Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions
An MCM-48 supported 2-pyridinylmethanimine Pd-catalyst was found to be a highly efficient catalyst in the Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under aqueous reaction conditions. The catalyst efficiently promoted these coupling reactions...
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| Format: | Article |
| Language: | English |
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Royal Society of Chemistry
2015
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| Online Access: | http://umpir.ump.edu.my/id/eprint/12769/ http://umpir.ump.edu.my/id/eprint/12769/1/RSC%20Adv%20MCM-48.pdf |
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| author | Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff |
| author_facet | Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff |
| author_sort | Sarkar, Shaheen M. |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | An MCM-48 supported 2-pyridinylmethanimine Pd-catalyst was found to be a highly efficient catalyst in the
Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides
under aqueous reaction conditions. The catalyst efficiently promoted these coupling reactions with ppm
levels of palladium to afford the corresponding coupling products in up to 98% yield. The supported Pdcatalyst
was readily recovered and reused several times without significant loss of its catalytic activity. |
| first_indexed | 2025-11-15T01:51:32Z |
| format | Article |
| id | ump-12769 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T01:51:32Z |
| publishDate | 2015 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-127692018-02-14T04:08:29Z http://umpir.ump.edu.my/id/eprint/12769/ Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff QD Chemistry An MCM-48 supported 2-pyridinylmethanimine Pd-catalyst was found to be a highly efficient catalyst in the Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under aqueous reaction conditions. The catalyst efficiently promoted these coupling reactions with ppm levels of palladium to afford the corresponding coupling products in up to 98% yield. The supported Pdcatalyst was readily recovered and reused several times without significant loss of its catalytic activity. Royal Society of Chemistry 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/12769/1/RSC%20Adv%20MCM-48.pdf Sarkar, Shaheen M. and Lutfor, M. R. and M. M., Yusoff (2015) Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions. RSC Advances, 5 (25). pp. 19630-19637. ISSN 2046-2069. (Published) http://dx.doi.org/10.1039/C4RA16677A DOI: 10.1039/C4RA16677A |
| spellingShingle | QD Chemistry Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions |
| title | Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions |
| title_full | Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions |
| title_fullStr | Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions |
| title_full_unstemmed | Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions |
| title_short | Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions |
| title_sort | pyridinyl functionalized mcm-48 supported highly active heterogeneous palladium catalyst for crosscoupling reactions |
| topic | QD Chemistry |
| url | http://umpir.ump.edu.my/id/eprint/12769/ http://umpir.ump.edu.my/id/eprint/12769/ http://umpir.ump.edu.my/id/eprint/12769/ http://umpir.ump.edu.my/id/eprint/12769/1/RSC%20Adv%20MCM-48.pdf |