Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles
Palm oil based alkyd resin was synthesized by an alcoholysis–polyesterification process over a base catalyst tailored by copper oxide (CuO) nanoparticles. In the present paper we synthesized CuO sol in glycerol and subsequently used it in alkyd resin synthesis. The formation of the alkyd resin was c...
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| Language: | English |
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Royal Society of Chemistry
2015
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| Online Access: | http://umpir.ump.edu.my/id/eprint/11128/ http://umpir.ump.edu.my/id/eprint/11128/1/Tailoring%20Base%20Catalyzed%20Synthesis%20of%20Palm%20Oil%20Based%20Alkyd%20Resin%20Through%20CuO%20Nanoparticles.pdf |
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| author | Ong, Huei Ruey Khan, Maksudur R. Ridzuan, Ramli Rahman, Md. Wasikur R. M., Yunus |
| author_facet | Ong, Huei Ruey Khan, Maksudur R. Ridzuan, Ramli Rahman, Md. Wasikur R. M., Yunus |
| author_sort | Ong, Huei Ruey |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Palm oil based alkyd resin was synthesized by an alcoholysis–polyesterification process over a base catalyst tailored by copper oxide (CuO) nanoparticles. In the present paper we synthesized CuO sol in glycerol and subsequently used it in alkyd resin synthesis. The formation of the alkyd resin was confirmed by FTIR, Raman, 1H-NMR and 13C-NMR methods and its molecular weight was determined by gel permeation chromatography (GPC). The antimicrobial activity of the pseudo-homogeneous additive was determined via the Kirby–Bauer method and the stability of the CuO was determined by X-ray absorption near edge structure spectroscopy (XANES). The addition of CuO nano-sol to the conventional homogeneous base catalyzed system explored a new catalytic route for the preparation of bioresin from vegetable oil, reducing the reaction time as well as adding antimicrobial properties to the resin. |
| first_indexed | 2025-11-15T01:45:30Z |
| format | Article |
| id | ump-11128 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T01:45:30Z |
| publishDate | 2015 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-111282018-01-15T02:04:47Z http://umpir.ump.edu.my/id/eprint/11128/ Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles Ong, Huei Ruey Khan, Maksudur R. Ridzuan, Ramli Rahman, Md. Wasikur R. M., Yunus TP Chemical technology Palm oil based alkyd resin was synthesized by an alcoholysis–polyesterification process over a base catalyst tailored by copper oxide (CuO) nanoparticles. In the present paper we synthesized CuO sol in glycerol and subsequently used it in alkyd resin synthesis. The formation of the alkyd resin was confirmed by FTIR, Raman, 1H-NMR and 13C-NMR methods and its molecular weight was determined by gel permeation chromatography (GPC). The antimicrobial activity of the pseudo-homogeneous additive was determined via the Kirby–Bauer method and the stability of the CuO was determined by X-ray absorption near edge structure spectroscopy (XANES). The addition of CuO nano-sol to the conventional homogeneous base catalyzed system explored a new catalytic route for the preparation of bioresin from vegetable oil, reducing the reaction time as well as adding antimicrobial properties to the resin. Royal Society of Chemistry 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11128/1/Tailoring%20Base%20Catalyzed%20Synthesis%20of%20Palm%20Oil%20Based%20Alkyd%20Resin%20Through%20CuO%20Nanoparticles.pdf Ong, Huei Ruey and Khan, Maksudur R. and Ridzuan, Ramli and Rahman, Md. Wasikur and R. M., Yunus (2015) Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles. RSC Advances, 5 (116). pp. 95894-95902. ISSN 2046-2069. (Published) http://dx.doi.org/10.1039/C5RA19575F DOI: 10.1039/C5RA19575F |
| spellingShingle | TP Chemical technology Ong, Huei Ruey Khan, Maksudur R. Ridzuan, Ramli Rahman, Md. Wasikur R. M., Yunus Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles |
| title | Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles |
| title_full | Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles |
| title_fullStr | Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles |
| title_full_unstemmed | Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles |
| title_short | Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles |
| title_sort | tailoring base catalyzed synthesis of palm oil based alkyd resin through cuo nanoparticles |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/11128/ http://umpir.ump.edu.my/id/eprint/11128/ http://umpir.ump.edu.my/id/eprint/11128/ http://umpir.ump.edu.my/id/eprint/11128/1/Tailoring%20Base%20Catalyzed%20Synthesis%20of%20Palm%20Oil%20Based%20Alkyd%20Resin%20Through%20CuO%20Nanoparticles.pdf |