Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions
A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was synthesized and characterized with FTIR, UV-Vis, FESEM, XPS and TEM analyses. The catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently the allylic arylation of allylic ester with sodium tetraarylborates...
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| Format: | Conference or Workshop Item |
| Language: | English |
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UTM Press
2016
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| Online Access: | http://umpir.ump.edu.my/id/eprint/15767/ http://umpir.ump.edu.my/id/eprint/15767/1/526-528.pdf |
| _version_ | 1848820035849551872 |
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| author | Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim |
| author_facet | Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim |
| author_sort | Mandal, Bablu Hira |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was synthesized and characterized with FTIR, UV-Vis, FESEM, XPS and TEM analyses. The catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently the allylic arylation of allylic ester with sodium tetraarylborates in ethanol at 60 °C temperature. Outstanding yields of the corresponding products as well as significant reusability of the catalyst were obtained. The total turnover number (TON) and frequency (TOF) were 144615 and 9641 h–1 respectively. |
| first_indexed | 2025-11-15T02:03:03Z |
| format | Conference or Workshop Item |
| id | ump-15767 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T02:03:03Z |
| publishDate | 2016 |
| publisher | UTM Press |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-157672019-09-10T02:35:17Z http://umpir.ump.edu.my/id/eprint/15767/ Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim QD Chemistry A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was synthesized and characterized with FTIR, UV-Vis, FESEM, XPS and TEM analyses. The catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently the allylic arylation of allylic ester with sodium tetraarylborates in ethanol at 60 °C temperature. Outstanding yields of the corresponding products as well as significant reusability of the catalyst were obtained. The total turnover number (TON) and frequency (TOF) were 144615 and 9641 h–1 respectively. UTM Press 2016 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/15767/1/526-528.pdf Mandal, Bablu Hira and Sarkar, Shaheen M. and Lutfor, M. R. and Mohd Hasbi, Ab. Rahim (2016) Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions. In: Proceedings of the 6th IGCESH2016: International Graduate Conference on Engineering, Science and Humanities , 15-17 August 2016 , Universiti Teknologi Malaysia, Johor. pp. 498-500.. ISBN 978-967-0194-67-7 (Published) http://sps.utm.my/igcesh2016/conference-proceedings/ |
| spellingShingle | QD Chemistry Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions |
| title | Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions |
| title_full | Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions |
| title_fullStr | Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions |
| title_full_unstemmed | Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions |
| title_short | Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions |
| title_sort | kenaf cellulose supported highly active poly(amidoxime) palladium complex as a reusable heterogeneous catalyst for allylic arylation reactions |
| topic | QD Chemistry |
| url | http://umpir.ump.edu.my/id/eprint/15767/ http://umpir.ump.edu.my/id/eprint/15767/ http://umpir.ump.edu.my/id/eprint/15767/1/526-528.pdf |