/10.1080/1023666X.2018.1446887
spellingShingle Q Science (General)
TS Manufactures
Nur Khalidah, Zainuddin
Noor Saadiah, Mohd Ali
Anwar, P. P. Abdul Majeed
Ahmad Salihin, Samsudin
Characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system
title Characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system
title_full Characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system
title_fullStr Characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system
title_full_unstemmed Characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system
title_short Characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system
title_sort characterization on conduction properties of carboxymethyl cellulose/kappa carrageenan blend-based polymer electrolyte system
topic Q Science (General)
TS Manufactures
url http://umpir.ump.edu.my/id/eprint/23025/
http://umpir.ump.edu.my/id/eprint/23025/
http://umpir.ump.edu.my/id/eprint/23025/
http://umpir.ump.edu.my/id/eprint/23025/1/Characterization%20on%20conduction%20properties%20of%20carboxymethyl%20cellulose.pdf