Methodized Depiction of Design of Experiment for Parameters Optimization in Synthesis of Poly(Nvinylcaprolactam) Thermoresponsive Polymers
Recently, common research on stimuli-responsive polymers comprising thermoresponsive polymers has been widely investigated. In this research study, the synthesis process parameters of poly(Nvinylcaprolactam) (PNVCL) a thermoresponsive polymer, has been engaged for optimization as an attempt. The res...
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IOP Publishing Ltd
2016
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| Online Access: | http://umpir.ump.edu.my/id/eprint/16760/ http://umpir.ump.edu.my/id/eprint/16760/1/Methodized%20Depiction%20of%20Design%20of%20Experiment%20for%20Parameters%20Optimization%20in%20Synthesis%20of%20Poly%28Nvinylcaprolactam%29%20Thermoresponsive%20Polymers.pdf |
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| author | Marwah Noori, Mohammed Kamal, Yusoh Jun Haslinda, Haji Shariffuddin |
| author_facet | Marwah Noori, Mohammed Kamal, Yusoh Jun Haslinda, Haji Shariffuddin |
| author_sort | Marwah Noori, Mohammed |
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| description | Recently, common research on stimuli-responsive polymers comprising thermoresponsive polymers has been widely investigated. In this research study, the synthesis process parameters of poly(Nvinylcaprolactam) (PNVCL) a thermoresponsive polymer, has been engaged for optimization as an attempt. The response surface methodology (RSM), has been employed in the identification of the elevated factors affecting on PNVCL production conversion (%) yield. Four independent process variables including monomer concentration, initiator concentration, polymerization temperature and time were studied. Various polymerization combination factors consist of a set of experiment runs were discussed using the Box–Behnken approach in Minitab 16. The study efficiently established the procedure and recompenses of RSM, for the estimation of process response. The optimum value for the most significant (temperature and time) variables for maximum PNVCL conversion (%) yield were obtained to be ~80 °C and 92.5 min, respectively. Monomer and initiator concentrations were hardly effective on the (%) yield. |
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| id | ump-16760 |
| institution | Universiti Malaysia Pahang |
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| language | English |
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| publishDate | 2016 |
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| spelling | ump-167602018-05-23T05:34:02Z http://umpir.ump.edu.my/id/eprint/16760/ Methodized Depiction of Design of Experiment for Parameters Optimization in Synthesis of Poly(Nvinylcaprolactam) Thermoresponsive Polymers Marwah Noori, Mohammed Kamal, Yusoh Jun Haslinda, Haji Shariffuddin TP Chemical technology Recently, common research on stimuli-responsive polymers comprising thermoresponsive polymers has been widely investigated. In this research study, the synthesis process parameters of poly(Nvinylcaprolactam) (PNVCL) a thermoresponsive polymer, has been engaged for optimization as an attempt. The response surface methodology (RSM), has been employed in the identification of the elevated factors affecting on PNVCL production conversion (%) yield. Four independent process variables including monomer concentration, initiator concentration, polymerization temperature and time were studied. Various polymerization combination factors consist of a set of experiment runs were discussed using the Box–Behnken approach in Minitab 16. The study efficiently established the procedure and recompenses of RSM, for the estimation of process response. The optimum value for the most significant (temperature and time) variables for maximum PNVCL conversion (%) yield were obtained to be ~80 °C and 92.5 min, respectively. Monomer and initiator concentrations were hardly effective on the (%) yield. IOP Publishing Ltd 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16760/1/Methodized%20Depiction%20of%20Design%20of%20Experiment%20for%20Parameters%20Optimization%20in%20Synthesis%20of%20Poly%28Nvinylcaprolactam%29%20Thermoresponsive%20Polymers.pdf Marwah Noori, Mohammed and Kamal, Yusoh and Jun Haslinda, Haji Shariffuddin (2016) Methodized Depiction of Design of Experiment for Parameters Optimization in Synthesis of Poly(Nvinylcaprolactam) Thermoresponsive Polymers. Materials Research Express, 3 (12). ISSN 2053-1591. (Published) https://doi.org/10.1088/2053-1591/3/12/125302 DOI: 10.1088/2053-1591/3/12/125302 |
| spellingShingle | TP Chemical technology Marwah Noori, Mohammed Kamal, Yusoh Jun Haslinda, Haji Shariffuddin Methodized Depiction of Design of Experiment for Parameters Optimization in Synthesis of Poly(Nvinylcaprolactam) Thermoresponsive Polymers |
| title | Methodized Depiction of Design of Experiment for Parameters Optimization in Synthesis of Poly(Nvinylcaprolactam) Thermoresponsive Polymers |
| title_full | Methodized Depiction of Design of Experiment for Parameters Optimization in Synthesis of Poly(Nvinylcaprolactam) Thermoresponsive Polymers |
| title_fullStr | Methodized Depiction of Design of Experiment for Parameters Optimization in Synthesis of Poly(Nvinylcaprolactam) Thermoresponsive Polymers |
| title_full_unstemmed | Methodized Depiction of Design of Experiment for Parameters Optimization in Synthesis of Poly(Nvinylcaprolactam) Thermoresponsive Polymers |
| title_short | Methodized Depiction of Design of Experiment for Parameters Optimization in Synthesis of Poly(Nvinylcaprolactam) Thermoresponsive Polymers |
| title_sort | methodized depiction of design of experiment for parameters optimization in synthesis of poly(nvinylcaprolactam) thermoresponsive polymers |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/16760/ http://umpir.ump.edu.my/id/eprint/16760/ http://umpir.ump.edu.my/id/eprint/16760/ http://umpir.ump.edu.my/id/eprint/16760/1/Methodized%20Depiction%20of%20Design%20of%20Experiment%20for%20Parameters%20Optimization%20in%20Synthesis%20of%20Poly%28Nvinylcaprolactam%29%20Thermoresponsive%20Polymers.pdf |