Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions
A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was sythesized and the catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently allylic arylation of allylic ester with sodium tetraarylborates and arylboronic acids in ethanol at 60 °C temperature. Oustanding...
| Main Authors: | , , , |
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| Format: | Conference or Workshop Item |
| Language: | English |
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Universiti Malaysia Pahang
2016
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/15778/ http://umpir.ump.edu.my/id/eprint/15778/1/P090%20pg663-675.pdf |
| _version_ | 1848820038766690304 |
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| author | Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim |
| author_facet | Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim |
| author_sort | Mandal, Bablu Hira |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was sythesized and the catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently allylic arylation of allylic ester with sodium tetraarylborates and arylboronic acids in ethanol at 60 °C temperature. Oustanding yields of the corresponding products as well as significant reusability of the catalyst were obtained. The total turnover number(TON) and frequency(TOF) were 144615 and 9641 h–1 respectively. |
| first_indexed | 2025-11-15T02:03:06Z |
| format | Conference or Workshop Item |
| id | ump-15778 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:03:06Z |
| publishDate | 2016 |
| publisher | Universiti Malaysia Pahang |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-157782019-09-10T02:36:01Z http://umpir.ump.edu.my/id/eprint/15778/ Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim TA Engineering (General). Civil engineering (General) A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was sythesized and the catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently allylic arylation of allylic ester with sodium tetraarylborates and arylboronic acids in ethanol at 60 °C temperature. Oustanding yields of the corresponding products as well as significant reusability of the catalyst were obtained. The total turnover number(TON) and frequency(TOF) were 144615 and 9641 h–1 respectively. Universiti Malaysia Pahang 2016 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/15778/1/P090%20pg663-675.pdf Mandal, Bablu Hira and Sarkar, Shaheen M. and Lutfor, M. R. and Mohd Hasbi, Ab. Rahim (2016) Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions. In: Proceedings of The National Conference for Postgraduate Research (NCON-PGR 2016) , 24-25 September 2016 , Universiti Malaysia Pahang (UMP), Pekan, Pahang. pp. 663-675.. (Published) http://ee.ump.edu.my/ncon/wp-content/uploads/2016/10/Proceeding-NCON-PGR-2016.zip |
| spellingShingle | TA Engineering (General). Civil engineering (General) Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions |
| title | Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions |
| title_full | Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions |
| title_fullStr | Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions |
| title_full_unstemmed | Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions |
| title_short | Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions |
| title_sort | synthesis of kenaf cellulose supported highly active poly(amidoxime) palladium complex and its application as a reusable catalyst for allylic arylation reactions |
| topic | TA Engineering (General). Civil engineering (General) |
| url | http://umpir.ump.edu.my/id/eprint/15778/ http://umpir.ump.edu.my/id/eprint/15778/ http://umpir.ump.edu.my/id/eprint/15778/1/P090%20pg663-675.pdf |