Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex
SBA-16 supported 1,2-diaminocyclohexane Pd-complex (100–500 mol ppm of Pd) was found to be an efficient catalyst in the palladium-catalyzed Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under mild reaction conditions. The Pd-complex efficiently pr...
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| Format: | Article |
| Language: | English |
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Royal Society of Chemistry
2015
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/12768/ http://umpir.ump.edu.my/id/eprint/12768/1/New%20J%20Chem.pdf |
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| author | Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff |
| author_facet | Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff |
| author_sort | Sarkar, Shaheen M. |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | SBA-16 supported 1,2-diaminocyclohexane Pd-complex (100–500 mol ppm of Pd) was found to be an efficient catalyst in the palladium-catalyzed Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under mild reaction conditions. The Pd-complex efficiently promoted all of these coupling reactions with appropriate coupling partners to afford the corresponding
coupling products with almost quantitative yield. The supported Pd-complex was readily recovered and
used five times without a significant loss of its catalytic activity. |
| first_indexed | 2025-11-15T01:51:31Z |
| format | Article |
| id | ump-12768 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T01:51:31Z |
| publishDate | 2015 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-127682018-02-14T04:00:41Z http://umpir.ump.edu.my/id/eprint/12768/ Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff QD Chemistry SBA-16 supported 1,2-diaminocyclohexane Pd-complex (100–500 mol ppm of Pd) was found to be an efficient catalyst in the palladium-catalyzed Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under mild reaction conditions. The Pd-complex efficiently promoted all of these coupling reactions with appropriate coupling partners to afford the corresponding coupling products with almost quantitative yield. The supported Pd-complex was readily recovered and used five times without a significant loss of its catalytic activity. Royal Society of Chemistry 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/12768/1/New%20J%20Chem.pdf Sarkar, Shaheen M. and Lutfor, M. R. and M. M., Yusoff (2015) Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex. New Journal of Chemistry, 39 (5). pp. 3564-3570. ISSN 1144-0546. (Published) http://dx.doi.org/10.1039/C4NJ02319F DOI: 10.1039/C4NJ02319F |
| spellingShingle | QD Chemistry Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
| title | Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
| title_full | Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
| title_fullStr | Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
| title_full_unstemmed | Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
| title_short | Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
| title_sort | heck, suzuki and sonogashira cross-coupling reactions using ppm level of sba-16 supported pd-complex |
| topic | QD Chemistry |
| url | http://umpir.ump.edu.my/id/eprint/12768/ http://umpir.ump.edu.my/id/eprint/12768/ http://umpir.ump.edu.my/id/eprint/12768/ http://umpir.ump.edu.my/id/eprint/12768/1/New%20J%20Chem.pdf |