Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide
A Schiff base, (E)-4-Hydroxy-N -(2-methoxybenzylidene) benzohydrazide, (E4HB) had been synthesized in good yield by the acid-catalyzed condensation methoxybenzaldehyde and 4-hydroxybenzhydrazide in synthesized compound was elucidated by elemental analysis (CHN), FTIR, 13C-NMR and single crystal X-ra...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
AENSI Publishing
2016
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/16838/ http://umpir.ump.edu.my/id/eprint/16838/1/fkksa-2016-nhabdurahman-Synthesis%2C%20Spectra.pdf |
| _version_ | 1848820285099212800 |
|---|---|
| author | Rassem, Hesham H. A. Nour, A. H. |
| author_facet | Rassem, Hesham H. A. Nour, A. H. |
| author_sort | Rassem, Hesham H. A. |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | A Schiff base, (E)-4-Hydroxy-N -(2-methoxybenzylidene) benzohydrazide, (E4HB) had been synthesized in good yield by the acid-catalyzed condensation methoxybenzaldehyde and 4-hydroxybenzhydrazide in synthesized compound was elucidated by elemental analysis (CHN), FTIR, 13C-NMR and single crystal X-ray diffraction. E4HB crystallized in the crystal system with space group Z = 8, V = 2656.74(10) Å3 14.3951(3) Å, b = 8.7449(2) Å, c =21.1047(4) Å . The crystal structure of the compound is stabilized by intermolecular N1—H1N1….O2, O1 C13—H13A…O1 hydrogen bonds. A π—π interaction with centroid of 3.628 (6) A also occurs (Cg1 = C9— C14, -x, -y, -z). |
| first_indexed | 2025-11-15T02:07:01Z |
| format | Article |
| id | ump-16838 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:07:01Z |
| publishDate | 2016 |
| publisher | AENSI Publishing |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-168382018-01-24T04:09:52Z http://umpir.ump.edu.my/id/eprint/16838/ Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide Rassem, Hesham H. A. Nour, A. H. TP Chemical technology A Schiff base, (E)-4-Hydroxy-N -(2-methoxybenzylidene) benzohydrazide, (E4HB) had been synthesized in good yield by the acid-catalyzed condensation methoxybenzaldehyde and 4-hydroxybenzhydrazide in synthesized compound was elucidated by elemental analysis (CHN), FTIR, 13C-NMR and single crystal X-ray diffraction. E4HB crystallized in the crystal system with space group Z = 8, V = 2656.74(10) Å3 14.3951(3) Å, b = 8.7449(2) Å, c =21.1047(4) Å . The crystal structure of the compound is stabilized by intermolecular N1—H1N1….O2, O1 C13—H13A…O1 hydrogen bonds. A π—π interaction with centroid of 3.628 (6) A also occurs (Cg1 = C9— C14, -x, -y, -z). AENSI Publishing 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16838/1/fkksa-2016-nhabdurahman-Synthesis%2C%20Spectra.pdf Rassem, Hesham H. A. and Nour, A. H. (2016) Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide. Australian Journal of Basic and Applied Sciences, 10 (1). pp. 513-516. ISSN 1991-8178. (Published) http://ajbasweb.com/old/ajbas/2016/January/513-516.pdf |
| spellingShingle | TP Chemical technology Rassem, Hesham H. A. Nour, A. H. Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide |
| title | Synthesis, Spectral Characterization and Crystal Structure of
(E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide |
| title_full | Synthesis, Spectral Characterization and Crystal Structure of
(E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide |
| title_fullStr | Synthesis, Spectral Characterization and Crystal Structure of
(E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide |
| title_full_unstemmed | Synthesis, Spectral Characterization and Crystal Structure of
(E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide |
| title_short | Synthesis, Spectral Characterization and Crystal Structure of
(E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide |
| title_sort | synthesis, spectral characterization and crystal structure of
(e)-4- hydroxy-n -(2-methoxybenzylidene) benzohydrazide |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/16838/ http://umpir.ump.edu.my/id/eprint/16838/ http://umpir.ump.edu.my/id/eprint/16838/1/fkksa-2016-nhabdurahman-Synthesis%2C%20Spectra.pdf |