Synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / Siti Hafizah Aminuddin

Synthesis of new hybrid nanocomposite material zinc-aluminium-3,4,5-trihydroxybenzoic acid (Zn-Al-Gallic acid) was successfully attained by the direct method with a molar ratio of Zn to Al; R=4 at different concentration of 3,4,5-trihydroxybenzoic acid in the range between 0.05 M to 0.5 M. The synth...

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Main Author: Aminuddin, Siti Hafizah
Format: Student Project
Language:English
Published: Faculty of Applied Sciences 2016
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/24737/
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author Aminuddin, Siti Hafizah
author_facet Aminuddin, Siti Hafizah
author_sort Aminuddin, Siti Hafizah
building UiTM Institutional Repository
collection Online Access
description Synthesis of new hybrid nanocomposite material zinc-aluminium-3,4,5-trihydroxybenzoic acid (Zn-Al-Gallic acid) was successfully attained by the direct method with a molar ratio of Zn to Al; R=4 at different concentration of 3,4,5-trihydroxybenzoic acid in the range between 0.05 M to 0.5 M. The synthesis pH is 7.0+ 0.5 and keeps in constant. The result from intercalation of gallic acid anion into zinc-aluminium-layered double hydroxide (Zn-Al-LDH) prove that size of interlayer spacing increasing from 8.8 Å in the layered double hydroxide to 9.8 Å in the Zn-Al-Gallic acid nanocomposite observed from the PXRD diffractogram. FTIR spectrum of synthesis of Zn-Al-Gallic acid nanocomposite shows the similarities of the Zn-Al-LDH and the gallic acid absorption bands which confirmed the gallic acid absorb into LDH inorganic interlayer. The percentage loading of the gallic acid results around 47.13 % (w/w) successfully intercalates into the interlayer based on the calculation and data obtained from the CHNS analysis. GA reaches equilibrium at 72 % released at 150 min so it can reach the target area efficiently.
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spelling uitm-247372019-07-19T00:41:25Z https://ir.uitm.edu.my/id/eprint/24737/ Synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / Siti Hafizah Aminuddin Aminuddin, Siti Hafizah QD Chemistry Extraction (Chemistry) Synthesis of new hybrid nanocomposite material zinc-aluminium-3,4,5-trihydroxybenzoic acid (Zn-Al-Gallic acid) was successfully attained by the direct method with a molar ratio of Zn to Al; R=4 at different concentration of 3,4,5-trihydroxybenzoic acid in the range between 0.05 M to 0.5 M. The synthesis pH is 7.0+ 0.5 and keeps in constant. The result from intercalation of gallic acid anion into zinc-aluminium-layered double hydroxide (Zn-Al-LDH) prove that size of interlayer spacing increasing from 8.8 Å in the layered double hydroxide to 9.8 Å in the Zn-Al-Gallic acid nanocomposite observed from the PXRD diffractogram. FTIR spectrum of synthesis of Zn-Al-Gallic acid nanocomposite shows the similarities of the Zn-Al-LDH and the gallic acid absorption bands which confirmed the gallic acid absorb into LDH inorganic interlayer. The percentage loading of the gallic acid results around 47.13 % (w/w) successfully intercalates into the interlayer based on the calculation and data obtained from the CHNS analysis. GA reaches equilibrium at 72 % released at 150 min so it can reach the target area efficiently. Faculty of Applied Sciences 2016 Student Project NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/24737/1/PPb_SITI%20HAFIZAH%20AMINUDDIN%20AS%20N%2016_5.pdf Aminuddin, Siti Hafizah (2016) Synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / Siti Hafizah Aminuddin. (2016) [Student Project] <http://terminalib.uitm.edu.my/24737.pdf> (Submitted)
spellingShingle QD Chemistry
Extraction (Chemistry)
Aminuddin, Siti Hafizah
Synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / Siti Hafizah Aminuddin
title Synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / Siti Hafizah Aminuddin
title_full Synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / Siti Hafizah Aminuddin
title_fullStr Synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / Siti Hafizah Aminuddin
title_full_unstemmed Synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / Siti Hafizah Aminuddin
title_short Synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / Siti Hafizah Aminuddin
title_sort synthesis of zn- al-3,4,5- trihydroxybenzoic acid – layered double hydroxide (ldh) by direct method and its controlled release activity / siti hafizah aminuddin
topic QD Chemistry
Extraction (Chemistry)
url https://ir.uitm.edu.my/id/eprint/24737/