Electrochemical Evaluation of Fluorinated MnO2 for Supercapacitor Application

Supercapacitors (SCs) functioning as alternative energy storage is useful in most electronic devices, renewable energy system and hybrid vehicles that have high demand in these days. Excellent electrochemical performance, environment friendliness and low cost material are needed to fulfil the energy...

Full description

Bibliographic Details
Main Authors: Siti Nur Najwa, Mohd Yusof, Nurul Khairiyyah, Mohd Zain, Izan Izwan, Misnon, Rajan, Jose
Format: Conference or Workshop Item
Language:English
Published: EDP Sciences 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/19588/
http://umpir.ump.edu.my/id/eprint/19588/7/Electrochemical%20Evaluation%20of%20Fluorinated%20MnO-fist-2018.pdf
_version_ 1848820914840403968
author Siti Nur Najwa, Mohd Yusof
Nurul Khairiyyah, Mohd Zain
Izan Izwan, Misnon
Rajan, Jose
author_facet Siti Nur Najwa, Mohd Yusof
Nurul Khairiyyah, Mohd Zain
Izan Izwan, Misnon
Rajan, Jose
author_sort Siti Nur Najwa, Mohd Yusof
building UMP Institutional Repository
collection Online Access
description Supercapacitors (SCs) functioning as alternative energy storage is useful in most electronic devices, renewable energy system and hybrid vehicles that have high demand in these days. Excellent electrochemical performance, environment friendliness and low cost material are needed to fulfil the energy demand by most developed country. In this study, fluorination treatment on manganese oxide (MnO2) is considered as an effective way to develop better energy storage due to fluorine electronegativity and reactivity when correlate with other element. Hydrothermal method is used to synthesis MnO2 (MnO2 and MnO2) and the effect of fluorination (FMnO2 and FMnO2) on MnO2 surfaces is investigated on the charge storage ability. The crystallinity and functional groups of the samples was confirmed by the X-ray diffractogram and fourier transforms infrared spectroscopy (FTIR). The cyclic voltammetry (CV) and galvanostatic charging–discharging (CDC) analysis in 0.5 M K2SO4 electrolyte shows that F--MnO2 gives the highest Cs value of 184 F g-1 at scan rate of 5 mV s-1 and 66 F g-1 at current density of 0.3 A g-1. The electrochemical impedance spectroscopy shows that the FMnO2 has the lowest electrode resistances and charge transfer resistance which contributes to high Cs and the high conductivity of electrode.
first_indexed 2025-11-15T02:17:02Z
format Conference or Workshop Item
id ump-19588
institution Universiti Malaysia Pahang
institution_category Local University
language English
last_indexed 2025-11-15T02:17:02Z
publishDate 2018
publisher EDP Sciences
recordtype eprints
repository_type Digital Repository
spelling ump-195882018-03-19T05:46:47Z http://umpir.ump.edu.my/id/eprint/19588/ Electrochemical Evaluation of Fluorinated MnO2 for Supercapacitor Application Siti Nur Najwa, Mohd Yusof Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Rajan, Jose QD Chemistry Supercapacitors (SCs) functioning as alternative energy storage is useful in most electronic devices, renewable energy system and hybrid vehicles that have high demand in these days. Excellent electrochemical performance, environment friendliness and low cost material are needed to fulfil the energy demand by most developed country. In this study, fluorination treatment on manganese oxide (MnO2) is considered as an effective way to develop better energy storage due to fluorine electronegativity and reactivity when correlate with other element. Hydrothermal method is used to synthesis MnO2 (MnO2 and MnO2) and the effect of fluorination (FMnO2 and FMnO2) on MnO2 surfaces is investigated on the charge storage ability. The crystallinity and functional groups of the samples was confirmed by the X-ray diffractogram and fourier transforms infrared spectroscopy (FTIR). The cyclic voltammetry (CV) and galvanostatic charging–discharging (CDC) analysis in 0.5 M K2SO4 electrolyte shows that F--MnO2 gives the highest Cs value of 184 F g-1 at scan rate of 5 mV s-1 and 66 F g-1 at current density of 0.3 A g-1. The electrochemical impedance spectroscopy shows that the FMnO2 has the lowest electrode resistances and charge transfer resistance which contributes to high Cs and the high conductivity of electrode. EDP Sciences 2018 Conference or Workshop Item PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/19588/7/Electrochemical%20Evaluation%20of%20Fluorinated%20MnO-fist-2018.pdf Siti Nur Najwa, Mohd Yusof and Nurul Khairiyyah, Mohd Zain and Izan Izwan, Misnon and Rajan, Jose (2018) Electrochemical Evaluation of Fluorinated MnO2 for Supercapacitor Application. In: MATEC Web of Conferences: Malaysia Technical Universities Conference on Engineering and Technology (MUCET 2017) , 6-7 December 2017 , Penang, Malaysia. pp. 1-6., 150 (02006). ISSN 2261-236X (Published) https://doi.org/10.1051/matecconf/201815002006
spellingShingle QD Chemistry
Siti Nur Najwa, Mohd Yusof
Nurul Khairiyyah, Mohd Zain
Izan Izwan, Misnon
Rajan, Jose
Electrochemical Evaluation of Fluorinated MnO2 for Supercapacitor Application
title Electrochemical Evaluation of Fluorinated MnO2 for Supercapacitor Application
title_full Electrochemical Evaluation of Fluorinated MnO2 for Supercapacitor Application
title_fullStr Electrochemical Evaluation of Fluorinated MnO2 for Supercapacitor Application
title_full_unstemmed Electrochemical Evaluation of Fluorinated MnO2 for Supercapacitor Application
title_short Electrochemical Evaluation of Fluorinated MnO2 for Supercapacitor Application
title_sort electrochemical evaluation of fluorinated mno2 for supercapacitor application
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/19588/
http://umpir.ump.edu.my/id/eprint/19588/
http://umpir.ump.edu.my/id/eprint/19588/7/Electrochemical%20Evaluation%20of%20Fluorinated%20MnO-fist-2018.pdf