Production of CO-rich Hydrogen from Methane Dry Reforming Over Lanthania-Supported Cobalt Catalyst: Kinetic and Mechanistic Studies
In this study, the production of CO-rich hydrogen from methane dry reforming over lanthania-supported Co catalyst was investigated. The Co/La2O3 catalyst was synthesized via wet-impregnation method and characterized using instrument techniques such as TGA, FTIR, XRD, FESEM-EDX and N2 adsorption-des...
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| Format: | Article |
| Language: | English English |
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Elsevier
2016
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| Online Access: | http://umpir.ump.edu.my/id/eprint/11901/ http://umpir.ump.edu.my/id/eprint/11901/1/ayodele2016.pdf http://umpir.ump.edu.my/id/eprint/11901/7/Production%20of%20CO-rich%20Hydrogen%20from%20Methane%20Dry%20Reforming%20Over%20Lanthania-Supported%20Cobalt%20Catalyst-%20Kinetic%20and%20Mechanistic%20Studies.pdf |
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| author | Ayodele, Bamidele V. Khan, Maksudur R. Lam, Su Shiung Cheng, C. K. |
| author_facet | Ayodele, Bamidele V. Khan, Maksudur R. Lam, Su Shiung Cheng, C. K. |
| author_sort | Ayodele, Bamidele V. |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | In this study, the production of CO-rich hydrogen from methane dry reforming over lanthania-supported Co catalyst was investigated. The Co/La2O3 catalyst was synthesized
via wet-impregnation method and characterized using instrument techniques such as TGA, FTIR, XRD, FESEM-EDX and N2 adsorption-desorption analysis. The catalytic activity of the Co/La2O3 catalyst tested in a fixed bed stainless steel reactor yielded highest CH4 and CO2 conversion of 50% and 60% respectively at 1023 K and feed ratio of 1.0. The methane dry reforming reaction gave highest H2 and CO yield of 45% and 58% respectively. Furthermore, kinetics and mechanistic behavior of the La2O3 supported Co catalyst in
methane dry reforming reaction was investigated as a function of temperature and partial pressure of reactants (CH4 and CO2). The experimental data obtained from the kinetics measurements were fitted using the empirical power-law rate expression, as well as six different Langmuir-Hinshelwood kinetics models. The six models were then statistically and thermodynamically discriminated. Consequently, the Langmuir-Hinshelwood kinetics model (dual-site associative adsorption of both CH4 and CO2 with bimolecular surface reaction) was adjudged the best representative model. Activation energy values of 96.44 and 98.11 kJ mol�1 were obtained for the CH4 consumptions from the power-law and Langmuir-Hinshelwood models, respectively. A lower activation energy of circa 72 kJ mol�1
obtained for CO2 consumption showed that the rate of consumption of CO2 consumption was speedier than CH4. |
| first_indexed | 2025-11-15T01:48:12Z |
| format | Article |
| id | ump-11901 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T01:48:12Z |
| publishDate | 2016 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-119012019-08-28T03:27:11Z http://umpir.ump.edu.my/id/eprint/11901/ Production of CO-rich Hydrogen from Methane Dry Reforming Over Lanthania-Supported Cobalt Catalyst: Kinetic and Mechanistic Studies Ayodele, Bamidele V. Khan, Maksudur R. Lam, Su Shiung Cheng, C. K. TP Chemical technology In this study, the production of CO-rich hydrogen from methane dry reforming over lanthania-supported Co catalyst was investigated. The Co/La2O3 catalyst was synthesized via wet-impregnation method and characterized using instrument techniques such as TGA, FTIR, XRD, FESEM-EDX and N2 adsorption-desorption analysis. The catalytic activity of the Co/La2O3 catalyst tested in a fixed bed stainless steel reactor yielded highest CH4 and CO2 conversion of 50% and 60% respectively at 1023 K and feed ratio of 1.0. The methane dry reforming reaction gave highest H2 and CO yield of 45% and 58% respectively. Furthermore, kinetics and mechanistic behavior of the La2O3 supported Co catalyst in methane dry reforming reaction was investigated as a function of temperature and partial pressure of reactants (CH4 and CO2). The experimental data obtained from the kinetics measurements were fitted using the empirical power-law rate expression, as well as six different Langmuir-Hinshelwood kinetics models. The six models were then statistically and thermodynamically discriminated. Consequently, the Langmuir-Hinshelwood kinetics model (dual-site associative adsorption of both CH4 and CO2 with bimolecular surface reaction) was adjudged the best representative model. Activation energy values of 96.44 and 98.11 kJ mol�1 were obtained for the CH4 consumptions from the power-law and Langmuir-Hinshelwood models, respectively. A lower activation energy of circa 72 kJ mol�1 obtained for CO2 consumption showed that the rate of consumption of CO2 consumption was speedier than CH4. Elsevier 2016-02-10 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11901/1/ayodele2016.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/11901/7/Production%20of%20CO-rich%20Hydrogen%20from%20Methane%20Dry%20Reforming%20Over%20Lanthania-Supported%20Cobalt%20Catalyst-%20Kinetic%20and%20Mechanistic%20Studies.pdf Ayodele, Bamidele V. and Khan, Maksudur R. and Lam, Su Shiung and Cheng, C. K. (2016) Production of CO-rich Hydrogen from Methane Dry Reforming Over Lanthania-Supported Cobalt Catalyst: Kinetic and Mechanistic Studies. International Journal of Hydrogen Energy, 41 (8). pp. 4603-4615. ISSN 0360-3199. (Published) http://dx.doi.org/10.1016/j.ijhydene.2016.01.091 DOI: 10.1016/j.ijhydene.2016.01.091 |
| spellingShingle | TP Chemical technology Ayodele, Bamidele V. Khan, Maksudur R. Lam, Su Shiung Cheng, C. K. Production of CO-rich Hydrogen from Methane Dry Reforming Over Lanthania-Supported Cobalt Catalyst: Kinetic and Mechanistic Studies |
| title | Production of CO-rich Hydrogen from Methane Dry Reforming Over Lanthania-Supported Cobalt Catalyst: Kinetic and Mechanistic Studies |
| title_full | Production of CO-rich Hydrogen from Methane Dry Reforming Over Lanthania-Supported Cobalt Catalyst: Kinetic and Mechanistic Studies |
| title_fullStr | Production of CO-rich Hydrogen from Methane Dry Reforming Over Lanthania-Supported Cobalt Catalyst: Kinetic and Mechanistic Studies |
| title_full_unstemmed | Production of CO-rich Hydrogen from Methane Dry Reforming Over Lanthania-Supported Cobalt Catalyst: Kinetic and Mechanistic Studies |
| title_short | Production of CO-rich Hydrogen from Methane Dry Reforming Over Lanthania-Supported Cobalt Catalyst: Kinetic and Mechanistic Studies |
| title_sort | production of co-rich hydrogen from methane dry reforming over lanthania-supported cobalt catalyst: kinetic and mechanistic studies |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/11901/ http://umpir.ump.edu.my/id/eprint/11901/ http://umpir.ump.edu.my/id/eprint/11901/ http://umpir.ump.edu.my/id/eprint/11901/1/ayodele2016.pdf http://umpir.ump.edu.my/id/eprint/11901/7/Production%20of%20CO-rich%20Hydrogen%20from%20Methane%20Dry%20Reforming%20Over%20Lanthania-Supported%20Cobalt%20Catalyst-%20Kinetic%20and%20Mechanistic%20Studies.pdf |