CeO2-TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol

The performance of CeO2-TiO2 photocatalyst for the photocatalytic reduction of CO2 into methanol was studied under visible light irradiation. The as-prepared catalysts were characterized for their structural, textural and optical properties using X-ray diffraction (XRD), field emission scanning elec...

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Main Authors: Hamidah, Abdullah, Khan, Maksudur R., Manoj, Pudukudya, Zahira, Yaakob, Nur Aminatulmimi, Ismail
Format: Article
Language:English
Published: Elsevier Ltd 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/11571/
http://umpir.ump.edu.my/id/eprint/11571/1/Ceo2-Tio2%20as%20a%20Visible%20Light%20Active%20Catalyst%20for%20the%20Photoreduction%20of%20Co2%20to%20Methanol.pdf
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author Hamidah, Abdullah
Khan, Maksudur R.
Manoj, Pudukudya
Zahira, Yaakob
Nur Aminatulmimi, Ismail
author_facet Hamidah, Abdullah
Khan, Maksudur R.
Manoj, Pudukudya
Zahira, Yaakob
Nur Aminatulmimi, Ismail
author_sort Hamidah, Abdullah
building UMP Institutional Repository
collection Online Access
description The performance of CeO2-TiO2 photocatalyst for the photocatalytic reduction of CO2 into methanol was studied under visible light irradiation. The as-prepared catalysts were characterized for their structural, textural and optical properties using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), nitrogen physisorption analysis, UV-vis spectroscopy and photoluminescence (PL) spectroscopy. The characterization results indicated that the presence of CeO2 stabilized the anatase phase of TiO2, decreased its crystallite size, increased the surface area, reduced the band gap energy and lowered the rate of electron-hole pair recombination. The CeO2-TiO2 photocatalyst showed an increased methanol yield of 18.6 µmol/g under visible light irradiation, compared to the bare TiO2 (6.0 µmol/g).
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institution Universiti Malaysia Pahang
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publishDate 2015
publisher Elsevier Ltd
recordtype eprints
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spelling ump-115712018-03-27T04:18:13Z http://umpir.ump.edu.my/id/eprint/11571/ CeO2-TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol Hamidah, Abdullah Khan, Maksudur R. Manoj, Pudukudya Zahira, Yaakob Nur Aminatulmimi, Ismail TP Chemical technology The performance of CeO2-TiO2 photocatalyst for the photocatalytic reduction of CO2 into methanol was studied under visible light irradiation. The as-prepared catalysts were characterized for their structural, textural and optical properties using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), nitrogen physisorption analysis, UV-vis spectroscopy and photoluminescence (PL) spectroscopy. The characterization results indicated that the presence of CeO2 stabilized the anatase phase of TiO2, decreased its crystallite size, increased the surface area, reduced the band gap energy and lowered the rate of electron-hole pair recombination. The CeO2-TiO2 photocatalyst showed an increased methanol yield of 18.6 µmol/g under visible light irradiation, compared to the bare TiO2 (6.0 µmol/g). Elsevier Ltd 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11571/1/Ceo2-Tio2%20as%20a%20Visible%20Light%20Active%20Catalyst%20for%20the%20Photoreduction%20of%20Co2%20to%20Methanol.pdf Hamidah, Abdullah and Khan, Maksudur R. and Manoj, Pudukudya and Zahira, Yaakob and Nur Aminatulmimi, Ismail (2015) CeO2-TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol. Journal of Rare Earths, 33 (11). pp. 1155-1161. ISSN 1002-0721. (Published) http://dx.doi.org/10.1016/S1002-0721(14)60540-8 doi:10.1016/S1002-0721(14)60540-8
spellingShingle TP Chemical technology
Hamidah, Abdullah
Khan, Maksudur R.
Manoj, Pudukudya
Zahira, Yaakob
Nur Aminatulmimi, Ismail
CeO2-TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol
title CeO2-TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol
title_full CeO2-TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol
title_fullStr CeO2-TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol
title_full_unstemmed CeO2-TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol
title_short CeO2-TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol
title_sort ceo2-tio2 as a visible light active catalyst for the photoreduction of co2 to methanol
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/11571/
http://umpir.ump.edu.my/id/eprint/11571/
http://umpir.ump.edu.my/id/eprint/11571/
http://umpir.ump.edu.my/id/eprint/11571/1/Ceo2-Tio2%20as%20a%20Visible%20Light%20Active%20Catalyst%20for%20the%20Photoreduction%20of%20Co2%20to%20Methanol.pdf