Polyetherimide hollow fiber membranes for CO2 absorption and stripping in membrane contactor application

Porous asymmetric polyetherimide (PEI) hollow fiber membranes with various non-solvent additives, e.g. lithium chloride, methanol and phosphoric acid (PA) were prepared for CO2 absorption and stripping process in a membrane contractor. The PEI membranes were characterized via gas permeation, liquid...

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Main Authors: Rosmawati, Naim, A. F., Ismail, Matsuura, T., Izzati, Ahmad Rudaini, Syamsul Bahari, Abdullah
Format: Article
Language:English
English
Published: Royal Society of Chemistry 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/20335/
http://umpir.ump.edu.my/id/eprint/20335/1/Polyetherimide%20hollow%20fiber%20membranes%20for%20CO2%20absorption%20and%20stripping%20in%20membrane%20contactor%20application.pdf
http://umpir.ump.edu.my/id/eprint/20335/2/Polyetherimide%20hollow%20fiber%20membranes%20for%20CO2%20absorption%20and%20stripping%20in%20membrane%20contactor%20application%201.pdf
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author Rosmawati, Naim
A. F., Ismail
Matsuura, T.
Izzati, Ahmad Rudaini
Syamsul Bahari, Abdullah
author_facet Rosmawati, Naim
A. F., Ismail
Matsuura, T.
Izzati, Ahmad Rudaini
Syamsul Bahari, Abdullah
author_sort Rosmawati, Naim
building UMP Institutional Repository
collection Online Access
description Porous asymmetric polyetherimide (PEI) hollow fiber membranes with various non-solvent additives, e.g. lithium chloride, methanol and phosphoric acid (PA) were prepared for CO2 absorption and stripping process in a membrane contractor. The PEI membranes were characterized via gas permeation, liquid entry pressure of water (LEPw), contact angle and field emission scanning electronic microscopy analysis. The CO2 absorption and stripping performance was evaluated via the membrane contactor system. Addition of non-solvent additives increased the LEPw and membrane porosity of the PEI membrane with the formation of various membrane microstructures and contact angles. Absorption test was performed at 40 °C showed that the PEI–PA membrane produced the highest absorption flux of 2.7 × 10−2 mol m−2 s−1 at 0.85 m s−1 of liquid velocity. Further testing on PEI–PA membrane was conducted on CO2 stripping at 60 °C, 70 °C to 80 °C and the results indicated that the stripping flux was lower compared to the absorption flux. Stripping tests at 80 °C produced the highest stripping flux which might due to the increase in equilibrium partial pressure of CO2 in the liquid absorbent. Modification of PEI membrane via incorporation of additive can enhanced the performance of a membrane contactor via increasing the absorption and stripping flux.
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publishDate 2018
publisher Royal Society of Chemistry
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spelling ump-203352018-07-30T07:28:34Z http://umpir.ump.edu.my/id/eprint/20335/ Polyetherimide hollow fiber membranes for CO2 absorption and stripping in membrane contactor application Rosmawati, Naim A. F., Ismail Matsuura, T. Izzati, Ahmad Rudaini Syamsul Bahari, Abdullah TP Chemical technology Porous asymmetric polyetherimide (PEI) hollow fiber membranes with various non-solvent additives, e.g. lithium chloride, methanol and phosphoric acid (PA) were prepared for CO2 absorption and stripping process in a membrane contractor. The PEI membranes were characterized via gas permeation, liquid entry pressure of water (LEPw), contact angle and field emission scanning electronic microscopy analysis. The CO2 absorption and stripping performance was evaluated via the membrane contactor system. Addition of non-solvent additives increased the LEPw and membrane porosity of the PEI membrane with the formation of various membrane microstructures and contact angles. Absorption test was performed at 40 °C showed that the PEI–PA membrane produced the highest absorption flux of 2.7 × 10−2 mol m−2 s−1 at 0.85 m s−1 of liquid velocity. Further testing on PEI–PA membrane was conducted on CO2 stripping at 60 °C, 70 °C to 80 °C and the results indicated that the stripping flux was lower compared to the absorption flux. Stripping tests at 80 °C produced the highest stripping flux which might due to the increase in equilibrium partial pressure of CO2 in the liquid absorbent. Modification of PEI membrane via incorporation of additive can enhanced the performance of a membrane contactor via increasing the absorption and stripping flux. Royal Society of Chemistry 2018 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/20335/1/Polyetherimide%20hollow%20fiber%20membranes%20for%20CO2%20absorption%20and%20stripping%20in%20membrane%20contactor%20application.pdf pdf en http://umpir.ump.edu.my/id/eprint/20335/2/Polyetherimide%20hollow%20fiber%20membranes%20for%20CO2%20absorption%20and%20stripping%20in%20membrane%20contactor%20application%201.pdf Rosmawati, Naim and A. F., Ismail and Matsuura, T. and Izzati, Ahmad Rudaini and Syamsul Bahari, Abdullah (2018) Polyetherimide hollow fiber membranes for CO2 absorption and stripping in membrane contactor application. RSC Advances, 8 (7). pp. 3556-3563. ISSN 2046-2069. (Published) http://pubs.rsc.org/en/content/articlepdf/2018/ra/c7ra12045a 10.1039/c7ra12045a
spellingShingle TP Chemical technology
Rosmawati, Naim
A. F., Ismail
Matsuura, T.
Izzati, Ahmad Rudaini
Syamsul Bahari, Abdullah
Polyetherimide hollow fiber membranes for CO2 absorption and stripping in membrane contactor application
title Polyetherimide hollow fiber membranes for CO2 absorption and stripping in membrane contactor application
title_full Polyetherimide hollow fiber membranes for CO2 absorption and stripping in membrane contactor application
title_fullStr Polyetherimide hollow fiber membranes for CO2 absorption and stripping in membrane contactor application
title_full_unstemmed Polyetherimide hollow fiber membranes for CO2 absorption and stripping in membrane contactor application
title_short Polyetherimide hollow fiber membranes for CO2 absorption and stripping in membrane contactor application
title_sort polyetherimide hollow fiber membranes for co2 absorption and stripping in membrane contactor application
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/20335/
http://umpir.ump.edu.my/id/eprint/20335/
http://umpir.ump.edu.my/id/eprint/20335/
http://umpir.ump.edu.my/id/eprint/20335/1/Polyetherimide%20hollow%20fiber%20membranes%20for%20CO2%20absorption%20and%20stripping%20in%20membrane%20contactor%20application.pdf
http://umpir.ump.edu.my/id/eprint/20335/2/Polyetherimide%20hollow%20fiber%20membranes%20for%20CO2%20absorption%20and%20stripping%20in%20membrane%20contactor%20application%201.pdf