Influence of PVDF/Pebax TFC Casting Temperature towards CO2/N2 Gas Separation

Objectives: A Thin Film Composite (TFC) membranes has been successfully synthesized via introducing casting temperature adjustment to counter the permeability-selectivity conflict. Methods: 15 wt% Polyvinylidene Fluoride (PVDF) was diluted in 85 wt% N-Methyl-2-Pyrrolidone (NMP) and cast on a glass p...

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Main Authors: Abdul Wahab, Mohammad, Sunarti, Abd Rahman
Format: Article
Language:English
Published: Informatics Publishing Limited 2017
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/17109/
http://umpir.ump.edu.my/id/eprint/17109/1/Influence%20of%20PVDF.pdf
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author Abdul Wahab, Mohammad
Sunarti, Abd Rahman
author_facet Abdul Wahab, Mohammad
Sunarti, Abd Rahman
author_sort Abdul Wahab, Mohammad
building UMP Institutional Repository
collection Online Access
description Objectives: A Thin Film Composite (TFC) membranes has been successfully synthesized via introducing casting temperature adjustment to counter the permeability-selectivity conflict. Methods: 15 wt% Polyvinylidene Fluoride (PVDF) was diluted in 85 wt% N-Methyl-2-Pyrrolidone (NMP) and cast on a glass plate at 40°C-80°C. To form the TFC, 3 wt% of Polyether block amides (Pebax 1657) was used as a coating layer on top of the PVDF substrate. Findings: The surface roughness of the samples cast at 60°C was measured to be 102.6 nm while the other is less than 100 nm and the CO2 and N2 flux was measured to be 749 and 13 barrer respectively with CO2 /N2 selectivity of 58.54. Application: The result has been plot on Robeson 1991 and it fall beyond the upper boundaries, indicate that the future of coating material and casting techniques can be further explored to maximize the limit of material capabilities.
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spelling ump-171092018-11-30T01:26:43Z http://umpir.ump.edu.my/id/eprint/17109/ Influence of PVDF/Pebax TFC Casting Temperature towards CO2/N2 Gas Separation Abdul Wahab, Mohammad Sunarti, Abd Rahman TP Chemical technology Objectives: A Thin Film Composite (TFC) membranes has been successfully synthesized via introducing casting temperature adjustment to counter the permeability-selectivity conflict. Methods: 15 wt% Polyvinylidene Fluoride (PVDF) was diluted in 85 wt% N-Methyl-2-Pyrrolidone (NMP) and cast on a glass plate at 40°C-80°C. To form the TFC, 3 wt% of Polyether block amides (Pebax 1657) was used as a coating layer on top of the PVDF substrate. Findings: The surface roughness of the samples cast at 60°C was measured to be 102.6 nm while the other is less than 100 nm and the CO2 and N2 flux was measured to be 749 and 13 barrer respectively with CO2 /N2 selectivity of 58.54. Application: The result has been plot on Robeson 1991 and it fall beyond the upper boundaries, indicate that the future of coating material and casting techniques can be further explored to maximize the limit of material capabilities. Informatics Publishing Limited 2017-01 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/17109/1/Influence%20of%20PVDF.pdf Abdul Wahab, Mohammad and Sunarti, Abd Rahman (2017) Influence of PVDF/Pebax TFC Casting Temperature towards CO2/N2 Gas Separation. Indian Journal of Science and Technology, 10 (2). pp. 1-5. ISSN 0974-6846 (Print); 0974-5645 (Online). (Published) http://dx.doi.org/10.17485/ijst%2F2017%2Fv10i2%2F110384 DOI: 10.17485/ijst/2017/v10i2/110384
spellingShingle TP Chemical technology
Abdul Wahab, Mohammad
Sunarti, Abd Rahman
Influence of PVDF/Pebax TFC Casting Temperature towards CO2/N2 Gas Separation
title Influence of PVDF/Pebax TFC Casting Temperature towards CO2/N2 Gas Separation
title_full Influence of PVDF/Pebax TFC Casting Temperature towards CO2/N2 Gas Separation
title_fullStr Influence of PVDF/Pebax TFC Casting Temperature towards CO2/N2 Gas Separation
title_full_unstemmed Influence of PVDF/Pebax TFC Casting Temperature towards CO2/N2 Gas Separation
title_short Influence of PVDF/Pebax TFC Casting Temperature towards CO2/N2 Gas Separation
title_sort influence of pvdf/pebax tfc casting temperature towards co2/n2 gas separation
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/17109/
http://umpir.ump.edu.my/id/eprint/17109/
http://umpir.ump.edu.my/id/eprint/17109/
http://umpir.ump.edu.my/id/eprint/17109/1/Influence%20of%20PVDF.pdf