Transesterification of Waste Cooking Oil using Calcium Loaded on Deoiled Spent Bleaching Clay as a Solid Base Catalyst

Waste cooking oil has a high potential as a raw material in biodiesel production due to its abundant availability and cheapest among other feedstock. Hence transesterification reaction is carried out using waste cooking oil in this research. The objective of this study is to synthesize and character...

Full description

Bibliographic Details
Main Authors: Gaanty Pragas, Maniam, Rehan, Zainol Abidin, Mohd Hasbi, Ab. Rahim
Format: Article
Language:English
Published: Universitas Diponegoro 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/16830/
http://umpir.ump.edu.my/id/eprint/16830/1/33%29%202016%20BCREC%2011%282%29%2C%20176-181.pdf
_version_ 1848820283343896576
author Gaanty Pragas, Maniam
Rehan, Zainol Abidin
Mohd Hasbi, Ab. Rahim
author_facet Gaanty Pragas, Maniam
Rehan, Zainol Abidin
Mohd Hasbi, Ab. Rahim
author_sort Gaanty Pragas, Maniam
building UMP Institutional Repository
collection Online Access
description Waste cooking oil has a high potential as a raw material in biodiesel production due to its abundant availability and cheapest among other feedstock. Hence transesterification reaction is carried out using waste cooking oil in this research. The objective of this study is to synthesize and characterize the catalyst. On the other hand, deoiled spent bleaching clay impregnated with 40% CaO utilized as a catalyst. Optimization was carried out on methanol to oil molar ratio (6:1-24:1), catalyst loading (3-10 wt.%) and reaction duration (2-10 h). The catalyst of deoiled spent bleaching clay doped with 40% CaO was prepared by wet impregnation method and calcined at 500 °C for 4 hours. The catalyst shows high activity under optimum condition of 5 hours of reaction time, 12:1 of methanol to oil molar ratio with 7 wt.% of catalyst. The transesterification yields 84.7% methyl ester. Therefore, this catalyst has potential to be used in the transesterification of waste cooking oil in producing biodiesel due to its high activity.
first_indexed 2025-11-15T02:06:59Z
format Article
id ump-16830
institution Universiti Malaysia Pahang
institution_category Local University
language English
last_indexed 2025-11-15T02:06:59Z
publishDate 2016
publisher Universitas Diponegoro
recordtype eprints
repository_type Digital Repository
spelling ump-168302018-11-22T08:10:14Z http://umpir.ump.edu.my/id/eprint/16830/ Transesterification of Waste Cooking Oil using Calcium Loaded on Deoiled Spent Bleaching Clay as a Solid Base Catalyst Gaanty Pragas, Maniam Rehan, Zainol Abidin Mohd Hasbi, Ab. Rahim QD Chemistry Waste cooking oil has a high potential as a raw material in biodiesel production due to its abundant availability and cheapest among other feedstock. Hence transesterification reaction is carried out using waste cooking oil in this research. The objective of this study is to synthesize and characterize the catalyst. On the other hand, deoiled spent bleaching clay impregnated with 40% CaO utilized as a catalyst. Optimization was carried out on methanol to oil molar ratio (6:1-24:1), catalyst loading (3-10 wt.%) and reaction duration (2-10 h). The catalyst of deoiled spent bleaching clay doped with 40% CaO was prepared by wet impregnation method and calcined at 500 °C for 4 hours. The catalyst shows high activity under optimum condition of 5 hours of reaction time, 12:1 of methanol to oil molar ratio with 7 wt.% of catalyst. The transesterification yields 84.7% methyl ester. Therefore, this catalyst has potential to be used in the transesterification of waste cooking oil in producing biodiesel due to its high activity. Universitas Diponegoro 2016-08 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16830/1/33%29%202016%20BCREC%2011%282%29%2C%20176-181.pdf Gaanty Pragas, Maniam and Rehan, Zainol Abidin and Mohd Hasbi, Ab. Rahim (2016) Transesterification of Waste Cooking Oil using Calcium Loaded on Deoiled Spent Bleaching Clay as a Solid Base Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2). pp. 176-181. ISSN 1978-2993. (Published) http://dx.doi.org/10.9767/bcrec.11.2.548.176-181 doi: 10.9767/bcrec.11.2.548.176-181
spellingShingle QD Chemistry
Gaanty Pragas, Maniam
Rehan, Zainol Abidin
Mohd Hasbi, Ab. Rahim
Transesterification of Waste Cooking Oil using Calcium Loaded on Deoiled Spent Bleaching Clay as a Solid Base Catalyst
title Transesterification of Waste Cooking Oil using Calcium Loaded on Deoiled Spent Bleaching Clay as a Solid Base Catalyst
title_full Transesterification of Waste Cooking Oil using Calcium Loaded on Deoiled Spent Bleaching Clay as a Solid Base Catalyst
title_fullStr Transesterification of Waste Cooking Oil using Calcium Loaded on Deoiled Spent Bleaching Clay as a Solid Base Catalyst
title_full_unstemmed Transesterification of Waste Cooking Oil using Calcium Loaded on Deoiled Spent Bleaching Clay as a Solid Base Catalyst
title_short Transesterification of Waste Cooking Oil using Calcium Loaded on Deoiled Spent Bleaching Clay as a Solid Base Catalyst
title_sort transesterification of waste cooking oil using calcium loaded on deoiled spent bleaching clay as a solid base catalyst
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/16830/
http://umpir.ump.edu.my/id/eprint/16830/
http://umpir.ump.edu.my/id/eprint/16830/
http://umpir.ump.edu.my/id/eprint/16830/1/33%29%202016%20BCREC%2011%282%29%2C%20176-181.pdf