Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions
Waste corn-cob cellulose supported poly(amidoxime) palladium nanoparticles (PdNs@PA) were prepared by the surface modification of waste corn-cob cellulose through graft co-polymerization and subsequent amidoximation. The supported nanoperticles showed high catalytic activity (45-400 mol ppm) toward...
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| Format: | Article |
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Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
2016
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| Online Access: | http://umpir.ump.edu.my/id/eprint/16925/ |
| _version_ | 1848820304485285888 |
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| author | Sultana, Tahnim Mandal, Bablu Hira Lutfor, M. R. Sarkar, Shaheen M. |
| author_facet | Sultana, Tahnim Mandal, Bablu Hira Lutfor, M. R. Sarkar, Shaheen M. |
| author_sort | Sultana, Tahnim |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Waste corn-cob cellulose supported poly(amidoxime) palladium
nanoparticles (PdNs@PA) were prepared by the surface modification of waste corn-cob cellulose through graft co-polymerization and subsequent amidoximation. The supported nanoperticles showed high catalytic activity (45-400 mol ppm) towards Suzuki-Miyaura cross-coupling of aryl bromides/chlorides with organoboronic acids to give the corresponding biaryl products up to 99% yield with high turnover number (TON) 19777 and turnover frequency (TOF) 4944 h-1. The PdNs@PA was easily recovered from the reaction mixture and reused several times without significant loss of its catalytic activity |
| first_indexed | 2025-11-15T02:07:19Z |
| format | Article |
| id | ump-16925 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| last_indexed | 2025-11-15T02:07:19Z |
| publishDate | 2016 |
| publisher | Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-169252019-09-10T02:29:00Z http://umpir.ump.edu.my/id/eprint/16925/ Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions Sultana, Tahnim Mandal, Bablu Hira Lutfor, M. R. Sarkar, Shaheen M. QD Chemistry Waste corn-cob cellulose supported poly(amidoxime) palladium nanoparticles (PdNs@PA) were prepared by the surface modification of waste corn-cob cellulose through graft co-polymerization and subsequent amidoximation. The supported nanoperticles showed high catalytic activity (45-400 mol ppm) towards Suzuki-Miyaura cross-coupling of aryl bromides/chlorides with organoboronic acids to give the corresponding biaryl products up to 99% yield with high turnover number (TON) 19777 and turnover frequency (TOF) 4944 h-1. The PdNs@PA was easily recovered from the reaction mixture and reused several times without significant loss of its catalytic activity Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 2016 Article PeerReviewed Sultana, Tahnim and Mandal, Bablu Hira and Lutfor, M. R. and Sarkar, Shaheen M. (2016) Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions. ChemistrySelect, 1 (13). pp. 4108-4112. ISSN 2365-6549. (Published) http://dx.doi.org/10.1002/slct.201600537 DOI: 10.1002/slct.201600537 |
| spellingShingle | QD Chemistry Sultana, Tahnim Mandal, Bablu Hira Lutfor, M. R. Sarkar, Shaheen M. Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions |
| title | Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions |
| title_full | Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions |
| title_fullStr | Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions |
| title_full_unstemmed | Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions |
| title_short | Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions |
| title_sort | bio-waste corn–cob cellulose supported poly(amidoxime) palladium nanoparticles for suzuki-miyaura cross-coupling reactions |
| topic | QD Chemistry |
| url | http://umpir.ump.edu.my/id/eprint/16925/ http://umpir.ump.edu.my/id/eprint/16925/ http://umpir.ump.edu.my/id/eprint/16925/ |