Thermal degradation and morphology of Polymer blends comprising Poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / Kamilah Binti Mohd. Alwai

Poly(ε-caprolactone) (PCL) is an aliphatic polyester. The PCL chains with weight-average molecular weight (Mw) of 4,200 g mol-1 are relatively short and contains terminal hydroxyl group. In blends with epoxidized natural rubber with 50% epoxidation level (ENR) (Mw = 700,000 g mol-1) as well as the a...

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Main Author: Mohd. Alwai, Kamilah
Format: Student Project
Language:English
Published: Faculty of Applied Sciences 2009
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/754/
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author Mohd. Alwai, Kamilah
author_facet Mohd. Alwai, Kamilah
author_sort Mohd. Alwai, Kamilah
building UiTM Institutional Repository
collection Online Access
description Poly(ε-caprolactone) (PCL) is an aliphatic polyester. The PCL chains with weight-average molecular weight (Mw) of 4,200 g mol-1 are relatively short and contains terminal hydroxyl group. In blends with epoxidized natural rubber with 50% epoxidation level (ENR) (Mw = 700,000 g mol-1) as well as the addition of phenol as catalyst, thermal properties and morphology of PCL/ENR/phenol blends were investigated. The FTIR studies show that there are no chemical changes for the neat polymers and the blends when phenol is added. Morphologies of PCL/ENR/phenol blends show that the PCL spherulites become smaller than that of the neat spherulites when phenol is added to the system. The degradation temperature experiments of the blends show that the T5% wt loss of the blends is lower than that of ENR.
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spelling uitm-7542017-04-21T00:48:55Z https://ir.uitm.edu.my/id/eprint/754/ Thermal degradation and morphology of Polymer blends comprising Poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / Kamilah Binti Mohd. Alwai Mohd. Alwai, Kamilah Polymers. Macromolecules Poly(ε-caprolactone) (PCL) is an aliphatic polyester. The PCL chains with weight-average molecular weight (Mw) of 4,200 g mol-1 are relatively short and contains terminal hydroxyl group. In blends with epoxidized natural rubber with 50% epoxidation level (ENR) (Mw = 700,000 g mol-1) as well as the addition of phenol as catalyst, thermal properties and morphology of PCL/ENR/phenol blends were investigated. The FTIR studies show that there are no chemical changes for the neat polymers and the blends when phenol is added. Morphologies of PCL/ENR/phenol blends show that the PCL spherulites become smaller than that of the neat spherulites when phenol is added to the system. The degradation temperature experiments of the blends show that the T5% wt loss of the blends is lower than that of ENR. Faculty of Applied Sciences 2009 Student Project NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/754/1/PPb_KAMILAH%20MOHD.%20ALWAI%20AS%2009_5.pdf Mohd. Alwai, Kamilah (2009) Thermal degradation and morphology of Polymer blends comprising Poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / Kamilah Binti Mohd. Alwai. (2009) [Student Project] <http://terminalib.uitm.edu.my/754.pdf> (Unpublished)
spellingShingle Polymers. Macromolecules
Mohd. Alwai, Kamilah
Thermal degradation and morphology of Polymer blends comprising Poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / Kamilah Binti Mohd. Alwai
title Thermal degradation and morphology of Polymer blends comprising Poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / Kamilah Binti Mohd. Alwai
title_full Thermal degradation and morphology of Polymer blends comprising Poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / Kamilah Binti Mohd. Alwai
title_fullStr Thermal degradation and morphology of Polymer blends comprising Poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / Kamilah Binti Mohd. Alwai
title_full_unstemmed Thermal degradation and morphology of Polymer blends comprising Poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / Kamilah Binti Mohd. Alwai
title_short Thermal degradation and morphology of Polymer blends comprising Poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / Kamilah Binti Mohd. Alwai
title_sort thermal degradation and morphology of polymer blends comprising poly(ε-caprolactone) and epoxidized natural rubber with addition of phenol as catalyst / kamilah binti mohd. alwai
topic Polymers. Macromolecules
url https://ir.uitm.edu.my/id/eprint/754/