Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate

Glycerol carbonate can be readily synthesized from glycerol and urea catalyzed by PdZnO, PdSnO2, SnO2, and ZnO. The superior catalytic activity of ZnO over SnO2 is mainly due to basicity property. The incorporation of low metal loading of Pd on both SnO2 and ZnO produced higher yield of glycerol car...

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Main Authors: Anisah Sajidah, Haji Saud, Indran, Vidhyaa Paroo, Nazira, Mahmud, Mohd Hasbi, Ab. Rahim
Format: Article
Language:English
Published: Asian Online Journals 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/13486/
http://umpir.ump.edu.my/id/eprint/13486/1/Low%20Metal%20Loading%20Palladium%20Mixed-Oxides%20Catalyst%20for%20the%20Synthesis%20of%20Glycerol%20Carbonate.pdf
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author Anisah Sajidah, Haji Saud
Indran, Vidhyaa Paroo
Nazira, Mahmud
Mohd Hasbi, Ab. Rahim
author_facet Anisah Sajidah, Haji Saud
Indran, Vidhyaa Paroo
Nazira, Mahmud
Mohd Hasbi, Ab. Rahim
author_sort Anisah Sajidah, Haji Saud
building UMP Institutional Repository
collection Online Access
description Glycerol carbonate can be readily synthesized from glycerol and urea catalyzed by PdZnO, PdSnO2, SnO2, and ZnO. The superior catalytic activity of ZnO over SnO2 is mainly due to basicity property. The incorporation of low metal loading of Pd on both SnO2 and ZnO produced higher yield of glycerol carbonate to bulk material counterpart. In addition, the sol-gel technique was shown to have higher turn-over frequency (TOF) due to highly disperse Pd with small crystallite size.
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institution Universiti Malaysia Pahang
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publishDate 2016
publisher Asian Online Journals
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spelling ump-134862020-02-28T03:45:15Z http://umpir.ump.edu.my/id/eprint/13486/ Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate Anisah Sajidah, Haji Saud Indran, Vidhyaa Paroo Nazira, Mahmud Mohd Hasbi, Ab. Rahim QD Chemistry Glycerol carbonate can be readily synthesized from glycerol and urea catalyzed by PdZnO, PdSnO2, SnO2, and ZnO. The superior catalytic activity of ZnO over SnO2 is mainly due to basicity property. The incorporation of low metal loading of Pd on both SnO2 and ZnO produced higher yield of glycerol carbonate to bulk material counterpart. In addition, the sol-gel technique was shown to have higher turn-over frequency (TOF) due to highly disperse Pd with small crystallite size. Asian Online Journals 2016-02 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/13486/1/Low%20Metal%20Loading%20Palladium%20Mixed-Oxides%20Catalyst%20for%20the%20Synthesis%20of%20Glycerol%20Carbonate.pdf Anisah Sajidah, Haji Saud and Indran, Vidhyaa Paroo and Nazira, Mahmud and Mohd Hasbi, Ab. Rahim (2016) Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate. Asian Journal of Applied Sciences, 4 (1). pp. 181-189. ISSN 2321–0893. (Published) http://www.ajouronline.com/index.php?journal=AJAS&page=article&op=view&path%5B%5D=3107
spellingShingle QD Chemistry
Anisah Sajidah, Haji Saud
Indran, Vidhyaa Paroo
Nazira, Mahmud
Mohd Hasbi, Ab. Rahim
Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate
title Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate
title_full Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate
title_fullStr Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate
title_full_unstemmed Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate
title_short Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate
title_sort low metal loading palladium mixed-oxides catalyst for the synthesis of glycerol carbonate
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/13486/
http://umpir.ump.edu.my/id/eprint/13486/
http://umpir.ump.edu.my/id/eprint/13486/1/Low%20Metal%20Loading%20Palladium%20Mixed-Oxides%20Catalyst%20for%20the%20Synthesis%20of%20Glycerol%20Carbonate.pdf