Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation

It is the first time ethylene glycol dry reforming (EGDR) reaction was carried out for syngas production on 10%Ni/Al2O3 catalyst in a tubular fixed-bed reactor at atmospheric condition. Wet-impregnation method was employed for the synthesis of 10%Ni/Al2O3 catalyst. The results of X-ray diffraction m...

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Main Authors: Bahari, M. B., Jun, Lau N., Nor Shafiqah, Mohd Nasir, Fayaz, Fahim, Vo, Dai-Viet N.
Format: Conference or Workshop Item
Language:English
Published: IOP Publishing 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/21193/
http://umpir.ump.edu.my/id/eprint/21193/1/Ethylene%20glycol%20dry%20reforming%20on%20NiAl2O3.pdf
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author Bahari, M. B.
Jun, Lau N.
Nor Shafiqah, Mohd Nasir
Fayaz, Fahim
Vo, Dai-Viet N.
author_facet Bahari, M. B.
Jun, Lau N.
Nor Shafiqah, Mohd Nasir
Fayaz, Fahim
Vo, Dai-Viet N.
author_sort Bahari, M. B.
building UMP Institutional Repository
collection Online Access
description It is the first time ethylene glycol dry reforming (EGDR) reaction was carried out for syngas production on 10%Ni/Al2O3 catalyst in a tubular fixed-bed reactor at atmospheric condition. Wet-impregnation method was employed for the synthesis of 10%Ni/Al2O3 catalyst. The results of X-ray diffraction measurement revealed the presence of γ-Al2O3, NiO, NiAl2O4, Ni0 and graphitic carbon phases on the surface of spent 10%Ni/Al2O3 catalyst. H2 temperature-programmed reduction indicates that NiO and NiAl2O4 phases were totally reduced to metallic nickel phase at reduction temperature above 970 K. EGDR activity appeared to be steady with time-on-stream beyond 5-7 h. Catalytic activity was considerably improved with increasing feed ratio of CO2:C2H6O2 from 1:1 to 2.5:1.
first_indexed 2025-11-15T02:23:04Z
format Conference or Workshop Item
id ump-21193
institution Universiti Malaysia Pahang
institution_category Local University
language English
last_indexed 2025-11-15T02:23:04Z
publishDate 2018
publisher IOP Publishing
recordtype eprints
repository_type Digital Repository
spelling ump-211932019-10-03T08:04:01Z http://umpir.ump.edu.my/id/eprint/21193/ Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation Bahari, M. B. Jun, Lau N. Nor Shafiqah, Mohd Nasir Fayaz, Fahim Vo, Dai-Viet N. TP Chemical technology It is the first time ethylene glycol dry reforming (EGDR) reaction was carried out for syngas production on 10%Ni/Al2O3 catalyst in a tubular fixed-bed reactor at atmospheric condition. Wet-impregnation method was employed for the synthesis of 10%Ni/Al2O3 catalyst. The results of X-ray diffraction measurement revealed the presence of γ-Al2O3, NiO, NiAl2O4, Ni0 and graphitic carbon phases on the surface of spent 10%Ni/Al2O3 catalyst. H2 temperature-programmed reduction indicates that NiO and NiAl2O4 phases were totally reduced to metallic nickel phase at reduction temperature above 970 K. EGDR activity appeared to be steady with time-on-stream beyond 5-7 h. Catalytic activity was considerably improved with increasing feed ratio of CO2:C2H6O2 from 1:1 to 2.5:1. IOP Publishing 2018 Conference or Workshop Item PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/21193/1/Ethylene%20glycol%20dry%20reforming%20on%20NiAl2O3.pdf Bahari, M. B. and Jun, Lau N. and Nor Shafiqah, Mohd Nasir and Fayaz, Fahim and Vo, Dai-Viet N. (2018) Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation. In: IOP Conference Series: Materials Science and Engineering, 3rd International Conference on Energy Materials and Applications , 9-11 May 2018 , University of Salamanca, Salamanca. pp. 1-6., 446 (012013). ISSN 1757-8981 (Print), 1757-899X (Online) (Published) https://doi.org/10.1088/1757-899X/446/1/012013
spellingShingle TP Chemical technology
Bahari, M. B.
Jun, Lau N.
Nor Shafiqah, Mohd Nasir
Fayaz, Fahim
Vo, Dai-Viet N.
Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation
title Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation
title_full Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation
title_fullStr Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation
title_full_unstemmed Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation
title_short Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation
title_sort ethylene glycol dry reforming on ni/al2o3 catalyst for syngas generation
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/21193/
http://umpir.ump.edu.my/id/eprint/21193/
http://umpir.ump.edu.my/id/eprint/21193/1/Ethylene%20glycol%20dry%20reforming%20on%20NiAl2O3.pdf