Characterization of Multiwalled Carbon Nanotube Filled, Palm-Oil-Based Polyalkyds: Effects of Loading and In Situ Reaction

In this study, the contribution of multiwalled carbon nanotubes (MWCNTs) was studied for the evaluation of the performances of polyalkyd-based films produced from dehydrated palm oil. Initially, different percentages of MWCNTs, including 0.5, 1.0, and 1.5 wt %, were considered for loading into the r...

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Main Authors: M. R., Islam, Beg, M. D. H., Saidatul Shima, Jamari
Format: Article
Language:English
Published: John Wiley & Sons, Inc. 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/11251/
http://umpir.ump.edu.my/id/eprint/11251/1/Characterization%20of%20Multiwalled%20Carbon%20Nanotube%20Filled%2C%20Palm-Oil-Based%20Polyalkyds-%20Effects%20of%20Loading%20and%20In%20Situ%20Reaction.pdf
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author M. R., Islam
Beg, M. D. H.
Saidatul Shima, Jamari
author_facet M. R., Islam
Beg, M. D. H.
Saidatul Shima, Jamari
author_sort M. R., Islam
building UMP Institutional Repository
collection Online Access
description In this study, the contribution of multiwalled carbon nanotubes (MWCNTs) was studied for the evaluation of the performances of polyalkyd-based films produced from dehydrated palm oil. Initially, different percentages of MWCNTs, including 0.5, 1.0, and 1.5 wt %, were considered for loading into the resin with the help of sonication. Additionally, a 1.0 wt % loading was considered for in situ conditions during the esterification process to achieve better dispersion and obtain improved properties of the film. The loading was evaluated by different performance tests, such as those of tensile, elongation, pencil hardness, swelling ratio, gel content, wettability, chemical resistivity, adhesion, and surface morphology. The results of mechanical testing showed that the addition of 1.0 wt % MWCNTs enhanced the tensile strength by 50%, whereas in situ conditions were found to be favorable for significantly improving the tensile strength by 75%. Moreover, the wettability, surface morphology, and thermal properties were also found to be in favor of in situ conditions for the dispersion of the MWCNTs
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spelling ump-112512017-08-22T07:43:53Z http://umpir.ump.edu.my/id/eprint/11251/ Characterization of Multiwalled Carbon Nanotube Filled, Palm-Oil-Based Polyalkyds: Effects of Loading and In Situ Reaction M. R., Islam Beg, M. D. H. Saidatul Shima, Jamari TP Chemical technology In this study, the contribution of multiwalled carbon nanotubes (MWCNTs) was studied for the evaluation of the performances of polyalkyd-based films produced from dehydrated palm oil. Initially, different percentages of MWCNTs, including 0.5, 1.0, and 1.5 wt %, were considered for loading into the resin with the help of sonication. Additionally, a 1.0 wt % loading was considered for in situ conditions during the esterification process to achieve better dispersion and obtain improved properties of the film. The loading was evaluated by different performance tests, such as those of tensile, elongation, pencil hardness, swelling ratio, gel content, wettability, chemical resistivity, adhesion, and surface morphology. The results of mechanical testing showed that the addition of 1.0 wt % MWCNTs enhanced the tensile strength by 50%, whereas in situ conditions were found to be favorable for significantly improving the tensile strength by 75%. Moreover, the wettability, surface morphology, and thermal properties were also found to be in favor of in situ conditions for the dispersion of the MWCNTs John Wiley & Sons, Inc. 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11251/1/Characterization%20of%20Multiwalled%20Carbon%20Nanotube%20Filled%2C%20Palm-Oil-Based%20Polyalkyds-%20Effects%20of%20Loading%20and%20In%20Situ%20Reaction.pdf M. R., Islam and Beg, M. D. H. and Saidatul Shima, Jamari (2015) Characterization of Multiwalled Carbon Nanotube Filled, Palm-Oil-Based Polyalkyds: Effects of Loading and In Situ Reaction. Journal of Applied Polymer Science, 133 (5). p. 42934. ISSN 1097-4628. (Published) http://dx.doi.org/10.1002/app.42934 DOI: 10.1002/app.42934
spellingShingle TP Chemical technology
M. R., Islam
Beg, M. D. H.
Saidatul Shima, Jamari
Characterization of Multiwalled Carbon Nanotube Filled, Palm-Oil-Based Polyalkyds: Effects of Loading and In Situ Reaction
title Characterization of Multiwalled Carbon Nanotube Filled, Palm-Oil-Based Polyalkyds: Effects of Loading and In Situ Reaction
title_full Characterization of Multiwalled Carbon Nanotube Filled, Palm-Oil-Based Polyalkyds: Effects of Loading and In Situ Reaction
title_fullStr Characterization of Multiwalled Carbon Nanotube Filled, Palm-Oil-Based Polyalkyds: Effects of Loading and In Situ Reaction
title_full_unstemmed Characterization of Multiwalled Carbon Nanotube Filled, Palm-Oil-Based Polyalkyds: Effects of Loading and In Situ Reaction
title_short Characterization of Multiwalled Carbon Nanotube Filled, Palm-Oil-Based Polyalkyds: Effects of Loading and In Situ Reaction
title_sort characterization of multiwalled carbon nanotube filled, palm-oil-based polyalkyds: effects of loading and in situ reaction
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/11251/
http://umpir.ump.edu.my/id/eprint/11251/
http://umpir.ump.edu.my/id/eprint/11251/
http://umpir.ump.edu.my/id/eprint/11251/1/Characterization%20of%20Multiwalled%20Carbon%20Nanotube%20Filled%2C%20Palm-Oil-Based%20Polyalkyds-%20Effects%20of%20Loading%20and%20In%20Situ%20Reaction.pdf