Synthesis and characterization of Mn-doped CdSe quantum dots via inverse micelle technique / Nor Aliya Hamizi

Various sizes of manganese-doped cadmium selenide quantum dots (Mn-doped CdSe QDs) synthesized using inverse Micelle technique with organic solvent and surfactant possesses zinc blende structure with physical size ranging from 3 to 14 nm and crystallite size 2.46 to 5.46 nm respectively for 0 to 90...

Full description

Bibliographic Details
Main Author: Nor Aliya, Hamizi
Format: Thesis
Published: 2017
Subjects:
Online Access:http://studentsrepo.um.edu.my/7428/
http://studentsrepo.um.edu.my/7428/1/All.pdf
http://studentsrepo.um.edu.my/7428/6/aliya.pdf
_version_ 1848773389476429824
author Nor Aliya, Hamizi
author_facet Nor Aliya, Hamizi
author_sort Nor Aliya, Hamizi
building UM Research Repository
collection Online Access
description Various sizes of manganese-doped cadmium selenide quantum dots (Mn-doped CdSe QDs) synthesized using inverse Micelle technique with organic solvent and surfactant possesses zinc blende structure with physical size ranging from 3 to 14 nm and crystallite size 2.46 to 5.46 nm respectively for 0 to 90 mins samples with narrow size distribution. Mn-doped CdSe QDs observed to growth larger QDs compared to pure CdSe QDs at significantly same reaction times. The lattice parameter compressed with QDs sizes growth due to the introduction of lattice strain due to the incorporation of Mn atoms into CdSe QDs lattice. The Mn-doped CdSe QDs shows a slight blue-shift on absorption and emission spectra’s compared to pure CdSe even though is possessed larger QDs. The band gap structure modification prominently affected by the lattice strain were transition of Stoke`s, Rayleigh to anti-Stoke`s shifts observed as the Mn doped CdSe QDs size growth. The typical red-shift of absorption and emission wavelength observed with growth of QDs sizes. The role of oleic acid acid as a surfactant and capping agent shows in FTIR spectra. The lattice strain tailored the binding energy between the ion prominently on the surface of the QDs with growth of QDs sizes.
first_indexed 2025-11-14T13:41:38Z
format Thesis
id um-7428
institution University Malaya
institution_category Local University
last_indexed 2025-11-14T13:41:38Z
publishDate 2017
recordtype eprints
repository_type Digital Repository
spelling um-74282020-06-30T00:03:27Z Synthesis and characterization of Mn-doped CdSe quantum dots via inverse micelle technique / Nor Aliya Hamizi Nor Aliya, Hamizi TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery Various sizes of manganese-doped cadmium selenide quantum dots (Mn-doped CdSe QDs) synthesized using inverse Micelle technique with organic solvent and surfactant possesses zinc blende structure with physical size ranging from 3 to 14 nm and crystallite size 2.46 to 5.46 nm respectively for 0 to 90 mins samples with narrow size distribution. Mn-doped CdSe QDs observed to growth larger QDs compared to pure CdSe QDs at significantly same reaction times. The lattice parameter compressed with QDs sizes growth due to the introduction of lattice strain due to the incorporation of Mn atoms into CdSe QDs lattice. The Mn-doped CdSe QDs shows a slight blue-shift on absorption and emission spectra’s compared to pure CdSe even though is possessed larger QDs. The band gap structure modification prominently affected by the lattice strain were transition of Stoke`s, Rayleigh to anti-Stoke`s shifts observed as the Mn doped CdSe QDs size growth. The typical red-shift of absorption and emission wavelength observed with growth of QDs sizes. The role of oleic acid acid as a surfactant and capping agent shows in FTIR spectra. The lattice strain tailored the binding energy between the ion prominently on the surface of the QDs with growth of QDs sizes. 2017 Thesis NonPeerReviewed application/pdf http://studentsrepo.um.edu.my/7428/1/All.pdf application/pdf http://studentsrepo.um.edu.my/7428/6/aliya.pdf Nor Aliya, Hamizi (2017) Synthesis and characterization of Mn-doped CdSe quantum dots via inverse micelle technique / Nor Aliya Hamizi. PhD thesis, University of Malaya. http://studentsrepo.um.edu.my/7428/
spellingShingle TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
Nor Aliya, Hamizi
Synthesis and characterization of Mn-doped CdSe quantum dots via inverse micelle technique / Nor Aliya Hamizi
title Synthesis and characterization of Mn-doped CdSe quantum dots via inverse micelle technique / Nor Aliya Hamizi
title_full Synthesis and characterization of Mn-doped CdSe quantum dots via inverse micelle technique / Nor Aliya Hamizi
title_fullStr Synthesis and characterization of Mn-doped CdSe quantum dots via inverse micelle technique / Nor Aliya Hamizi
title_full_unstemmed Synthesis and characterization of Mn-doped CdSe quantum dots via inverse micelle technique / Nor Aliya Hamizi
title_short Synthesis and characterization of Mn-doped CdSe quantum dots via inverse micelle technique / Nor Aliya Hamizi
title_sort synthesis and characterization of mn-doped cdse quantum dots via inverse micelle technique / nor aliya hamizi
topic TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
url http://studentsrepo.um.edu.my/7428/
http://studentsrepo.um.edu.my/7428/1/All.pdf
http://studentsrepo.um.edu.my/7428/6/aliya.pdf