Reforming of Glycerol for Hydrogen Production over Ni Based Catalysts: Effect of Support Type

This current work focuses on hydrogen production that is a component in syngas by glycerol dry reforming over 15% nickel (Ni) loading supported on different oxides, namely CaO, ZrO2, and La2O3. The screening process was conducted in a fixed-bed reactor at 700°C under atmospheric pressure. It was fou...

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Main Authors: Nur Nabillah, Mohd Arif, Norazimah, Harun, Nursofia, Mohd Yunus, Vo, Dai-Viet N., Mohammad Tazli, Azizan, Sumaiya, Zainal Abidin
Format: Article
Language:English
Published: Taylor & Francis 2017
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/17377/
http://umpir.ump.edu.my/id/eprint/17377/1/Reforming%20of%20glycerol%20for%20hydrogen%20production%20over%20Ni%20based%20catalysts-%20Effect%20of%20support%20type.pdf
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author Nur Nabillah, Mohd Arif
Norazimah, Harun
Nursofia, Mohd Yunus
Vo, Dai-Viet N.
Mohammad Tazli, Azizan
Sumaiya, Zainal Abidin
author_facet Nur Nabillah, Mohd Arif
Norazimah, Harun
Nursofia, Mohd Yunus
Vo, Dai-Viet N.
Mohammad Tazli, Azizan
Sumaiya, Zainal Abidin
author_sort Nur Nabillah, Mohd Arif
building UMP Institutional Repository
collection Online Access
description This current work focuses on hydrogen production that is a component in syngas by glycerol dry reforming over 15% nickel (Ni) loading supported on different oxides, namely CaO, ZrO2, and La2O3. The screening process was conducted in a fixed-bed reactor at 700°C under atmospheric pressure. It was found that 15% Ni/CaO showed the best performance in screening studies. The effect of temperature and the carbon to glycerol ratio (CGR) was then analyzed for this catalyst. From the analysis, it was seen that 15% Ni/CaO has its optimum condition at 800°C and CGR = 1, where it gives the highest glycerol conversion (XG = 37.66%) and hydrogen yield (YH = 32.45%).
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publisher Taylor & Francis
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spelling ump-173772019-10-18T03:07:47Z http://umpir.ump.edu.my/id/eprint/17377/ Reforming of Glycerol for Hydrogen Production over Ni Based Catalysts: Effect of Support Type Nur Nabillah, Mohd Arif Norazimah, Harun Nursofia, Mohd Yunus Vo, Dai-Viet N. Mohammad Tazli, Azizan Sumaiya, Zainal Abidin TP Chemical technology This current work focuses on hydrogen production that is a component in syngas by glycerol dry reforming over 15% nickel (Ni) loading supported on different oxides, namely CaO, ZrO2, and La2O3. The screening process was conducted in a fixed-bed reactor at 700°C under atmospheric pressure. It was found that 15% Ni/CaO showed the best performance in screening studies. The effect of temperature and the carbon to glycerol ratio (CGR) was then analyzed for this catalyst. From the analysis, it was seen that 15% Ni/CaO has its optimum condition at 800°C and CGR = 1, where it gives the highest glycerol conversion (XG = 37.66%) and hydrogen yield (YH = 32.45%). Taylor & Francis 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/17377/1/Reforming%20of%20glycerol%20for%20hydrogen%20production%20over%20Ni%20based%20catalysts-%20Effect%20of%20support%20type.pdf Nur Nabillah, Mohd Arif and Norazimah, Harun and Nursofia, Mohd Yunus and Vo, Dai-Viet N. and Mohammad Tazli, Azizan and Sumaiya, Zainal Abidin (2017) Reforming of Glycerol for Hydrogen Production over Ni Based Catalysts: Effect of Support Type. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 39 (7). pp. 657-663. ISSN 1556-7036 (Print); 1556-7230 (Online). (Published) http://dx.doi.org/10.1080/15567036.2016.1244580 DOI: 10.1080/15567036.2016.1244580
spellingShingle TP Chemical technology
Nur Nabillah, Mohd Arif
Norazimah, Harun
Nursofia, Mohd Yunus
Vo, Dai-Viet N.
Mohammad Tazli, Azizan
Sumaiya, Zainal Abidin
Reforming of Glycerol for Hydrogen Production over Ni Based Catalysts: Effect of Support Type
title Reforming of Glycerol for Hydrogen Production over Ni Based Catalysts: Effect of Support Type
title_full Reforming of Glycerol for Hydrogen Production over Ni Based Catalysts: Effect of Support Type
title_fullStr Reforming of Glycerol for Hydrogen Production over Ni Based Catalysts: Effect of Support Type
title_full_unstemmed Reforming of Glycerol for Hydrogen Production over Ni Based Catalysts: Effect of Support Type
title_short Reforming of Glycerol for Hydrogen Production over Ni Based Catalysts: Effect of Support Type
title_sort reforming of glycerol for hydrogen production over ni based catalysts: effect of support type
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/17377/
http://umpir.ump.edu.my/id/eprint/17377/
http://umpir.ump.edu.my/id/eprint/17377/
http://umpir.ump.edu.my/id/eprint/17377/1/Reforming%20of%20glycerol%20for%20hydrogen%20production%20over%20Ni%20based%20catalysts-%20Effect%20of%20support%20type.pdf