Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process
Hypercrosslinked microsphere hydrophilic polymer derived from 2-hydroxylethyl methacrylate (HEMA), ethylene glycol dimethacrylate (EDGMA), and vinyl benzene chloride (VBC) have been successfully synthesized using hypercrosslinking reaction chemistry. In this study, dispersion polymerization techniqu...
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| Format: | Article |
| Language: | English |
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Penerbit Universiti Malaysia Pahang
2016
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| Online Access: | http://umpir.ump.edu.my/id/eprint/16194/ http://umpir.ump.edu.my/id/eprint/16194/1/fkksa-2016-Development_of_Hypercrosslinked_Hydrophilic_Polymer1.pdf |
| _version_ | 1848820137159819264 |
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| author | Mohammad Zuhaili, Yahya Norhayati, Abdullah |
| author_facet | Mohammad Zuhaili, Yahya Norhayati, Abdullah |
| author_sort | Mohammad Zuhaili, Yahya |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Hypercrosslinked microsphere hydrophilic polymer derived from 2-hydroxylethyl methacrylate (HEMA), ethylene glycol dimethacrylate (EDGMA), and vinyl benzene chloride (VBC) have been successfully synthesized using hypercrosslinking reaction chemistry. In this study, dispersion polymerization technique has been used in order to develop precursor prior to hypercrosslinking reaction. Mixture of water/toluene system as a medium polymerization showed promising result with high yield and good quality of microsphere precursor and meanwhile increasing VBC content up to 5% based on monomer feed showed decreasing in quality of microsphere precursor in term of shape and size. FTIR result showed both EDGMA and VBC successfully incorporated into the precursor polymer backbone. After undergo hypercrosslinking reaction, hypercrosslinked microsphere polymer still can retain their original shape as before hypercrosslinking reaction with satisfy quality. From BET analysis, it showed slightly increment in specific surface area of hypercrosslinked microsphere polymer from 10.621 m2/g to 16.831 m2/g. |
| first_indexed | 2025-11-15T02:04:40Z |
| format | Article |
| id | ump-16194 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:04:40Z |
| publishDate | 2016 |
| publisher | Penerbit Universiti Malaysia Pahang |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-161942018-09-18T01:06:54Z http://umpir.ump.edu.my/id/eprint/16194/ Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process Mohammad Zuhaili, Yahya Norhayati, Abdullah TP Chemical technology Hypercrosslinked microsphere hydrophilic polymer derived from 2-hydroxylethyl methacrylate (HEMA), ethylene glycol dimethacrylate (EDGMA), and vinyl benzene chloride (VBC) have been successfully synthesized using hypercrosslinking reaction chemistry. In this study, dispersion polymerization technique has been used in order to develop precursor prior to hypercrosslinking reaction. Mixture of water/toluene system as a medium polymerization showed promising result with high yield and good quality of microsphere precursor and meanwhile increasing VBC content up to 5% based on monomer feed showed decreasing in quality of microsphere precursor in term of shape and size. FTIR result showed both EDGMA and VBC successfully incorporated into the precursor polymer backbone. After undergo hypercrosslinking reaction, hypercrosslinked microsphere polymer still can retain their original shape as before hypercrosslinking reaction with satisfy quality. From BET analysis, it showed slightly increment in specific surface area of hypercrosslinked microsphere polymer from 10.621 m2/g to 16.831 m2/g. Penerbit Universiti Malaysia Pahang 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16194/1/fkksa-2016-Development_of_Hypercrosslinked_Hydrophilic_Polymer1.pdf Mohammad Zuhaili, Yahya and Norhayati, Abdullah (2016) Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process. Journal of Malaysian Critical Metals, 1. pp. 31-39. ISSN 0128-2557. (Published) http://mycm.ump.edu.my/images/Vol12016/Development_of_Hypercrosslinked_Hydrophilic_Polymer_using_Dispersion_Polymerization_Technique_for_Separation_Process.pdf |
| spellingShingle | TP Chemical technology Mohammad Zuhaili, Yahya Norhayati, Abdullah Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process |
| title | Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process |
| title_full | Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process |
| title_fullStr | Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process |
| title_full_unstemmed | Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process |
| title_short | Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process |
| title_sort | development of hypercrosslinked hydrophilic polymer using dispersion polymerization technique for separation process |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/16194/ http://umpir.ump.edu.my/id/eprint/16194/ http://umpir.ump.edu.my/id/eprint/16194/1/fkksa-2016-Development_of_Hypercrosslinked_Hydrophilic_Polymer1.pdf |