Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad

Three Schiff base ligands were suscesssfully synthesized by condensation reaction of 4-hydroxybenzaldehye with benzylamine, o-phenylenediamine and ethylenediamine in 1:1 and 2:1 ratio yielding 4-hbba, 4-hbopd and 4-hben, respectively. Metal complex of Cu(II) has been isolated with the 4-hbba ligand...

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Main Author: Ahmad, Illuni Hayaty
Format: Student Project
Language:English
Published: Faculty of Applied Sciences 2009
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/23249/
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author Ahmad, Illuni Hayaty
author_facet Ahmad, Illuni Hayaty
author_sort Ahmad, Illuni Hayaty
building UiTM Institutional Repository
collection Online Access
description Three Schiff base ligands were suscesssfully synthesized by condensation reaction of 4-hydroxybenzaldehye with benzylamine, o-phenylenediamine and ethylenediamine in 1:1 and 2:1 ratio yielding 4-hbba, 4-hbopd and 4-hben, respectively. Metal complex of Cu(II) has been isolated with the 4-hbba ligand and all of the synthesized compounds are characterized by infrared spectroscopy, ¹H NMR, magnetic susceptibility and molar conductivity. It is proposed that the synthesized complex [Cu(4-hbba)(OAc)₂]₂.xH₂O, has a tetrahedral geometry. The synthesized compounds have been screened for antioxidant properties by comparing their activities with vitamin C, where the ligands 4-hben and 4-hbopd are found to possess some antioxidation activities.
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spelling uitm-232492019-02-22T02:21:01Z https://ir.uitm.edu.my/id/eprint/23249/ Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad Ahmad, Illuni Hayaty Organic chemistry Three Schiff base ligands were suscesssfully synthesized by condensation reaction of 4-hydroxybenzaldehye with benzylamine, o-phenylenediamine and ethylenediamine in 1:1 and 2:1 ratio yielding 4-hbba, 4-hbopd and 4-hben, respectively. Metal complex of Cu(II) has been isolated with the 4-hbba ligand and all of the synthesized compounds are characterized by infrared spectroscopy, ¹H NMR, magnetic susceptibility and molar conductivity. It is proposed that the synthesized complex [Cu(4-hbba)(OAc)₂]₂.xH₂O, has a tetrahedral geometry. The synthesized compounds have been screened for antioxidant properties by comparing their activities with vitamin C, where the ligands 4-hben and 4-hbopd are found to possess some antioxidation activities. Faculty of Applied Sciences 2009 Student Project NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/23249/1/PPb_ILLUNI%20HAYATY%20AHMAD%20AS%2009_5.pdf Ahmad, Illuni Hayaty (2009) Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad. (2009) [Student Project] <http://terminalib.uitm.edu.my/23249.pdf> (Unpublished)
spellingShingle Organic chemistry
Ahmad, Illuni Hayaty
Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_full Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_fullStr Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_full_unstemmed Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_short Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_sort synthesis, characterization and antioxidant studies of copper(ii) complex with schiff bases derived from 4-hydroxybenzaldehyde / illuni hayaty ahmad
topic Organic chemistry
url https://ir.uitm.edu.my/id/eprint/23249/