Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah

In this study, solid biopolymer electrolyte (SBE) has been prepared using carboxymethyl cellulose (CMC) and ammonium chloride (AC) by solution casting method. The effect of plasticizers ; ethylene carbonate (BC) and propylene carbonate (PC) was investigated. The ionic conductivity of CMC-AC-EC an...

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Main Author: Abdullah, Fitriyah Munirah
Format: Student Project
Language:English
Published: Faculty of Applied Sciences 2017
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/23943/
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author Abdullah, Fitriyah Munirah
author_facet Abdullah, Fitriyah Munirah
author_sort Abdullah, Fitriyah Munirah
building UiTM Institutional Repository
collection Online Access
description In this study, solid biopolymer electrolyte (SBE) has been prepared using carboxymethyl cellulose (CMC) and ammonium chloride (AC) by solution casting method. The effect of plasticizers ; ethylene carbonate (BC) and propylene carbonate (PC) was investigated. The ionic conductivity of CMC-AC-EC and CMC-AC-PC achieved at 2.715 x 10-5 Scm-1 and 3.672 x 10-5 Scm-1, respectively. The Fourier Transform Infrared (FTIR) spectra showed the occurrence of complexation between the SBE and AC salt. X-Ray diffraction (XRD) indicated that amorphous nature is higher in CMC-AC-PC. Differential Scanning Calorimetry (DSC) showed higher Tg for CMC-AC-PC. It can be concluded that PC is the promising plasticizer to enhance the ionic conductivity and performance of SBE system.
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publishDate 2017
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spelling uitm-239432019-04-29T08:44:14Z https://ir.uitm.edu.my/id/eprint/23943/ Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah Abdullah, Fitriyah Munirah Polymers. Macromolecules In this study, solid biopolymer electrolyte (SBE) has been prepared using carboxymethyl cellulose (CMC) and ammonium chloride (AC) by solution casting method. The effect of plasticizers ; ethylene carbonate (BC) and propylene carbonate (PC) was investigated. The ionic conductivity of CMC-AC-EC and CMC-AC-PC achieved at 2.715 x 10-5 Scm-1 and 3.672 x 10-5 Scm-1, respectively. The Fourier Transform Infrared (FTIR) spectra showed the occurrence of complexation between the SBE and AC salt. X-Ray diffraction (XRD) indicated that amorphous nature is higher in CMC-AC-PC. Differential Scanning Calorimetry (DSC) showed higher Tg for CMC-AC-PC. It can be concluded that PC is the promising plasticizer to enhance the ionic conductivity and performance of SBE system. Faculty of Applied Sciences 2017 Student Project NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/23943/1/PPb_FITRIYAH%20MUNIRAH%20ABDULLAH%20AS%20C%2017_5.PDF Abdullah, Fitriyah Munirah (2017) Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah. (2017) [Student Project] <http://terminalib.uitm.edu.my/23943.pdf> (Unpublished)
spellingShingle Polymers. Macromolecules
Abdullah, Fitriyah Munirah
Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah
title Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah
title_full Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah
title_fullStr Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah
title_full_unstemmed Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah
title_short Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah
title_sort synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / fitriyah munirah abdullah
topic Polymers. Macromolecules
url https://ir.uitm.edu.my/id/eprint/23943/