Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study
The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical p...
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| Format: | Article |
| Language: | English |
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DRPM Universitas Indonesia
2017
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| Online Access: | http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/1/Influence%20of%20Polyethylene%20Glycol%20%28PEG%29%20in%20CMC-NH4BR%20Based%20Polymer%20Electrolytes%20Conductivity%20and%20Electrical%20Study.pdf |
| _version_ | 1848820506867793920 |
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| author | Nur Khalidah, Zainuddin Ahmad Salihin, Samsudin |
| author_facet | Nur Khalidah, Zainuddin Ahmad Salihin, Samsudin |
| author_sort | Nur Khalidah, Zainuddin |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | The present work was carried with new type and promising polymer electrolytes system by development of carboxyl
methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully
prepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity and
thermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedance spectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1 at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable for
the conductance and assist to enhancing the ionic conductivity of the CMC-NH4Br-PEG electrolyte system. The addition of PEG to the CMC-based electrolyte can enhance towards the cation mobility which is turn increases ionic conductivity. The conductivity-temperature of plasticized BdPEs system was found obeys the Arrhenius relation where the ionic conductivity increases with temperature and activation energy for the ions hopping of the highest conducting PEs system only required small value to migrate. The electrical studies show a non-Debye behaviour of BdPEs based on the analyzed data using complex permittivity, ε* and complex electrical modulus, M* of the sample at different temperature. |
| first_indexed | 2025-11-15T02:10:32Z |
| format | Article |
| id | ump-17756 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:10:32Z |
| publishDate | 2017 |
| publisher | DRPM Universitas Indonesia |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-177562018-07-26T01:51:16Z http://umpir.ump.edu.my/id/eprint/17756/ Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study Nur Khalidah, Zainuddin Ahmad Salihin, Samsudin Q Science (General) The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity and thermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedance spectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1 at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable for the conductance and assist to enhancing the ionic conductivity of the CMC-NH4Br-PEG electrolyte system. The addition of PEG to the CMC-based electrolyte can enhance towards the cation mobility which is turn increases ionic conductivity. The conductivity-temperature of plasticized BdPEs system was found obeys the Arrhenius relation where the ionic conductivity increases with temperature and activation energy for the ions hopping of the highest conducting PEs system only required small value to migrate. The electrical studies show a non-Debye behaviour of BdPEs based on the analyzed data using complex permittivity, ε* and complex electrical modulus, M* of the sample at different temperature. DRPM Universitas Indonesia 2017 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/17756/1/Influence%20of%20Polyethylene%20Glycol%20%28PEG%29%20in%20CMC-NH4BR%20Based%20Polymer%20Electrolytes%20Conductivity%20and%20Electrical%20Study.pdf Nur Khalidah, Zainuddin and Ahmad Salihin, Samsudin (2017) Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study. Makara Journal of Technology, 21 (1). pp. 37-42. ISSN 2355-2786. (Published) http://journal.ui.ac.id/technology/index.php/journal/article/view/3078 DOI: 10.7454/mst.v21i1.3078 |
| spellingShingle | Q Science (General) Nur Khalidah, Zainuddin Ahmad Salihin, Samsudin Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study |
| title | Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study |
| title_full | Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study |
| title_fullStr | Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study |
| title_full_unstemmed | Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study |
| title_short | Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study |
| title_sort | influence of polyethylene glycol (peg) in cmc-nh4br based polymer electrolytes: conductivity and electrical study |
| topic | Q Science (General) |
| url | http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/1/Influence%20of%20Polyethylene%20Glycol%20%28PEG%29%20in%20CMC-NH4BR%20Based%20Polymer%20Electrolytes%20Conductivity%20and%20Electrical%20Study.pdf |