Development of nonlinear model for pH system

The control of pH process is a problem frequently encountered in the chemical process and biotechnology industries. It has been recognized as a challenging problem due to the time varying and nonlinear characteristics of the pH processes. This is particularly true when control has to be achieved in...

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Main Author: Mohamad Fikhri, Nor Azman
Format: Undergraduates Project Papers
Language:English
Published: 2010
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/17790/
http://umpir.ump.edu.my/id/eprint/17790/1/Development%20of%20nonlinear%20model%20for%20pH%20system.pdf
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author Mohamad Fikhri, Nor Azman
author_facet Mohamad Fikhri, Nor Azman
author_sort Mohamad Fikhri, Nor Azman
building UMP Institutional Repository
collection Online Access
description The control of pH process is a problem frequently encountered in the chemical process and biotechnology industries. It has been recognized as a challenging problem due to the time varying and nonlinear characteristics of the pH processes. This is particularly true when control has to be achieved in the neutral range (a pH betweens 6 to 8) when only strong acid and strong bases are present. The objectives of this research are development mathematical model for pH system, simulation studies under steady and unsteady state condition and validation of mathematical model through experimentation. The model of the pH process applied in this paper known as the principle of physico- chemical dynamic modeling. This model used acetic acid and sodium hydroxide for simulating the behavior of a simple pH process in a time optimal control loop. The mathematical model based on first principles is developed from acetate balance, sodium balance, acetic acid equilibrium, water equilibrium and electroneutrality equation. Then, the model equations are solved in MATLAB environment. The results from the MATLAB simulation program are compared with experimental result to validate the developed fundamental model. The results showed that most of the error between the model and experiment result are within 3% which proved the model has the capability to capture the dynamics of the process.
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format Undergraduates Project Papers
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institution Universiti Malaysia Pahang
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spelling ump-177902023-08-10T05:58:37Z http://umpir.ump.edu.my/id/eprint/17790/ Development of nonlinear model for pH system Mohamad Fikhri, Nor Azman TP Chemical technology The control of pH process is a problem frequently encountered in the chemical process and biotechnology industries. It has been recognized as a challenging problem due to the time varying and nonlinear characteristics of the pH processes. This is particularly true when control has to be achieved in the neutral range (a pH betweens 6 to 8) when only strong acid and strong bases are present. The objectives of this research are development mathematical model for pH system, simulation studies under steady and unsteady state condition and validation of mathematical model through experimentation. The model of the pH process applied in this paper known as the principle of physico- chemical dynamic modeling. This model used acetic acid and sodium hydroxide for simulating the behavior of a simple pH process in a time optimal control loop. The mathematical model based on first principles is developed from acetate balance, sodium balance, acetic acid equilibrium, water equilibrium and electroneutrality equation. Then, the model equations are solved in MATLAB environment. The results from the MATLAB simulation program are compared with experimental result to validate the developed fundamental model. The results showed that most of the error between the model and experiment result are within 3% which proved the model has the capability to capture the dynamics of the process. 2010-12 Undergraduates Project Papers NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/17790/1/Development%20of%20nonlinear%20model%20for%20pH%20system.pdf Mohamad Fikhri, Nor Azman (2010) Development of nonlinear model for pH system. Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang.
spellingShingle TP Chemical technology
Mohamad Fikhri, Nor Azman
Development of nonlinear model for pH system
title Development of nonlinear model for pH system
title_full Development of nonlinear model for pH system
title_fullStr Development of nonlinear model for pH system
title_full_unstemmed Development of nonlinear model for pH system
title_short Development of nonlinear model for pH system
title_sort development of nonlinear model for ph system
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/17790/
http://umpir.ump.edu.my/id/eprint/17790/1/Development%20of%20nonlinear%20model%20for%20pH%20system.pdf